公开(公告)号：US5427601A

公开(公告)日：1995-06-27

申请号：US767889

申请日：1991-09-30

申请人： Takashi Harada ,  Yoshihiro Fujiwara ,  Fumio Abe ,  Tsuneaki Ohashi ,  Hiroshige Mizuno ,  Kevin R. Brundage ,  Srinivas H. Swaroop ,  David F. Thompson ,  Raja R. Wusirika ,  David S. Weiss

发明人： Takashi Harada ,  Yoshihiro Fujiwara ,  Fumio Abe ,  Tsuneaki Ohashi ,  Hiroshige Mizuno ,  Kevin R. Brundage ,  Srinivas H. Swaroop ,  David F. Thompson ,  Raja R. Wusirika ,  David S. Weiss

IPC分类号： B22F1/00 ,  B01D53/94 ,  B01J23/86 ,  B22F3/11 ,  B22F5/00 ,  C22C32/00 ,  C22C33/02 ,  C22C38/00 ,  C22C29/12 ,  B22F3/00

CPC分类号： C22C32/0026 ,  B01D53/945 ,  B01J23/862 ,  C22C33/0285 ,  Y02T10/22 ,  Y10T428/12611

摘要： A sintered metal body is disclosed of composition consisting essentially of in weight percent about 5 to 40 Cr, about 2 to 30 Al, 0 to about 5 special metal, 0 to about 4 rare earth oxide additive, and the balance Fe group metal and unavoidable impurities,the composition including at least one component selected from component A and/or component B, component A being special metal, and component B being at least an effective amount of rare earth oxide additive,the special metal being a first special metal component, and optionally, a second special metal component when rare earth oxide additive is 0, the first special metal component consisting of at least one of: Y, lanthanides, Zr, Hf, Ti, Si, and B, and the second special metal component consisting of at least one of: alkaline earth metal, Cu, and Sn, and the special metal being a third special metal component when rare earth oxide additive is >0, the third special metal component consisting of at least one of Y, lanthanides, Zr, Hf, Ti, Si, alkaline earth metal, B, Cu, and Sn.The body is excellent in oxidation resistance at high temperatures, heat resistance, and corrosion resistance, and can be suitably used by itself as a carrier for catalysts, for exhaust gas purification, etc., or as a monolith catalyst comprising catalyst carrier and catalyst supported thereon, and as a heater or catalytic converter by providing electrodes on the body.

摘要翻译： 公开了一种烧结金属体，其组成主要包括重量百分比约5至40 Cr，约2至30种Al，0至约5种特殊金属，0至约4种稀土氧化物添加剂，余量为Fe族金属，不可避免 杂质，所述组合物包含选自组分A和/或组分B中的至少一种组分，组分A为特殊金属，组分B为至少有效量的稀土氧化物添加剂，所述特殊金属为第一特殊金属组分， 以及任选地，当稀土氧化物添加剂为0时的第二特殊金属组分，所述第一特殊金属组分由以下中的至少一种组成：Y，镧系元素，Zr，Hf，Ti，Si和B，并且所述第二特殊金属组分 的碱土金属，Cu和Sn中的至少一种，当稀土氧化物添加剂为> 0时，特殊金属是第三种特殊金属组分，第三种特殊金属组分由Y，镧系元素，Zr中的至少一种组成 ， H f，Ti，Si，碱土金属，B，Cu和Sn。 本体在高温下的耐氧化性，耐热性和耐腐蚀性优异，可以适合用作催化剂载体，废气净化等，或作为包含催化剂载体和催化剂的整料催化剂 以及作为加热器或催化转化器，通过在主体上设置电极。

公开(公告)号：US5292485A

公开(公告)日：1994-03-08

申请号：US955247

申请日：1992-10-01

申请人： Takashi Harada ,  Hiroshige Mizuno ,  Fumio Abe ,  Tsuneaki Ohashi

发明人： Takashi Harada ,  Hiroshige Mizuno ,  Fumio Abe ,  Tsuneaki Ohashi

IPC分类号： B01D39/20 ,  B01J35/00 ,  B01J35/04 ,  B22F3/11 ,  F01N3/20 ,  F01N3/28 ,  H05B3/12 ,  F01N3/10 ,  B21D39/00

CPC分类号： B01D39/2093 ,  B01D39/2034 ,  B01J35/0033 ,  B01J35/04 ,  B22F3/1115 ,  F01N3/2026 ,  F01N3/2803 ,  H05B3/12 ,  B01D2239/0478 ,  B01D2239/10 ,  F01N2330/14 ,  Y02T10/26 ,  Y10T428/12042 ,  Y10T428/12056 ,  Y10T428/1234 ,  Y10T428/12611

摘要： A heat-resistant metallic monolith, manufactured by forming metal powders into a honeycomb structure and by sintering the structure, has a heat-resistant metal oxide coated on the surface of the cell walls and that of the pores thereof. Such a heat-resistant metallic monolith is manufactured by mixing metal powders, an organic binder and water to prepare a mixture, by forming the mixture into a shape of a desired honeycomb configuration, by sintering the shape in a non-oxidizing atmosphere at a temperature between 1000.degree. and 1450.degree. C. and then by coating a heat-resistant metal oxide on a surface of the cell walls and that of the pores of the obtained sintered body.

