-
公开(公告)号：US06417005B1
公开(公告)日：2002-07-09
申请号：US09171330
申请日：1998-12-07
IPC分类号： G01N3320
CPC分类号： C07C69/712 , C07C2603/92 , C07D219/08 , G01N31/22 , G01N33/84
摘要： Fluoroionophores that are functionalised with reactive groups and correspond to the formula I—R1—F—R2—G, wherein I is a monovalen residue of an ionophore, wherein F is a divalent residue of a fluorophore, wherein G is a functional group and R1 and R2 are each independently of the other a direct bond or a bridging group. The fluoroionophores may be covalently bound to carrier materials and are used as active components in polymer membranes of optical sensors for the detection of ions. The sensors are distinguished by a long usable life and a high degree of sensitivity.
摘要翻译： 用反应性基团官能化且对应于式I-R1-F-R2-G的氟荧光团，其中I是离子载体的单价残基，其中F是荧光团的二价残基，其中G是官能团，R 1 和R2各自独立地为另一个直接键或桥接基团。 氟代荧光体可以与载体材料共价结合，并且用作用于检测离子的光学传感器的聚合物膜中的活性组分。 传感器的使用寿命长，灵敏度高。
-
公开(公告)号：US06294390B1
公开(公告)日：2001-09-25
申请号：US09230217
申请日：1999-01-21
IPC分类号： G01N2176
CPC分类号： C07D493/08 , C07C69/00 , C07C2603/00 , C07D219/08 , C07D311/90 , G01N33/52 , G01N33/84 , Y10S436/80
摘要： Compounds, constructed in modular manner, of formula (I), wherein I is the monovalent residue of an ionophore, F is the monovalent residue of a fluorophore, G is a functional group, T is a trivalent organic radical and R01, R02 and R03 are each independently of the others a direct bond or a bridging group. The compounds may be used in immobilized form as active components in polymer membranes of optical sensors for the detection of ions. The sensors are distinguished by a long usable life and a high degree of sensitivity.
摘要翻译： 以式（I）的方式构建的化合物，其中I是离子载体的一价残基，F是荧光团的一价残基，G是官能团，T是三价有机基团，R 01，R 02和R 03各自 独立于其它直接键或桥接基团。化合物可以以固定形式用作用于检测离子的光学传感器的聚合物膜中的活性成分。 传感器的使用寿命长，灵敏度高。
-
公开(公告)号：US06576192B1
公开(公告)日：2003-06-10
申请号：US09171333
申请日：1999-02-08
IPC分类号： G01N2164
CPC分类号： C07D219/08 , C07D311/82 , C07D311/90 , G01N31/22 , G01N33/84
摘要： Fluoroionophores of formula (I) wherein R06 is H or substituted or unsubstituted C1-C20alkyl, R6 is H or substituted or unsubstituted C1-C30alkyl or C1-C30alkoxy, R1 is a bridging group, and F is a residue of a fluorophore. The fluoroionophores may be covalently bound to support materials and may be used as active components in polymer membranes of optical sensors for the detection of ions. The sensors are distinguished by short response times, a high degree of sensitivity and a long usable life.
摘要翻译： 式（I）的氟代磷酸酯，其中R06为H或取代或未取代的C1-C20烷基，R6为H或取代或未取代的C1-C30烷基或C1-C30烷氧基，R1为桥连基团，F为荧光团的残基。氟代荧光体可为 共价结合到支撑材料上，并且可以用作用于检测离子的光学传感器的聚合物膜中的活性成分。 传感器的响应时间短，灵敏度高，使用寿命长。
-
4.发明授权公开(公告)号：US06303385B2
公开(公告)日：2001-10-16
申请号：US09800667
申请日：2001-03-08
IPC分类号： G01N2164
CPC分类号： G01N33/84 , C08F220/56 , G01N21/6428 , G01N2021/7786 , Y10T436/15
摘要： A water-insoluble copolymer which is composed of (a) from 39.9 to 60% by weight of N,N-dimethylacrylamide or N,N-dimethylmethacrylamide; (b) from 60 to 39.9% by weight of N-alkylated acryl amides or N-alkylated methacryl amides; (c) from 0.1 to 0.7% by weight of a proton-sensitive fluorophore which is covalently bonded to the copolymer; and (d) from 0 to 20% by weight of a diolefinic crosslinking component. The copolymer is used in the form of a membrane on a transparent support material as an optical sensor for ionic strength-independent pH value determination.
摘要翻译： 由（a）39.9-60重量％的N，N-二甲基丙烯酰胺或N，N-二甲基甲基丙烯酰胺组成的水不溶性共聚物; （b）60〜39.9重量％的N-烷基化丙烯酰胺或N-烷基化甲基丙烯酰胺; （c）0.1〜0.7重量％的共价键共价键合的质子敏感荧光团; 和（d）0至20重量％的二烯烃交联组分。 共聚物以透明载体材料上的膜的形式用作用于离子强度非依赖性pH值测定的光学传感器。
-
公开(公告)号：US06252024B1
公开(公告)日：2001-06-26
申请号：US09051496
申请日：1998-11-02
IPC分类号： C08F22606
CPC分类号： G01N33/84 , C08F220/56 , G01N21/6428 , G01N2021/7786 , Y10T436/15
摘要： A water-insoluble copolymer which is composed of (a) from 39.9 to 60% by weight of N,N-dimethylacrylamide or N,N-dimethylmethacrylamide; (b) from 60 to 39.9% by weight of N-alkylated acryl amides or N-alkylated methacryl amides; (c) from 0.1 to 0.7% by weight of a proton-sensitive fluorophore which is covalently bonded to the copolymer; and (d) from 0 to 20% by weight of a diolefinic crosslinking component. The copolymer is used in the form of a membrane on a transparent support material as an optical sensor for ionic strength-independent pH value determination.
