摘要:
A coating composition comprising a major amount of resin and a minor amount of a property-improving additive,said resin being:(A) a fluorocarbon resin selected from the group consisting of (1) perfluoroalkoxy tetrafluoroethylene copolymer resin (PFA), (2) ethylenechlorotrifluoroethylene copolymer resin (E-CTFE), (3) ethylenetetrafluoroethylene copolymer resin (E-TFE), (4) poly(vinylidene fluoride) resin (PVDF), (5) tetrafluoroethylene-hexafluoropropylene copolymer resin (FEP), (6) poly(chlorotrifluoroethylene) resin (CTFE), or a mixture of two or more of said fluorocarbon resins; or(B) a polyether resin selected from the group consisting of (7) polyethersulfone resin (PES), (8) polyether ketone resin (PEK) and (9) polyether ether ketone resin (PEEK) or a mixture or two or more of said polyether resin;said additive being:(C) a poly(phenylene sulfide) (PPS); or(D) an inorganic crystalline ceramic powder and/or fluorocarbon resin when said resin is a polyether of (B) above; or(E) an inorganic material selected from the group consisting of a nitride, an oxide, a diboride, and a carbide of silicon, of zirconium, of tungsten or of boron, or a polyester when said resin is a fluorocarbon of (A) above.Coatings and articles including a fused form of said composition and a method for forming said fused composition.
摘要:
A coating composition comprising a major amount of resin and a minor amount of a property-improving additive,said resin being:(A) a fluorocarbon resin selected from the group consisting of (1) perfluoroalkoxy tetrafluoroethylene copolymer resin (PFA), (2) ethylenechlorotrifluoroethylene copolymer resin (E-CTFE), (3) ethylenetetrafluoroethylene copolymer resin (E-TFE), (4) poly(vinylidine fluoride) resin (PVDF), (5) tetrafluoroethylene-hexafluoropropylene copolymer resin (FEP), (6) poly(chlorotrifluoroethylene) resin (CTFE), or a mixture of two or more of said fluorocarbon resins; or(B) a polyether resin selected from the group consisting of (7) polyethersulfone resin (PES), (8) polyether ketone resin (PEK) and (9) polyether ether ketone resin (PEEK) or a mixture of two or more of said polyether resins;said additive being:(C) a poly(phenylene sulfide) (PPS); or(D) an inorganic crystalline ceramic powder and/or fluorocarbon resin when said resin is a polyether of (B) above; or(E) an inorganic material selected from the group consisting of a nitride, an oxide, a diboride, and a carbide of silicon, of zirconium, of tungsten or of boron, or a polyether when said resin is a fluorocarbon of (A) above.Coatings and articles including a fused form of said composition and a method for forming said fused composition.
摘要:
A coating composition is based on a polyester mixed with an alkyl-etherified melamine formaldehyde. The coating composition is partially cured in a first stage to provide a thermoformable partially cured, tack-free, non-blocking, coating layer, followed by application to generally a contoured substrate and thermoforming to conform thereto. The contoured partially cured coating layer is then heat cured to form a cured coating. A hydroxyl-terminated polyoxetane containing repeat units derived from oxetane monomers having one or two pendent —CH2—O—(CH2)n—Rf groups, wherein Rf is partially or fully fluorinated, can be esterified with polyester-forming reactants to form a fluorinated polyoxetane-modified polyester.
摘要:
A method for preparing a substrate having an adherent, durable, flexible, and stain resistant layer. The layer is formed by applying a composition that includes (i) the reaction product of a polyester and a polyoxetane having at least one carboxylic acid end group and at least one pendant —CH2—O—(CH2)n—Rf group and (ii) an amino resin curative. The substrate may be printed or embossed or both. The coated substrate has both stain resistant properties and dry erase properties.
摘要:
A fluorine containing polymer which acts as a wetting, flow or leveling agent, and has at least one polar group. The polymer has at least one pendant or ether side chain containing from about 1 to about 20 carbon atoms with at least 25% of the hydrogen atoms being replaced by fluorine atoms. The fluorinated polymers unexpectedly impart wetting, flow or leveling properties to a variety of coatings while producing little foam.
摘要:
A polyester polymer includes at least one hydroxyl terminated polyoxetane block containing repeat units derived from polymerizing at least one oxetane monomer having a pendant —CH2—O—(CH2)n—Rf group wherein said Rf group is partially or fully fluorinated. A preferred process for forming said polymer is by reacting a hydroxyl terminated polyoxetane with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants. The polyester polymer containing at least one polyoxetane block therein when reacted with an amino resin curative can be used as a coating on a substrate wherein the coating has dry erase properties. The coated substrate can be used as prepared or applied to yet other substrates.
摘要:
The polymer of the present invention is derived from cyclic ether monomers, dioxane, dioxalane or trioxane and contains both pendant Rf fluoro groups as well as polar groups. These polymers have good wetting, or flow, or leveling properties. They can be reacted with other monomers, such as in the preparation of polyesters, and can be used in waxes, polishes and coatings.
摘要:
Anionic waterborne polyurethane dispersions are formed in the presence of polyfluorooxetane oligomers, polymers, or copolymers so that the polyfluorooxetanes are incorporated in the polyurethane. Coatings made from such polyurethanes have good low temperature flexibility, good chemical resistance and abrasion resistance, as well as a low coefficient of friction. Alternatively, the anionic water borne polyurethane dispersion can be blended with vinyl ester monomers such as various acrylates and subsequently polymerized by radiation, for example ultraviolet light, to form a comingled blend of at least two different types of polymers.
摘要:
Ethylene is polymerized by a catalyst system comprised of a transition metal complex consisting of at least one binucleating ligand attached to at least one transition metal containing nucleus; and an organometallic cocatalyst containing at least one element of Group IA, IIA or Group IIIA.
摘要:
Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.