摘要翻译： 通过将金属粉末形成为蜂窝结构体并通过烧结该结构而制造的耐热金属整体，具有涂覆在孔壁表面和孔的表面上的耐热金属氧化物。 通过将金属粉末，有机粘合剂和水混合以制备混合物，通过将混合物形成为所需蜂窝结构的形状，通过在非氧化性气氛中在温度下烧结形状来制造这种耐热金属整料 在1000度至1450摄氏度之间，然后通过在所述单元壁的表面和所获得的烧结体的孔的表面上涂覆耐热金属氧化物。

公开(公告)号：US5234668A

公开(公告)日：1993-08-10

申请号：US853005

申请日：1992-03-17

申请人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

发明人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  H05B3/12

CPC分类号： F01N3/2053 ,  F01N3/2026 ,  H05B3/12 ,  F01N2330/14 ,  Y02T10/26 ,  Y10S55/30 ,  Y10T428/24149

摘要： A catalytic converter suitable for use in controlling automotive exhaust emissions including honeycomb heaters which are respectively disposed upstream and downstream of a main monolithic catalyst. Each honeycomb heater includes a honeycomb structure with at least two electrodes provided thereon to supply a current to the honeycomb structure.

摘要翻译： 一种适用于控制汽车排气排放的催化转化器，包括蜂窝式加热器，其分别设置在主单片催化剂的上游和下游。 每个蜂窝式加热器包括蜂窝结构，其中设置有至少两个电极以向蜂窝结构提供电流。

公开(公告)号：US5200154A

公开(公告)日：1993-04-06

申请号：US581985

申请日：1990-09-14

申请人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

发明人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  H05B3/03 ,  H05B3/12

CPC分类号： F01N3/2026 ,  H05B3/12 ,  Y02T10/26

摘要： A honeycomb heater having integrally formed and/or integrally sintered electrodes comprises a honeycomb structure having a desired honeycomb configuration, and electrodes which are integrally sintered with the honeycomb structure at predetermined positions thereon. The honeycomb heater having integrally sintered is manufactured by joining or contacting the electrode-like formed bodies to the formed honeycomb body, and then by sintering the formed honeycomb body with the electrode-like formed bodies attached or contacted thereto. The electrodes are made of the same material as that of the honeycomb body, or of a material having an electric resistance lower than that of the material comprising the honeycomb body. Alternatively, the honeycomb heater having integrally formed and integrally sintered electrodes is manufactured by preparing an extrusion of a honeycomb body as one body which has a honeycomb configuration and an electrode-like shape at predetermined positions thereon, and then sintering that formed honeycomb body.

公开(公告)号：US5286460A

公开(公告)日：1994-02-15

申请号：US965013

申请日：1992-10-23

申请人： Fumio Abe ,  Takashi Harada ,  Hiroshige Mizuno

发明人： Fumio Abe ,  Takashi Harada ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  F01N3/24 ,  H05B3/12 ,  F01N3/10 ,  B01D53/36 ,  H05B3/10

CPC分类号： F01N3/2026 ,  H05B3/12 ,  Y02T10/26

摘要： In a catalytic converter operating method according to the present invention, a heater is energized at a predetermined power level or above and thereby heated substantially concurrently with the operation of an engine. During the heating, an oxidizing gas is introduced into the catalytic converter. When the temperature of the heater exceeds a value at which a main catalyst of the catalytic converter or a light-off catalyst carried on the heater functions, the power level is reduced by an output adjuster and supply of the oxidizing gas is suspended.

摘要翻译： 在根据本发明的催化转化器操作方法中，加热器以预定的功率水平或更高的水平通电，从而与发动机的操作基本同时加热。 在加热期间，将氧化气体引入催化转化器。 当加热器的温度超过催化转化器的主催化剂或负载在加热器上的点火催化剂的功能时，通过输出调节器降低功率水平，并且中断氧化气体的供给。

公开(公告)号：US5202547A

公开(公告)日：1993-04-13

申请号：US842964

申请日：1992-02-28

申请人： Fumio Abe ,  Hiroshige Mizuno ,  Takashi Harada ,  Tomoharu Kondo

发明人： Fumio Abe ,  Hiroshige Mizuno ,  Takashi Harada ,  Tomoharu Kondo

IPC分类号： B01J35/00 ,  F01N3/20 ,  F01N3/24 ,  F01N3/28 ,  H05B3/14

CPC分类号： B01J35/0033 ,  F01N3/2026 ,  F01N3/2803 ,  H05B3/14 ,  F01N2330/04 ,  F01N2510/06 ,  Y02T10/26 ,  Y10S55/30 ,  Y10T428/24149

摘要： A resistance adjusting type heater has a honeycomb structure having a large number of passages, at least two electrodes to enable electrical heating of the honeycomb structure provided on the honeycomb structure, and a resistance adjusting means, a slit, provided between the electrodes. The thicknesses of passage walls at the portions of the honeycomb structure at which electricity flows at a very high density are increased with a conductive material to prevent the abnormal heat generation at the portions of the honeycomb structure.

