Fluorinated compound, water repellent composition and thin film
    1.
    发明授权
    Fluorinated compound, water repellent composition and thin film 失效
    氟化合物,防水组合物和薄膜

    公开(公告)号:US07393515B2

    公开(公告)日:2008-07-01

    申请号:US11446200

    申请日:2006-06-05

    IPC分类号: B01J3/06 C07F7/04

    摘要: To provide a fluorinated compound, which can readily form a thin film having a hydrophobic/hydrophilic pattern, by employing an ultraviolet light having a relatively low energy.A thin film having a hydrophobic/hydrophilic pattern is formed by irradiating a thin film formed by employing a fluorinated compound represented by the following formula 1 (in the formula 1, each of R1, R2, R3 and R4 which are independent of one another, is a hydrogen atom, a halogen atom or a monovalent organic group, provided that at least one of them is a monovalent organic group having fluorine atoms, and R5 is a hydrogen atom or a monovalent organic group, R6 is a monovalent organic group, and A is a hetero atom) with ultraviolet light

    摘要翻译: 为了提供能够容易地形成具有疏水/亲水图案的薄膜的氟化化合物,通过使用具有较低能量的紫外光。 通过照射通过使用由下式1表示的氟化化合物形成的薄膜来形成具有疏水/亲水图案的薄膜(在式1中,R 1,R 2, 2个,R 3和R 4彼此独立的是氢原子,卤素原子或一价有机基团,条件是至少 其中一个是具有氟原子的一价有机基团,R 5是氢原子或一价有机基团,R 6是一价有机基团,A是 一个杂原子)与紫外线

    Polymerizable fluorine-containing compound and treated substrate having a hydrophilic region and a water repellent region
    2.
    发明授权
    Polymerizable fluorine-containing compound and treated substrate having a hydrophilic region and a water repellent region 失效
    可聚合的含氟化合物和具有亲水区域和拒水区域的处理过的基材

    公开(公告)号:US08338502B2

    公开(公告)日:2012-12-25

    申请号:US12365970

    申请日:2009-02-05

    摘要: To provide a polymerizable fluorine-containing compound useful for producing a treated substrate having a hydrophilic region and a water repellent region, of which the contrast is high on its surface, without requiring a special apparatus, high energy light, or irradiation with light for a long time.A polymerizable fluorine-containing compound, which is a derivative of a polyhydric alcohol and comprises at least one following structure (A) and at least one following structure (B) in its molecule: structure (A): a structure wherein a compound having a fluoroalkyl group and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage, structure (B): a structure wherein a compound having an ethylenic double bond and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage or a structure wherein a compound having an ethylenic double bond and an isocyanate group is bonded to one hydroxyl group of a polyhydric alcohol by a urethane bond.

    摘要翻译: 为了提供可用于制备具有亲水区域和防水区域的处理基材的可聚合含氟化合物,其表面上的对比度高,而不需要特殊装置,高能量光或用于光的照射 长时间。 一种可聚合的含氟化合物,其是多元醇的衍生物,其分子中包含至少一种以下结构(A)和至少一种以下结构(B):结构(A):其中具有 氟烷基和羧基通过酯键与多元醇的一个羟基键合,结构(B):其中具有烯键式双键和羧基的化合物与多元醇的一个羟基键合的结构 通过酯键或其中具有烯属双键和异氰酸酯基的化合物通过氨基甲酸酯键与多元醇的一个羟基键合的结构。

    POLYMERIZABLE FLUORINE-CONTAINING COMPOUND AND TREATED SUBSTRATE HAVING A HYDROPHILIC REGION AND A WATER REPELLENT REGION
    3.
    发明申请
    POLYMERIZABLE FLUORINE-CONTAINING COMPOUND AND TREATED SUBSTRATE HAVING A HYDROPHILIC REGION AND A WATER REPELLENT REGION 失效
    含聚合氟化合物和处理的具有水解区域和水分区域的基底

    公开(公告)号:US20090155549A1

    公开(公告)日:2009-06-18

    申请号:US12365970

    申请日:2009-02-05

    摘要: To provide a polymerizable fluorine-containing compound useful for producing a treated substrate having a hydrophilic region and a water repellent region, of which the contrast is high on its surface, without requiring a special apparatus, high energy light, or irradiation with light for a long time.A polymerizable fluorine-containing compound, which is a derivative of a polyhydric alcohol and comprises at least one following structure (A) and at least one following structure (B) in its molecule: structure (A): a structure wherein a compound having a fluoroalkyl group and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage, structure (B): a structure wherein a compound having an ethylenic double bond and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage or a structure wherein a compound having an ethylenic double bond and an isocyanate group is bonded to one hydroxyl group of a polyhydric alcohol by a urethane bond.

