摘要:
An object of the present invention is to provide a membrane-electrode assembly for solid polymer electrolyte fuel cells, which can impart high electrical properties by increasing the introduction amount of the sulfonic acid group, has excellent swell suppression effect even under the humidified condition of high-temperature, and which has excellent electrical properties even under the condition of high-temperature and low-humidity. By using sulfonated polyarylene having specific constitutional units as a proton conductive membrane, a membrane-electrode assembly for solid polymer electrolyte fuel cells can be provided which has excellent swell suppression effect even under the humidified condition of high-temperature, and which has excellent proton conductivity even under the condition of high-temperature and low-humidity.
摘要:
Disclosed is an electrode electrolyte for solid polymer fuel cells, which uses a polymer electrolyte containing a polyarylene copolymer containing a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —(O(CH2)hSO3H or —O(CF2)hSO3H (wherein h represents an integer of 1-12). By having such a constitution, the electrode electrolyte for solid polymer fuel cells can be produced at a low cost, while being excellent in proton conductivity, dimensional stability, hydrothermal resistance and mechanical strength. In addition, this electrode electrolyte for solid polymer fuel cells enables to recover a catalyst metal.
摘要翻译:公开了一种固体高分子型燃料电池用电极电解质,其使用含有含有-SO 3 H, - (O(CH 2)h SO 3 H或-O(CF 2)h SO 3 H(-O(CH 2)h SO 3 H)表示的取代基的含氮芳香环的聚亚芳基共聚物的聚合物电解质 其中h表示1-12的整数),通过这样构成,能够以低成本制造固体高分子型燃料电池用电极电解质,同时质子传导性,尺寸稳定性,耐水热性和机械强度优异。 此外,用于固体聚合物燃料电池的该电极电解质能够回收催化剂金属。
摘要:
Disclosed is an electrode electrolyte for solid polymer fuel cells, which uses a polymer electrolyte containing a polyarylene copolymer containing a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —(O(CH2)hSO3H or —O(CF2)hSO3H (wherein h represents an integer of 1-12). By having such a constitution, the electrode electrolyte for solid polymer fuel cells can be produced at a low cost, while being excellent in proton conductivity, dimensional stability, hydrothermal resistance and mechanical strength. In addition, this electrode electrolyte for solid polymer fuel cells enables to recover a catalyst metal.
摘要翻译:公开了一种固体高分子型燃料电池用电极电解质,其使用含有含有-SO 3 H, - (O(CH 2)h SO 3 H或-O(CF 2)h SO 3 H(-O(CH 2)h SO 3 H)表示的取代基的含氮芳香环的聚亚芳基共聚物的聚合物电解质 其中h表示1-12的整数),通过这样构成,能够以低成本制造固体高分子型燃料电池用电极电解质,同时质子传导性,尺寸稳定性,耐水热性和机械强度优异。 此外,用于固体聚合物燃料电池的该电极电解质能够回收催化剂金属。
摘要:
A membrane-electrode assembly for a solid polymer electrolyte fuel cell is provided that uses a proton conductive membrane having high proton conductivity and also superior heat resistance and chemical durability. A membrane-electrode assembly for a solid polymer electrolyte fuel cell is provided with an anode on one side of a proton conductive membrane and a cathode on another side thereof, and the proton conductive membrane is a sulfonated polyarylene containing a structure expressed by the general formula (1) below: —Rs—Z—Rh (1) In the formula (1), Z represents at least one structure selected from the group consisting of —CO—, —SO2—, and —SO—; Rs represents a direct bond or any divalent organic group; and Rh represents a nitrogen-containing heterocyclic group.
摘要:
Flow guides forming an inlet channel are formed on a surface of a metal separator of a fuel cell. The flow guides overlap a section of an outer seal provided on the other surface of the metal separator. When a load is applied to the flow guides and the overlapping section in a stacking direction of the fuel cell, the flow guides and the overlapping section are deformed substantially equally in the stacking direction to the same extent. The line pressure of the flow guides and the line pressure of the overlapping section are substantially the same. The seal length L1 of the flow guides and the seal length L2 of the overlapping section are substantially the same.
摘要:
A fuel gas inlet is provided at an outer circumferential edge portion of a second separator. First fuel gas flow passage grooves for supplying a fuel gas to an anode electrode are formed on a side of a surface of the second separator. First fuel gas connecting flow passages, which make communication between the fuel gas inlet and the first fuel gas flow passage grooves, include flow passage lo grooves which are provided on a side of a surface, and through-holes which penetrate through the second separator to make communication with the first fuel gas flow passage grooves. Accordingly, excellent sealing performance is ensured with a simple structure, and it is possible to realize a thin-walled fuel cell.
摘要:
Flow guides forming an inlet channel are formed on a surface of a metal separator of a fuel cell. The flow guides overlap a section of an outer seal provided on the other surface of the metal separator. When a load is applied to the flow guides and the overlapping section in a stacking direction of the fuel cell, the flow guides and the overlapping section are deformed substantially equally in the stacking direction to the same extent. The line pressure of the flow guides and the line pressure of the overlapping section are substantially the same. The seal length L1 of the flow guides and the seal length L2 of the overlapping section are substantially the same.
摘要:
Flow guides forming an inlet channel are formed on a surface of a metal separator of a fuel cell. The flow guides overlap a section of an outer seal provided on the other surface of the metal separator. When a load is applied to the flow guides and the overlapping section in a stacking direction of the fuel cell, the flow guides and the overlapping section are deformed substantially equally in the stacking direction to the same extent. The line pressure of the flow guides and the line pressure of the overlapping section are substantially the same. The seal length L1 of the flow guides and the seal length L2 of the overlapping section are substantially the same.
摘要:
A fuel cell includes a membrane electrode assembly and first and second metal separators sandwiching the membrane electrode assembly. A first cell voltage terminal for detecting a voltage generated in the membrane electrode assembly is formed integrally with an outer region of the first metal separator. The first cell voltage terminal extends outwardly from the first metal separator. A first seal member covers the outer region of the first metal separator, and includes a first extension seal which covers the first cell voltage terminal to a position near a tip end of the first cell voltage terminal.
摘要:
A cell assembly is formed by stacking a first cell and a second cell. In the cell assembly, oxygen-containing gas flow passages are connected in series by an intermediate oxygen-containing gas flow passage, and fuel gas flow passages are connected in series by an intermediate fuel gas flow passage. An additional oxygen-containing gas is supplied to an oxygen-containing gas passage which includes the intermediate oxygen-containing gas flow passage. An additional fuel gas is supplied to a fuel gas passage which includes the intermediate fuel gas flow passage.