公开(公告)号：US20130045159A1

公开(公告)日：2013-02-21

申请号：US13633316

申请日：2012-10-02

Applicant: TODA KOGYO CORPORATION

Inventor： Shinji TAKAHASHI ,  Naoya KOBAYASHI

IPC: B01J23/78 ,  C01B3/26

CPC classification number: B01J23/8946 ,  B01J21/005 ,  B01J23/007 ,  B01J23/78 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  C01B3/26 ,  C01B3/40 ,  C01B2203/0277 ,  C01B2203/066 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1094 ,  H01M8/0612 ,  H01M8/0637 ,  H01M10/0569 ,  Y02E60/50 ,  Y02E60/566 ,  Y02P20/52 ,  Y02P70/56 ,  Y10S502/524

Abstract: A process for producing the porous catalyst body for decomposing hydrocarbons, the body containing at least magnesium, aluminum and nickel, and has a pore volume of 0.01 to 0.5 cm3/g, an average pore diameter of not more than 300 Å and an average crushing strength of not less than 3 kgf. The process includes molding hydrotalcite containing at least magnesium, aluminum and nickel, and calcining the resulting molded product at a temperature of 700 to 1500° C.

Abstract translation: 一种生产用于分解烃的多孔催化剂体的方法，该体系至少含有镁，铝和镍，体积为0.01〜0.5cm 3 / g，平均孔径为300以下，平均粉碎 强度不低于3 kgf。 该方法包括模塑含有至少镁，铝和镍的水滑石，并在700至1500℃的温度下煅烧所得模制产品。

公开(公告)号：US20160167963A1

公开(公告)日：2016-06-16

申请号：US15047917

申请日：2016-02-19

Applicant: TODA KOGYO CORPORATION

Inventor： Naoya KOBAYASHI ,  Shinji TAKAHASHI

IPC: C01B3/26 ,  B01J23/89 ,  B01J23/889 ,  B01J23/755

CPC classification number: C01B3/26 ,  B01J23/755 ,  B01J23/78 ,  B01J23/8892 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/898 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J35/06 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0221 ,  B01J37/03 ,  C01B2203/0233 ,  C01B2203/0277 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1082 ,  C10G11/02 ,  C10G11/04 ,  C10G2300/807 ,  H01M8/00

Abstract: The present invention relates to a hydrocarbon-decomposing catalyst comprising magnesium, aluminum and nickel as constitutional elements, containing silicon in an amount of 0.001 to 20% by weight (calculated as Si) based on the weight of the catalyst, and having a nickel content of 0.1 to 40% by weight (calculated as metallic nickel) based on the weight of the catalyst; and a hydrocarbon-decomposing catalyst comprising a porous carrier and a catalytically active metal carried on the carrier, said porous carrier comprising magnesium and aluminum as constitutional elements and containing silicon in an amount of 0.001 to 20% by weight (calculated as Si) based on the weight of the catalyst, and said catalytically active metal comprising fine metallic nickel particles, a content of said fine metallic nickel particles being 0.1 to 40% by weight (calculated as metallic nickel) based on the weight of the catalyst. The hydrocarbon-decomposing catalyst of the present invention is less expensive, and can exhibit an excellent catalytic activity capable of decomposing C1 or more hydrocarbons, a good anti-coking property even under a less steam condition, a good effect of reducing an amount of ammonia by-produced even upon using nitrogen-containing hydrocarbon fuels, and a sufficient strength capable of preventing the catalyst from being crushed and broken even upon occurrence of coking inside thereof, and an excellent durability.

Abstract translation: 本发明涉及一种烃分解催化剂，其包含镁，铝和镍作为构成元素，其含量为基于催化剂重量的0.001-20重量％（以Si计），并且具有镍含量 0.1至40重量％（以金属镍计算）; 以及一种烃分解催化剂，其包含承载在所述载体上的多孔载体和催化活性金属，所述多孔载体包含镁和铝作为构成元素，并且含有硅的量为0.001至20重量％（以Si计）基于 催化剂的重量和包含细金属镍颗粒的所述催化活性金属，所述细金属镍颗粒的含量基于催化剂的重量为0.1-40重量％（以金属镍计））。 本发明的烃分解催化剂成本较低，即使在较少的蒸汽条件下也能表现出能够分解C1或更多烃的极好的催化活性，即使具有良好的抗焦化性，也能够有效地降低氨的量 即使使用含氮烃燃料也能够副产，具有足够的强度，即使在其内发生焦化时也能够防止催化剂破碎破碎，耐久性优异。

公开(公告)号：US20130287679A1

公开(公告)日：2013-10-31

申请号：US13926091

申请日：2013-06-25

Applicant: TODA KOGYO CORPORATION

Inventor： Shinji TAKAHASHI ,  Naoya KOBAYASHI

IPC: B01J23/89 ,  C01B3/26 ,  B01J23/78

CPC classification number: B01J23/8946 ,  B01J21/005 ,  B01J23/007 ,  B01J23/78 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  C01B3/26 ,  C01B3/40 ,  C01B2203/0277 ,  C01B2203/066 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1094 ,  H01M8/0612 ,  H01M8/0637 ,  H01M10/0569 ,  Y02E60/50 ,  Y02E60/566 ,  Y02P20/52 ,  Y02P70/56 ,  Y10S502/524

Abstract: A process for producing the porous catalyst body for decomposing hydrocarbons, the body containing at least magnesium, aluminum and nickel, and has a pore volume of 0.01 to 0.5 cm3/g, an average pore diameter of not more than 300 Å and an average crushing strength of not less than 3 kgf. The process includes molding hydrotalcite containing at least magnesium, aluminum and nickel, and calcining the resulting molded product at a temperature of 700 to 1500° C.