公开(公告)号：US20100012816A1

公开(公告)日：2010-01-21

申请号：US12568585

申请日：2009-09-28

申请人： Takaki Kuno ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

发明人： Takaki Kuno ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

IPC分类号： B29C33/56

CPC分类号： B29C33/38 ,  B29C33/56 ,  G01N19/04 ,  H01L2224/48091 ,  Y10T428/2839 ,  H01L2924/00014

摘要： A mold surface (6) of an upper mold (1) with which a fluid resin comes into contact has an oxide (3) therein. The oxide (3) contains a metal cation and an ion. Field strength is calculated based on a valence of the metal cation and an ionic radius of the ion. Based on predetermined relationship established between a value of the field strength and adhesion strength between a cured resin and the mold surface (6), releasability between the cured resin and the mold surface (6) is evaluated. Thereby, a method of evaluating releasability between the cured resin and the mold surface (6) is established. With this evaluation method, a material with high releasability (3) can readily be provided. Further, if the material with high releasability (3) is used for the mold surface (6) of the upper mold (1), a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 流体树脂与其接触的上模具（1）的模具表面（6）在其中具有氧化物（3）。 氧化物（3）含有金属阳离子和离子。 基于金属阳离子的价数和离子的离子半径计算场强。 基于在强度值和固化树脂与模具表面（6）之间的粘合强度之间建立的预定关系，评估了固化树脂和模具表面（6）之间的脱模性。 由此，建立了评价固化树脂与模具表面（6）之间的脱模性的方法。 通过该评价方法，可以容易地提供具有高脱模性（3）的材料。 此外，如果将具有高脱模性（3）的材料用于上模（1）的模具表面（6），则可以获得用于模制具有优异的剥离性的树脂的模具。

公开(公告)号：US20110042857A1

公开(公告)日：2011-02-24

申请号：US12914371

申请日：2010-10-28

申请人： Takaki KUNO ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

发明人： Takaki KUNO ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

IPC分类号： B28B7/36

CPC分类号： B29C33/38 ,  B29C33/56 ,  G01N19/04 ,  H01L2224/48091 ,  Y10T428/2839 ,  H01L2924/00014

摘要： A mold surface (6) of an upper mold (1) with which a fluid resin comes into contact has an oxide (3) therein. The oxide (3) contains a metal cation and an ion. Field strength is calculated based on a valence of the metal cation and an ionic radius of the ion. Based on predetermined relationship established between a value of the field strength and adhesion strength between a cured resin and the mold surface (6), releasability between the cured resin and the mold surface (6) is evaluated. Thereby, a method of evaluating releasability between the cured resin and the mold surface (6) is established. With this evaluation method, a material with high releasability (3) can readily be provided. Further, if the material with high releasability (3) is used for the mold surface (6) of the upper mold (1), a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 流体树脂与其接触的上模具（1）的模具表面（6）在其中具有氧化物（3）。 氧化物（3）含有金属阳离子和离子。 基于金属阳离子的价数和离子的离子半径计算场强。 基于在强度值和固化树脂与模具表面（6）之间的粘合强度之间建立的预定关系，评估了固化树脂和模具表面（6）之间的脱模性。 由此，建立了评价固化树脂与模具表面（6）之间的脱模性的方法。 通过该评价方法，可以容易地提供具有高脱模性（3）的材料。 此外，如果将具有高脱模性（3）的材料用于上模（1）的模具表面（6），则可以获得用于模制具有优异的剥离性的树脂的模具。

公开(公告)号：US20080296532A1

公开(公告)日：2008-12-04

申请号：US11920421

申请日：2006-12-27

申请人： Takaki Kuno ,  Yoshinori Noguchi ,  Keiji Maeda ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Masato Yoshiya ,  Seiichi Suda

发明人： Takaki Kuno ,  Yoshinori Noguchi ,  Keiji Maeda ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Masato Yoshiya ,  Seiichi Suda

IPC分类号： C09K3/00 ,  B28B1/00

CPC分类号： B29C33/56 ,  B29C33/60 ,  C04B35/50 ,  C04B35/505 ,  C04B35/645 ,  C04B2235/3213 ,  C04B2235/3225 ,  C04B2235/3227

摘要： A resin molding die has a molding surface formed of a low adhesion material formed of a solid solution of La—Y2O3 produced from Y2O3 and an other oxide of La2O3. La2O3 contains La, which has an ionic radius larger than Y3+, and is larger in basicity than Y2O3. The low adhesion material contains La2O3 at a predetermined ratio relative to a total of Y2O3 and La2O3. The low adhesion material thus has a large iconic radius contributing to a smaller number of sites per unit area than Y2O3, a larger basicity contributing to a smaller force binding the low adhesion material with a basic substance than Y2O3, and a ratio contributing to shape retention. The low adhesion material thus less adhesive and more shape-retentive than Y2O3 configures the molding surface. A low adhesion material that is less adhesive to a basic substance than Y2O3 is and excellently shape-retentive, and an excellently releasable and shape-retentive resin molding die can thus be obtained.

