摘要:
A polyurea resin composition for RIM or coating use Comprises (a) a polyoxyalkylenepolyamine, (b) an aromatic polyamine and/or a xylylenediamine and (c) a polyisocyanate compound with either one or both of components (a) and (b) having been modified by a Michael reaction with a vinyl monomer having an electron attracting group to convert the primary amino group thereof to a secondary amino group. The composition also contains as an internal mold release a polyoxyalkylene glycol mono-C.sub.4 -C.sub.1, alkyl ether and/or as a polyamine component a reaction product between a primary aromatic polyamine and a polyglycidyl ether.
摘要:
Trifunctional polyoxyalkylene polyamines having a plurality of 2-alkoxycarbonylethylamino groups at terminals are produced by reacting the corresponding primary amines with an alkyl acrylate. The trifunction secondary polyamines thus produced have a moderate reaction rate with a polyisocyanate component in polyurea RIM.
摘要:
A reactive injection molding resinous composition which is excellent in molding, properties and capable of resulting an injection-molded polyurea product having both excellent heat resistance and impact strength is provided, the resinous composition comprising, as polyamine components:(1) a polyoxyalkylene polyamine having an average molecular weight of 1,000-10,000 and 2 or more aliphatic amino groups,(2) a polyoxyalkylene polyamine product (A) obtained by the reaction of a polyoxyalkylene polyepoxy compound having an average molecular weight of 1,000-10,000 and an aromatic diamine having a molecular weight of 108-400,(3) a polyoxyalkylene polyamine product (B) obtained by the reaction of a polyoxyalkylene polyepoxy compound having an average molecular weight of 270-1,000 and an aromatic diamine having a molecular weight of 108-400, and(4) an aromatic diamine having at least one alkyl or thioalkyl substituent at the ortho position of respective amino group and an average molecular weight of 122-400, and as polyisocyanate components,(5) an aromatic polyisocyanate compound having an average molecular weight of 174-1,500,(6) an aliphatic polyisocyanate compound having an average molecular weight of 158-1,500, and(7) a liquid polyisocyanate prepolymer product obtained by the reaction of said (5) or (6) and a liquid polydiene compound having an average molecular weight of 1,000-5,000 and having 2 or more reactive functional groups selected from HD, amino, carboxyl and epoxy groups.
摘要:
Polyoxyalkylene polyamine or aromatic diamines or xylylenediamines are modified by them to the Michael reaction with an ethylenically unsaturated monomer having an electron-withdrawing group to convert the primary amino groups at least in part to a secondary amino group of the formula:--NH--CH.sub.2 --CH(R)--Ywherein R is a hydrogen atom or methyl, and Y is an electron-withdrawing group. The modified amines find use in the manufacture of plastics such as polyurea elastomers or polyurea RIM.
摘要:
A polyurea resin molding composition for RIM use comprising (a) polyoxyalkylenpolyamine having an average molecular weight greater than about 400 and a plurality of terminal primary or secondary amino groups, (b) an aromatic polyamine and/or xylylenediamine and (c) a polyisocyanate. The component (a) contains dispersed therein a polymer prepared by the in situ polymerization of at least two different olefinically unsaturated monomers in the presence of a radical polymerization initiator, the ratio of the average amino equivalent of said polyamines (a) and (b) in combination to the average NCO equivalent of said polyisocyanate (c) being between about 1:0.7 to 1:1.5.
摘要:
A stable polymer dispersion in polyoxyalkylenepolyamine is provided by the in situ polymerization of at two different monomers selected respectively from (a) a first monomer capable of forming a homopolymer which does not precipitate out upon the in situ polymerization and (b) a second monomer capable of forming a homopolymer which precipitates out upon the in situ polymerization. The dispersion is useful as a raw materials of polyurea RIM, forms, elastomers and other products.
摘要:
A polyurea resin molding composition for reaction injection molding use which comprises (a) a polyoxyalkylenepolyamine, (b) an aromatic polyamine and/or a xylylenediamine and (c) a polyisocyanate, wherein either one or both of components (a) and (b) have been modified by a Michael reaction with an unsaturated compound of the formula CH.sub.2 .dbd.C(R)--Y wherein R is H or CH.sub.3 and Y is an electron attracting group. The use of such modified polyamine(s) improves in-mold flow and green strength characteristics.
摘要:
A coating composition which comprises (A) a vinylic monomer-copolymerized resin having a hydroxyl group and a carboxyl group and (B) an alkoxylated amine-formaldehyde condensate as a curing agent for the resin (A). When the coating composition is used as a base coating composition and/or as a clear coating composition in the two coat-one bake coating system, the resulting coating film shows excellent weather resistance with good appearance.
摘要:
In order to reliably form a coating layer on the interior surface of a primary lining such as an underground pipe, etc., in a short time and form a coating layer having a uniform thickness, a spray gun 62 is attached to a revolving ring 30 attached to a running truck 2, right and left drive wheels of the running truck 2 are respectively independently driven and controlled to moving the running truck 2 in a primary lining 90 while the revolving ring 30 is rotated at a steady peripheral velocity to blow out a coating material from the spray gun 62, whereby a homogenous coating layer is formed with a fixed thickness on the interior surface of the primary lining 90.