pH SENSITIVE QUANTUM DOTS FOR USE AS CURE INDICATORS

    公开(公告)号:US20170152349A1

    公开(公告)日:2017-06-01

    申请号:US14955388

    申请日:2015-12-01

    CPC classification number: C08G75/14 B82Y30/00 C08G75/02 G01N21/80

    Abstract: Disclosed is a curable sealant composition including: (i) a thiol-terminated prepolymer and/or monomers thereof, wherein the thiol-terminated prepolymer is a polythioether or a polysulfide; (ii) an “ene” crosslinker having a molecular weight of about 100 to about 5000; and (iii) a pH indicator molecule including a quantum dot functionalized with a pH-responsive ligand. Methods for determining a sufficient cure state of a composition by combining the thiol-terminated prepolymer and/or monomers thereof and the “ene” crosslinker with a pH indicator molecule, including a quantum dot functionalized with a pH-responsive ligand, and (ii) then subjecting a resultant mixture of (i) to curing conditions until the mixture changes its color are also disclosed.

    pH SENSITIVE QUANTUM DOTS FOR USE AS CURE INDICATORS

    公开(公告)号:US20190153165A1

    公开(公告)日:2019-05-23

    申请号:US16255656

    申请日:2019-01-23

    Abstract: Disclosed is a curable sealant composition including: (i) a thiol-terminated prepolymer and/or monomers thereof, wherein the thiol-terminated prepolymer is a polythioether or a polysulfide; (ii) an “ene” crosslinker having a molecular weight of about 100 to about 5000; and (iii) a pH indicator molecule including a quantum dot functionalized with a pH-responsive ligand. Methods for determining a sufficient cure state of a composition by combining the thiol-terminated prepolymer and/or monomers thereof and the “ene” crosslinker with a pH indicator molecule, including a quantum dot functionalized with a pH-responsive ligand, and (ii) then subjecting a resultant mixture of (i) to curing conditions until the mixture changes its color are also disclosed.

    pH sensitive quantum dots for use as cure indicators

    公开(公告)号:US10246557B2

    公开(公告)日:2019-04-02

    申请号:US14955388

    申请日:2015-12-01

    Abstract: Disclosed is a curable sealant composition including: (i) a thiol-terminated prepolymer and/or monomers thereof, wherein the thiol-terminated prepolymer is a polythioether or a polysulfide; (ii) an “ene” crosslinker having a molecular weight of about 100 to about 5000; and (iii) a pH indicator molecule including a quantum dot functionalized with a pH-responsive ligand. Methods for determining a sufficient cure state of a composition by combining the thiol-terminated prepolymer and/or monomers thereof and the “ene” crosslinker with a pH indicator molecule, including a quantum dot functionalized with a pH-responsive ligand, and (ii) then subjecting a resultant mixture of (i) to curing conditions until the mixture changes its color are also disclosed.

    pH sensitive quantum dots for use as cure indicators

    公开(公告)号:US11072687B2

    公开(公告)日:2021-07-27

    申请号:US16255656

    申请日:2019-01-23

    Abstract: Disclosed is a curable sealant composition including: (i) a thiol-terminated prepolymer and/or monomers thereof, wherein the thiol-terminated prepolymer is a polythioether or a polysulfide; (ii) an “ene” crosslinker having a molecular weight of about 100 to about 5000; and (iii) a pH indicator molecule including a quantum dot functionalized with a pH-responsive ligand. Methods for determining a sufficient cure state of a composition by combining the thiol-terminated prepolymer and/or monomers thereof and the “ene” crosslinker with a pH indicator molecule, including a quantum dot functionalized with a pH-responsive ligand, and (ii) then subjecting a resultant mixture of (i) to curing conditions until the mixture changes its color are also disclosed.

    Peel adhesion test specimens and method for their preparation

    公开(公告)号:US10274416B2

    公开(公告)日:2019-04-30

    申请号:US15599209

    申请日:2017-05-18

    Abstract: A method of preparing specimens for peel-adhesion testing. The method includes applying a first predetermined amount of light-curable material to a substrate coupon, placing a first surface of a substantially transparent peel media in contact with the light-curable material disposed on the substrate coupon, where the substantially transparent peel media includes a second surface spaced from the first surface, and exposing the first predetermined amount of light-curable material disposed between the substrate coupon and the first surface to a light source to cure the first predetermined amount of light-curable material, with light from the light source passing through the substantially transparent peel media to the substrate coupon.

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