摘要翻译： 树脂成形模具具有由由Y 2 O 3制成的La-Y 2 O 3和La 2 O 3的其它氧化物的固溶体形成的低粘合性材料形成的成型面。 La2O3含有大于Y3 +的离子半径的La，其碱度比Y2O3大。 低粘附性材料相对于Y 2 O 3和La 2 O 3的总量以预定比例含有La 2 O 3。 因此，低粘附性材料具有大的标志性半径，有助于每单位面积比Y2O3更少的位置数，较大的碱度有助于结合低粘合材料与碱性物质比Y2O3更小的力，以及有助于形状保持的比例 。 因此，低粘合性材料因此比Y2O3更少的粘合性和更形状保持性构成了模制表面。 与Y 2 O 3相比，对碱性物质的粘合性较差的低粘合性材料具有良好的保持性，因此可以获得良好的脱模性和形状保持性的树脂成型模具。

公开(公告)号：US20080254286A1

公开(公告)日：2008-10-16

申请号：US10571683

申请日：2005-03-03

申请人： Takaki Kuno ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

发明人： Takaki Kuno ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

IPC分类号： B32B7/06

CPC分类号： B29C33/38 ,  B29C33/56 ,  G01N19/04 ,  H01L2224/48091 ,  Y10T428/2839 ,  H01L2924/00014

摘要： A mold surface of an upper mold with which a fluid resin comes into contact has an oxide therein. The oxide contains a metal cation and an ion. Field strength is calculated based on a valence of the metal cation and ionic radius of the ion. Based on predetermined relationship established between a value of the field strength and adhesion strength between a cured resin and the mold surface, releasability between the cured resin and the mold surface is evaluated. Thereby, a method of evaluating releasability between the cured resin and the mold surface is established. With this evaluation method, a material with high releasability can readily be provided. Further, if the material with high releasability is used for the mold surface of the upper mold, a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 流体树脂与其接触的上模的模具表面具有氧化物。 氧化物含有金属阳离子和离子。 场强基于金属阳离子的价数和离子的离子半径计算。 基于在强度值和固化树脂与模具表面之间的粘合强度之间建立的预定关系，评估固化树脂和模具表面之间的脱模性。 由此，建立了评价固化树脂与模具表面之间的剥离性的方法。 通过该评价方法，可以容易地提供具有高脱模性的材料。 此外，如果将具有高脱模性的材料用于上模的模具表面，则可以获得具有优异的脱模性的树脂模制用模具。

公开(公告)号：US20120076886A1

公开(公告)日：2012-03-29

申请号：US13307768

申请日：2011-11-30

申请人： Takaki KUNO ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

发明人： Takaki KUNO ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

IPC分类号： B29C33/56

CPC分类号： B29C33/38 ,  B29C33/56 ,  G01N19/04 ,  H01L2224/48091 ,  Y10T428/2839 ,  H01L2924/00014

摘要： A mold surface (6) of an upper mold (1) with which a fluid resin comes into contact has an oxide (3) therein. The oxide (3) contains a metal cation and an ion. Field strength is calculated based on a valence of the metal cation and an ionic radius of the ion. Based on predetermined relationship established between a value of the field strength and adhesion strength between a cured resin and the mold surface (6), releasability between the cured resin and the mold surface (6) is evaluated. Thereby, a method of evaluating releasability between the cured resin and the mold surface (6) is established. With this evaluation method, a material with high releasability (3) can readily be provided. Further, if the material with high releasability (3) is used for the mold surface (6) of the upper mold (1), a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 流体树脂与其接触的上模具（1）的模具表面（6）在其中具有氧化物（3）。 氧化物（3）含有金属阳离子和离子。 基于金属阳离子的价数和离子的离子半径计算场强。 基于在强度值和固化树脂与模具表面（6）之间的粘合强度之间建立的预定关系，评估了固化树脂和模具表面（6）之间的脱模性。 由此，建立了评价固化树脂与模具表面（6）之间的脱模性的方法。 通过该评价方法，可以容易地提供具有高脱模性（3）的材料。 此外，如果将具有高脱模性（3）的材料用于上模（1）的模具表面（6），则可以获得用于模制具有优异的剥离性的树脂的模具。

