Abstract:
According to the present disclosure, there is provided a technique capable of suitably reducing the battery resistance of a lithium ion secondary battery. In an aspect of a negative electrode disclosed herein, a negative electrode active material layer contains a negative electrode active material, a binder which includes a water-soluble polymer lithium salt, and a sub-material particle including a metal compound which has a hydroxyl group. With this, hopping conduction in which a Li ion moves in such a manner as to slide on hydroxyl groups on the surface of the sub-material particle can occur, and hence it is possible to accelerate supply of the Li ion to the negative electrode active material and achieve a significant reduction in the battery resistance of the lithium secondary battery.
Abstract:
A method of manufacturing a nonaqueous electrolyte secondary battery includes: a kneading step of kneading a carbon-based negative electrode active material, a binder, and a sugar alcohol with each other to form a negative electrode mixture paste; and an application step of applying the negative electrode mixture paste to a negative electrode current collector to form a negative electrode mixture layer.
Abstract:
A flat-plate portion of a negative electrode composite material layer includes a first end portion at one end portion in a direction of axis of winding of a flat electrode winding assembly, a second end portion located opposite to the first end portion, and a central portion lying between the first end portion and the second end portion. The flat-plate portion of the negative electrode composite material layer is provided with a plurality of communication grooves. The communication groove includes a first terminal end portion at the first end portion, includes a second terminal end portion at the second end portion, includes in the central portion, a starting portion located closer to a bottom portion of a prismatic case relative to the first terminal end portion and the second terminal end portion, and extends from the starting portion toward the first terminal end portion and the second terminal end portion.
Abstract:
A manufacturing method for a non-aqueous electrolyte secondary battery includes: forming a powder; forming a sheet-like green compact; and forming a heat-resistant layer. The powder contains composite particles and a solvent. The composite particles contain inorganic filler particles and a binder. The green compact is formed by pressing the powder in a state in which the solvent remains. The heat-resistant layer is formed by disposing the green compact on a surface of at least any of a positive electrode mixture layer and a negative electrode mixture layer after the green compact is formed.
Abstract:
A nonaqueous electrolyte secondary battery includes: a positive electrode collector core material; and a sheet body including a plurality of granulation bodies. The sheet body is disposed on the positive electrode collector core material. The granulation bodies each contain a first positive electrode active material particle, a second positive electrode active material particle, and expanded graphite, the first positive electrode active material particle including lithium-nickel composite oxide, the second positive electrode active material particle including lithium iron phosphate.
Abstract:
A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator provided between the positive electrode and the negative electrode, and a nonaqueous electrolytic solution at least held by the separator. The positive electrode has a positive electrode collector and a positive electrode mixture layer provided on the positive electrode collector. The positive electrode mixture layer has a first powder and a second powder. The first powder includes a first positive electrode active material, a first conductive material, and an organic-based binder. The second powder includes a second positive electrode active material, a second conductive material, and a water-based binder.
Abstract:
A lithium ion secondary battery includes: an electrode mixture layer that contains an electrode active material and an organic ferroelectric having a dielectric constant of 25 or higher; and an electrolytic solution that contains lithium bis(fluorosulfonyl)imide and a nonaqueous solvent. A content of the organic ferroelectric is 0.5 parts by mass to 10 parts by mass with respect to 100 parts by mass of the electrode active material. A proportion of a high-polarity solvent having a dielectric constant of 10 or higher in the nonaqueous solvent is 10 vol % or lower.
Abstract:
A nonaqueous electrolyte secondary battery includes: a negative electrode current collector foil; and a negative electrode mixture layer that is arranged on the negative electrode current collector foil. The negative electrode mixture layer contains a plurality of granulated particles. Each of the granulated particles contains a negative electrode active material and a coating film. The coating film is formed on a surface of the negative electrode active material. The coating film includes a first film and a second film. The first film is formed on the surface of the negative electrode active material. The second film is formed on the first film. The first film contains a carboxymethyl cellulose polymer. The second film contains a polyacrylic acid polymer.
Abstract:
Provided is a method for producing a negative electrode by using a negative electrode active material and ceramic particles, the method ensuring satisfactory coatability of the paste and high peel strength and hardness of the obtained negative electrode active material layer. The method for producing a negative electrode disclosed herein includes a step of coating a negative electrode paste including a negative electrode active material and ceramic particles on a negative electrode current collector; a step of drying the coated negative electrode paste to form a negative electrode active material layer; and a step of pressing the negative electrode active material layer. The ceramic particles have an aspect ratio of 1.5 or more and 20 or less. The ceramic particles have a short side length of 1/5 or less of an average particle diameter of the negative electrode active material. In the negative electrode paste, the ceramic particles are contained in an amount of 3% by mass to 20% by mass based on a total solid content of the negative electrode paste.
Abstract:
Provided is a non-aqueous electrolyte secondary battery in which an increase in resistance is suppressed when high rate pulsed charging and discharging is repeatedly carried out. The non-aqueous electrolyte secondary battery provided by the present disclosure is provided with: a positive electrode; a negative electrode; a separator; and a non-aqueous electrolyte solution. The separator is provided with a separator base made of a non-woven fabric; a first resin layer provided on a surface of the separator base that faces the positive electrode; and a second resin layer provided on a surface of the separator base that faces the negative electrode. In addition, a resin matrix of the first resin layer is constituted from polytetrafluoroethylene or a copolymer containing polytetrafluoroethylene as a primary component, and a resin matrix of the second resin layer is constituted from poly(vinylidene fluoride) or a copolymer containing poly(vinylidene fluoride) as a primary component.