    摘要翻译: 为了提供可用于制备具有亲水区域和防水区域的处理基材的可聚合含氟化合物,其表面上的对比度高,而不需要特殊装置,高能量光或用于光的照射 长时间。 一种可聚合的含氟化合物,其是多元醇的衍生物,其分子中包含至少一种以下结构(A)和至少一种以下结构(B):结构(A):其中具有 氟烷基和羧基通过酯键与多元醇的一个羟基键合,结构(B):其中具有烯键式双键和羧基的化合物与多元醇的一个羟基键合的结构 通过酯键或其中具有烯属双键和异氰酸酯基的化合物通过氨基甲酸酯键与多元醇的一个羟基键合的结构。

    Fluorinated compound, water repellent composition and thin film
    4.
    发明申请
    Fluorinated compound, water repellent composition and thin film 失效
    氟化合物,防水组合物和薄膜

    公开(公告)号:US20060222865A1

    公开(公告)日:2006-10-05

    申请号:US11446200

    申请日:2006-06-05

    IPC分类号: C07F7/10 B32B13/04

    摘要: To provide a fluorinated compound, which can readily form a thin film having a hydrophobic/hydrophilic pattern, by employing an ultraviolet light having a relatively low energy. A thin film having a hydrophobic/hydrophilic pattern is formed by irradiating a thin film formed by employing a fluorinated compound represented by the following formula 1 (in the formula 1, each of R1, R2, R3 and R4 which are independent of one another, is a hydrogen atom, a halogen atom or a monovalent organic group, provided that at least one of them is a monovalent organic group having fluorine atoms, and R5 is a hydrogen atom or a monovalent organic group, R6 is a monovalent organic group, and A is a hetero atom) with ultraviolet light.

    摘要翻译: 为了提供能够容易地形成具有疏水/亲水图案的薄膜的氟化化合物,通过使用具有较低能量的紫外光。 通过照射通过使用由下式1表示的氟化化合物形成的薄膜来形成具有疏水/亲水图案的薄膜(在式1中,R 1,R 2, 2个,R 3和R 4彼此独立的是氢原子,卤素原子或一价有机基团,条件是至少 其中一个是具有氟原子的一价有机基团,R 5是氢原子或一价有机基团,R 6是一价有机基团,A是 一个杂原子)与紫外线。

    Fluorine-containing unsaturated compound and method for its production
    5.
    发明申请
    Fluorine-containing unsaturated compound and method for its production 审中-公开
    含氟不饱和化合物及其制备方法

    公开(公告)号:US20050113609A1

    公开(公告)日:2005-05-26

    申请号:US11026012

    申请日:2005-01-03

    申请人: Yutaka Furukawa

    发明人: Yutaka Furukawa

    IPC分类号: C07C43/17 C07C41/00

    CPC分类号: C07C43/17

    摘要: A novel fluorine-containing unsaturated compound and a method for its production. A fluorine-containing unsaturated compound represented by R1CY1HCY2Y3OQ1CH═CH2 or CH2═CHQ2OCZ1Z2CZ3HR2CZ4HCZ5Z6OQ2CH═CH2 (wherein R1 is a monovalent fluorine containing organic group, etc., R2 is a bivalent fluorine containing organic group, etc., Y1 to Y3 and Z1 to Z6 are fluorine atoms, and Q1 and Q2 are alkylene groups, etc.). A method for producing a fluorine-containing unsaturated compound having a group represented by —CX1HCX2X3OQCH═CH2 (wherein X1 to X3 are fluorine atoms, and Q is an alkylene group, etc.), which comprises reacting a compound having —CX1═CX2X3 with HOQCH═CH2 in the presence of an alkali metal compound.