公开(公告)号：US07784764B2

公开(公告)日：2010-08-31

申请号：US11262897

申请日：2005-11-01

申请人： Takaki Kuno ,  Yoshinori Noguchi ,  Keiji Maeda ,  Seiichi Suda ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Masato Yoshiya

发明人： Takaki Kuno ,  Yoshinori Noguchi ,  Keiji Maeda ,  Seiichi Suda ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Masato Yoshiya

IPC分类号： B29C33/38 ,  B32B3/24

CPC分类号： B29C33/60 ,  B29C33/56 ,  B29C45/02 ,  B29C45/37 ,  B29C70/72 ,  Y10T428/12549 ,  Y10T428/1259

摘要： A low-adhesion material containing a rare-earth element is formed as a layer or a film on a mold surface of a mold for molding a resin. A main component of the low-adhesion material is a rare-earth compound, and Y2O3 is used as an example. A content of the rare-earth compound in the low-adhesion material is not less than 40 percent by volume. Thereby, a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 将含有稀土元素的低粘合材料作为层或膜形成在用于模制树脂的模具的模具表面上。 低粘合性材料的主要成分是稀土类化合物，以Y2O3为例。 低粘合性材料中的稀土类化合物的含量为40体积％以上。 由此，能够得到脱模性优异的树脂成形用模具。

公开(公告)号：US07614293B2

公开(公告)日：2009-11-10

申请号：US10571683

申请日：2005-03-03

申请人： Takaki Kuno ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

发明人： Takaki Kuno ,  Keiji Maeda ,  Yoshinori Noguchi ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Seiichi Suda ,  Masato Yoshiya ,  Norio Yamaguchi

IPC分类号： G01N19/04

CPC分类号： B29C33/38 ,  B29C33/56 ,  G01N19/04 ,  H01L2224/48091 ,  Y10T428/2839 ,  H01L2924/00014

摘要： A mold surface of an upper mold with which a fluid resin comes into contact has an oxide therein. The oxide contains a metal cation and an ion. Field strength is calculated based on a valence of the metal cation and ionic radius of the ion. Based on predetermined relationship established between a value of the field strength and adhesion strength between a cured resin and the mold surface, releasability between the cured resin and the mold surface is evaluated. Thereby, a method of evaluating releasability between the cured resin and the mold surface is established. With this evaluation method, a material with high releasability can readily be provided. Further, if the material with high releasability is used for the mold surface of the upper mold, a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 流体树脂与其接触的上模的模具表面具有氧化物。 氧化物含有金属阳离子和离子。 场强基于金属阳离子的价数和离子的离子半径计算。 基于在强度值和固化树脂与模具表面之间的粘合强度之间建立的预定关系，评估固化树脂和模具表面之间的脱模性。 由此，建立了评价固化树脂与模具表面之间的剥离性的方法。 通过该评价方法，可以容易地提供具有高脱模性的材料。 此外，如果将具有高脱模性的材料用于上模的模具表面，则可以获得具有优异的脱模性的树脂模制用模具。

公开(公告)号：US20060093693A1

公开(公告)日：2006-05-04

申请号：US11262897

申请日：2005-11-01

申请人： Takaki Kuno ,  Yoshinori Noguchi ,  Keiji Maeda ,  Seiichi Suda ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Masato Yoshiya

发明人： Takaki Kuno ,  Yoshinori Noguchi ,  Keiji Maeda ,  Seiichi Suda ,  Satoshi Kitaoka ,  Naoki Kawashima ,  Masato Yoshiya

IPC分类号： B29C70/44

CPC分类号： B29C33/60 ,  B29C33/56 ,  B29C45/02 ,  B29C45/37 ,  B29C70/72 ,  Y10T428/12549 ,  Y10T428/1259

摘要： A low-adhesion material containing a rare-earth element is formed as a layer or a film on a mold surface of a mold for molding a resin. A main component of the low-adhesion material is a rare-earth compound, and Y2O3 is used as an example. A content of the rare-earth compound in the low-adhesion material is not less than 40 percent by volume. Thereby, a mold for molding a resin having excellent releasability can be obtained.