-
公开(公告)号：US06338822B1
公开(公告)日：2002-01-15
申请号：US09485995
申请日：2000-02-18
IPC分类号： G01N2164
CPC分类号： G01N31/223 , Y10S436/80 , Y10T436/16 , Y10T436/173845
摘要： A sensor for the optical determination by fluorescence of carbon dioxide in liquid and gaseous media, which consist essentially of a carrier and a light-sensitive layer applied thereto. In addition to a polymer as a base substance and an anionic fluorescence dye, the light-sensitive layer also contains a quaternary onium phenolate.
摘要翻译： 液体和气体介质中二氧化碳的荧光光学测定的传感器，其基本上由载体和施加于其上的光敏层组成。 除了作为基础物质的聚合物和阴离子荧光染料之外，感光层还含有酚醛季铵盐。
-
公开(公告)号：US06245574B1
公开(公告)日：2001-06-12
申请号：US09108003
申请日：1998-06-30
申请人： Adrian Waldner , René Beerli , Steven Mark Barnard
发明人： Adrian Waldner , René Beerli , Steven Mark Barnard
IPC分类号： G01N3320
CPC分类号： G01N31/22 , G01N2410/10
摘要： Sensors for the qualitative and quantitative determination of K+ ions in aqueous systems are described, which consist essentially of a carrier and an active layer applied to this carrier, whereby the active layer contains a polymer in which is dispersed at least one modified valinomycin, in which a radical of a fluorescence dye which emits in long waves, preferably an acridine or fluorescein, with an emission wave length of >550, is covalently bound.
摘要翻译： 描述了用于水性体系中K +离子的定性和定量测定的传感器，其基本上由施加到该载体的载体和活性层组成，由此活性层含有其中分散有至少一种修饰的缬氨霉素的聚合物，其中 发射波长> 550的长波长发射的荧光染料，优选吖啶或荧光素的基团是共价结合的。
-
8.发明授权
公开(公告)号：US6084683A
公开(公告)日：2000-07-04
申请号：US194523
申请日：1998-11-25
申请人： Alfredo Emilio Bruno , Steven Mark Barnard , Markus Ehrat , Reinhard Volkel , Philippe Nussbaum , Hans Peter Herzig
发明人： Alfredo Emilio Bruno , Steven Mark Barnard , Markus Ehrat , Reinhard Volkel , Philippe Nussbaum , Hans Peter Herzig
CPC分类号： G01N21/03 , G01N2021/0346
摘要： Optical detection apparatus for chemical analyses of small volumes of samples has light sources (21) to emit induction light, a measuring cell (7) for the sample, photoelectric sensing elements (22) to receive light coming form the sample in the measuring cell (7), as well as beam-conducting means for the induction light or the light from the sample. In the apparatus, several essentially planar, laminar components (2-7) are arranged in a sandwich structure, whereby the components (2-7) contain the light sources (21), the measuring cell (7), the photoelectric sensing elements (22), and also the beam conducting means.
摘要翻译： PCT No.PCT / EP97 / 02745 Sec。 371日期：1998年11月25日 102（e）1998年11月25日日期PCT提交1997年5月27日PCT公布。 WO97 / 45718 PCT公开号 日期1997年12月4日用于小体积样品的化学分析的光学检测装置具有发射感光的光源（21），用于样品的测量单元（7），用于接收来自样品的光的光电感测元件（22） 在测量单元（7）中，以及用于感应光或来自样品的光的光束传导装置。 在该设备中，几个基本上平面的层状部件（2-7）被布置成夹层结构，由此部件（2-7）包含光源（21），测量单元（7），光电感测元件 22），以及光束传导装置。
-
9.发明授权
公开(公告)号：US5757014A
公开(公告)日：1998-05-26
申请号：US625330
申请日：1996-04-01
CPC分类号： G01N21/7703 , G01N21/645
摘要： In the optical detection device (1), the excitation light guide (11) and the emission light guide (12) form a structural unit having the end face (14) facing the fluorescence changer (4). The end face (14) physically corresponds substantially to one of the boundary surfaces of the two light guides (11, 12). As a result, the detection device (1) can be separated in a simple manner into an optical part and a mechanical part which are in optical contact only by way of the end face (14). All of the elements in the optical light path are connected in a mechanically stable manner by means of the index-matching medium 20, as a result of which the light between the light source (10) and the photoelectric sensor (13) propagates only in media having a comparable refractive index. The light source (10) is preferably a light-emitting diode. A plurality of those detection devices can be combined to form a compact detection apparatus with which the substance (3) can be examined with regard to several constituents in one measuring operation.
摘要翻译： 在光检测装置（1）中，激发光导（11）和发射光导（12）形成具有面向荧光变换器（4）的端面（14）的结构单元。 端面（14）物理地基本上对应于两个光导（11,12）的边界表面之一。 结果，可以将检测装置（1）以简单的方式分离成仅通过端面（14）光学接触的光学部件和机械部件。 光学路径中的所有元件通过折射率匹配介质20以机械稳定的方式连接，结果，光源（10）和光电传感器（13）之间的光仅在 具有相当折射率的介质。 光源（10）优选为发光二极管。 可以将多个检测装置组合以形成紧凑的检测装置，在一次测量操作中可以通过该检测装置检查物质（3）关于若干成分。
-
-
-
-
-
-
-
-
搜索结果
9 条记录 (耗时 0.033 秒)