    摘要翻译: 一种新型含氟不饱和化合物及其制备方法。 由R 1表示的含氟不饱和化合物1 CH 2 CH 2或CH 2 -CHQ 2 O 2 ZZZ 2 O 2 / SUP> CZ 3 2 > 2 CH-CH 2(其中R 1是一价含氟有机基团等,R 2是 二价含氟有机基团等,Y 1至Y 3和Z 1至Z 6均为氟 原子,Q 1和Q 2是亚烷基等)。 一种具有由-CX 1 -OXCH 2 O 3 OQCH-CH 2表示的基团的含氟不饱和化合物的制备方法 (其中X 1至X 3是氟原子,Q是亚烷基等),其包括使具有-CX 3 3。

    Fluorine-containing organic silicon compound and method for its production
    6.
    发明授权
    Fluorine-containing organic silicon compound and method for its production 失效
    含氟有机硅化合物及其制备方法

    公开(公告)号:US06448428B1

    公开(公告)日:2002-09-10

    申请号:US10002140

    申请日:2001-12-05

    IPC分类号: C07F708

    CPC分类号: C07F7/0836 C09K3/18

    摘要: A fluorine-containing organic silicon compound represented by the following formula (1):   (1) provided that the symbols in the formula (1) have the following meanings: R1 and R2: respectively independently monovalent hydrocarbon groups; Af: a group represented by the following formula (2), (3), (4) or (5): A1—X1—  (2) A2—X2—O—X1—  (3) A1—X2—O—X1—  (4) A2—X1—  (5) provided that the symbols in the formulae (2), (3), (4) and (5) have the following meanings: A1: a monovalent polyfluorohydrocarbon group; A2: a monovalent polyfluorohydrocarbon group containing an etheric oxygen atom; X1: —(CH2)a— (a is an integer of at least 3); X2: a bivalent hydrocarbon group.

    摘要翻译: 由下式(1)表示的含氟有机硅化合物:式(1)中的符号具有以下含义:R 1和R 2分别独立地为一价烃基; Af:由下式 式(2),(3),(4)或(5):式(2),(3),(4)和(5)中的符号具有下列含义:A1:一价多氟烃基; A2:含有醚性氧原子的一价多氟烃基; X1: - (CH2)a-(a为3以上的整数); X2为二价烃基。

    Stainproofing oil for a heat fixing roller
    7.
    发明授权
    Stainproofing oil for a heat fixing roller 失效
    用于热定影辊的防油

    公开(公告)号:US5568239A

    公开(公告)日:1996-10-22

    申请号:US412221

    申请日:1995-03-27

    摘要: A stainproofing oil for a heat fixing roller, which consists essentially of a fluorosilicone compound having a silicon atom to which a monovalent fluorine-containing group selected from the formulae (1) to (3) is bonded:R.sub.f.sup.1 --X.sup.1 -- (1)R.sub.f.sup.2 --X.sup.2 --O--X.sup.3 -- (2)R.sub.f.sup.3 --X.sup.4 --O--X.sup.5 -- (3)wherein R.sub.f.sup.1 is a monovalent polyfluorohydrocarbon group, R.sub.f.sup.2 is a monovalent polyfluoroalkyl group containing an ether oxygen atom, R.sub.f.sup.3 is a monovalent polyfluorohydrocarbon group, and each of X.sup.1 to X.sup.5 independently is a bivalent hydrocarbon group.

    摘要翻译: 用于热定影辊的防污油,其基本上由具有选自式(1)至(3)的一价含氟基团的具有硅原子的氟硅氧烷化合物组成:Rf1-X1-(1)Rf2 -X2-O-X3-(2)Rf3-X4-O-X5-(3)其中Rf1是一价多氟烃基,Rf2是含有醚氧原子的一价多氟烷基,Rf3是一价多氟烃基, X1〜X5独立地为二价烃基。

    Method for producing a fluoroalcohol
    8.
    发明授权
    Method for producing a fluoroalcohol 有权
    氟代醇的制造方法

    公开(公告)号:US06410808B1

    公开(公告)日:2002-06-25

    申请号:US09840072

    申请日:2001-04-24

    IPC分类号: C07C3134

    摘要: A method for producing a fluoroalcohol of the following formula 1a, which comprises reacting a compound of the following formula 1 with water in a liquid phase at a temperature of 150° C. or higher under a gauge pressure of 0.4 MPa or higher: wherein n is an integer of from 1 to 5, X is a chlorine atom, a bromine atom or an iodine atom, p is an integer of at least 1, and R is a p-valent organic group, provided that when p is 1, R may be a hydrogen atom or a halogen atom.