摘要翻译： 将含有稀土元素的低粘合材料作为层或膜形成在用于模制树脂的模具的模具表面上。 低附着材料的主要成分是稀土类化合物，作为实例使用Y 2 O 3 O 3。 低粘合性材料中的稀土类化合物的含量为40体积％以上。 由此，能够得到脱模性优异的树脂成形用模具。

公开(公告)号：US08658328B2

公开(公告)日：2014-02-25

申请号：US12934471

申请日：2009-03-26

申请人： Seiichi Suda ,  Kaori Jono ,  Fumio Hashimoto ,  Takayuki Hashimoto

发明人： Seiichi Suda ,  Kaori Jono ,  Fumio Hashimoto ,  Takayuki Hashimoto

IPC分类号： H01M8/24 ,  H01M8/00 ,  H01M8/02

CPC分类号： H01M8/2432 ,  H01M8/0263 ,  H01M8/0276 ,  H01M8/0282 ,  H01M8/0286 ,  H01M8/2404 ,  H01M8/2425 ,  H01M8/2485 ,  H01M2008/1293 ,  Y02P70/56

摘要： A stack structure for a solid oxide fuel cell includes a plurality of stacked single cells, each having a fuel electrode layer including a fuel electrode and an air electrode layer including an air electrode, the fuel electrode layer and the air electrode layer being arranged opposite each other on either side of a solid electrolyte, separators arranged between the stacked single cells to separate the single cells, and non-porous seal parts located within the fuel electrode layer and the air electrode layer, are equivalent to either the separators or the solid electrolyte at least in terms of thermal expansion and contraction characteristics, and are integrated with an edge of the fuel electrode or an edge of the air electrode, and also with the adjacent separator and the adjacent solid electrolyte.

摘要翻译： 固体氧化物型燃料电池用叠层结构体包括多个堆叠单体电池，具有包括燃料电极的燃料电极层和包括空气极的空气极层，多个燃料电极层和空气极层相对配置 另一方面，在固体电解质的两侧，布置在堆叠的单个电池之间以分离单个电池的隔板和位于燃料电极层和空气电极层内的无孔密封部件等同于隔板或固体电解质 至少在热膨胀和收缩特性方面，并且与燃料电极的边缘或空气电极的边缘以及与相邻的隔板和相邻的固体电解质结合。

公开(公告)号：US20110111320A1

公开(公告)日：2011-05-12

申请号：US12934471

申请日：2009-03-26

申请人： Seiichi Suda ,  Kaori Jono ,  Fumio Hashimoto ,  Takayuki Hashimoto

发明人： Seiichi Suda ,  Kaori Jono ,  Fumio Hashimoto ,  Takayuki Hashimoto

IPC分类号： H01M8/24 ,  H01M8/00 ,  H01M8/02

CPC分类号： H01M8/2432 ,  H01M8/0263 ,  H01M8/0276 ,  H01M8/0282 ,  H01M8/0286 ,  H01M8/2404 ,  H01M8/2425 ,  H01M8/2485 ,  H01M2008/1293 ,  Y02P70/56

摘要： A stack structure for a solid oxide fuel cell includes a plurality of stacked single cells, each having a fuel electrode layer including a fuel electrode and an air electrode layer including an air electrode, the fuel electrode layer and the air electrode layer being arranged opposite each other on either side of a solid electrolyte, separators arranged between the stacked single cells to separate the single cells, and non-porous seal parts located within the fuel electrode layer and the air electrode layer, are equivalent to either the separators or the solid electrolyte at least in terms of thermal expansion and contraction characteristics, and are integrated with an edge of the fuel electrode or an edge of the air electrode, and also with the adjacent separator and the adjacent solid electrolyte.

摘要翻译： 固体氧化物型燃料电池用叠层结构体包括多个堆叠单体电池，具有包括燃料电极的燃料电极层和包括空气极的空气极层，多个燃料电极层和空气极层相对配置 另一方面，在固体电解质的两侧，布置在堆叠的单个电池之间以分离单个电池的隔板和位于燃料电极层和空气电极层内的无孔密封部件等同于隔板或固体电解质 至少在热膨胀和收缩特性方面，并且与燃料电极的边缘或空气电极的边缘以及与相邻的隔板和相邻的固体电解质结合。