    摘要翻译: 一种下式1a的氟代醇的制造方法,其特征在于,在表压为0.4MPa以上的条件下,使下式1的化合物与液相中的水在150℃以上的温度下反应:其中n 为1〜5的整数,X为氯原子,溴原子或碘原子,p为1以上的整数,R为p价有机基团,条件是当p为1时,R 可以是氢原子或卤素原子。

    Polyether modified fluoroalkylsiloxanes
    9.
    发明授权
    Polyether modified fluoroalkylsiloxanes 失效
    聚醚改性氟烷基硅氧烷

    公开(公告)号:US5908950A

    公开(公告)日:1999-06-01

    申请号:US862939

    申请日:1997-05-29

    CPC分类号: C08G77/385 C08G77/46

    摘要: Polyether modified fluoroalkylsiloxanes having the general structure of Formula (I), Formula (II) or Formula (III): ##STR1## wherein x is about 0 to 500, y is about 1 to 50, z is about 1 to 50, R=C.sub.p H.sub.2p --(OC.sub.2 H.sub.4).sub.n --(OC.sub.3 H.sub.6).sub.n).sub.m --OR' in which p is about 2 to 5, n is about 0 to 50, N is about 0 to 50, and one of n or m must be >0, and R'=H, an alkyl group with 1-4 carbons, or an acetyl group and R.sub.f =C.sub.a H.sub.2a --O.sub.b --C.sub.c H.sub.2c --C.sub.d F.sub.2d+1 in which a is 3 or 4, b is 0 or 1, c is 0 or 2-4 and d is 4-12 with the provisos that if b=0, then c=0, and that if b=1, then c=2-4; z.sub.1 is about 0 to 50 and y.sub.1 is about 0 to 50, are useful to reduce the coefficient of friction and to increase mar resistance of coatings, to increase spreadability and wettability of coating formulations, and as foam control agents.

    摘要翻译: 具有式(I),式(II)或式(III)的通式结构的聚醚改性氟代烷基硅氧烷:其中x为约0至500,y为约1至50,z为约1至50,R = CpH 2 p-( OC2H4)n - (OC3H6)n)m-OR',其中p为约2至5,n为约0至50,N为约0至50,n或m中的一个必须> 0,R' = H,具有1-4个碳原子的烷基或乙酰基,R f = CaH 2 a -Ob-CcH2c-CdF2d + 1,其中a为3或4,b为0或1,c为0或2-4, d为4-12,条件是如果b = 0,则c = 0,如果b = 1,则c = 2-4; z1为约0〜50,y1约为0〜50,可用于降低摩擦系数,提高涂层的耐磨性,增加涂料配方的铺展性和润湿性,以及泡沫控制剂。

    Pulley type speed-shifting device
    10.
    发明授权
    Pulley type speed-shifting device 失效
    滑轮式变速装置

    公开(公告)号:US4969856A

    公开(公告)日:1990-11-13

    申请号:US481050

    申请日:1990-02-16

    IPC分类号: F16H7/08 F16H9/18 F16H63/06

    摘要: In a pulley type speed-shifting device with a belt trained between a pair of variable speed pulleys, a movable sheave of each pulley is driven by a cam mechanism. Each cam mechanism has a cylindrical cam arranged concentrically with a rotary shaft and a cam follower which is arranged concentrically with a rotary shaft and carries a rolling body which makes contact with the cam as it is rolling on a cam face. The movable sheave is driven in axial direction by either the cylindrical cam or the cam follower rotating around the rotary shaft and rotating relatively to the other. As the cam follower makes contact with the cam face through the medium of the rolling body, resistance is small and the transmission ratio can be shifted with light handling force.