公开(公告)号：US5266278A

公开(公告)日：1993-11-30

申请号：US968670

申请日：1992-10-30

申请人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

发明人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  H05B3/12 ,  F01N3/10 ,  B01D53/36 ,  H05B3/10

CPC分类号： F01N3/2026 ,  H05B3/12 ,  Y02T10/26 ,  Y10S55/30

摘要： A honeycomb heater having integrally formed and/or integrally sintered electrodes constructed of a metallic honeycomb structure having a desired honeycomb configuration, and metallic electrodes which are integrally sintered with the honeycomb structure at predetermined positions thereon. The honeycomb heater having integrally sintered electrodes is manufactured by joining or contacting the electrode-like formed bodies to the formed honeycomb body, and then by sintering the formed honeycomb body with the electrode-like formed bodies attached or contacted thereto. The electrodes are made of the same material as that of the honeycomb body, or of a material having an electric resistance lower than that of the material comprising the honeycomb body. Alternatively, the honeycomb heater having integrally formed and integrally sintered electrodes is manufactured by preparing an extrusion of a honeycomb body as one body which has a honeycomb configuration and an electrode-like shape at predetermined positions thereon, and then sintering that formed honeycomb body.

摘要翻译： 具有由具有所需蜂窝结构的金属蜂窝结构体构成的整体形成和/或整体烧结的电极的蜂窝式加热器以及与蜂窝结构体在其上的预定位置一体烧结的金属电极。 具有整体烧结电极的蜂窝式加热器通过将电极形成体与形成的蜂窝体接合或接触而制成，然后通过将形成的蜂窝体与附着或接触的电极状成形体烧结而形成。 电极由与蜂窝体相同的材料或具有比包含蜂窝体的材料的电阻低的材料制成。 或者，具有整体形成和整体烧结的电极的蜂窝式加热器通过将蜂窝体作为一体在其预定位置上预定的蜂窝结构和电极形状的一体制备，然后烧结形成的蜂窝体来制造。

公开(公告)号：US5264186A

公开(公告)日：1993-11-23

申请号：US581987

申请日：1990-09-14

申请人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

发明人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  F01N3/24 ,  F01N3/28 ,  H05B3/12 ,  B01D53/36

CPC分类号： F01N3/2026 ,  F01N3/2053 ,  H05B3/12 ,  F01N2330/14 ,  Y02T10/26 ,  Y10S55/30

摘要： The catalytic converter includes a first flow passage for an automotive exhaust gas and a second flow passage disposed parallel to the first flow passage to bypass the exhaust gas therethrough. The first flow passage contains a honeycomb heater or a heater catalyst which comprises a honeycomb heater with a catalyst carried thereon. At the beginning of an operation of any engine, the exhaust gas whose temperature is low is caused to flow through the first flow passage. When the temperature of the exhaust gas exceeds a predetermined value, the flow passage is switched from the first passage to the second flow passage.

摘要翻译： 催化转化器包括用于汽车废气的第一流动通道和与第一流动通道平行设置以绕过废气的第二流动通道。 第一流路包含蜂窝式加热器或加热器催化剂，该催化剂包括其上载有催化剂的蜂窝式加热器。 在任何发动机的操作开始时，使温度低的废气流过第一流路。 当废气的温度超过预定值时，流道从第一通道切换到第二流动通道。

公开(公告)号：US5229080A

公开(公告)日：1993-07-20

申请号：US853007

申请日：1992-03-17

申请人： Fumio Abe ,  Takashi Harada ,  Hiroshige Mizuno

发明人： Fumio Abe ,  Takashi Harada ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  H05B3/12

CPC分类号： H05B3/12 ,  F01N3/2026 ,  F01N3/2053 ,  F01N2330/14 ,  Y02T10/26 ,  Y10S55/30

摘要： A resistance adjusting type heater including a honeycomb structure with at least two electrodes provided thereon to supply a current to the honeycomb structure and with resistance adjusting elements provided between the electrodes. The resistance adjusting elements are formed such that a cross-section of a heating portion of the heater is substantially the same as that of a main monolithic catalyst. A catalytic converter includes the resistance adjusting heater which is disposed upstream of a main monolithic catalyst or between main monolithic catalysts. Also, the catalytic converter includes a resistance adjusting heater which is disposed downstream of a main monolithic catalyst. This resistance adjusting heater comprises a honeycomb structure with a catalyst carried thereon, with at least two electrodes provided thereon to supply a current to the honeycomb structure and with a resistance adjusting elements provided between the electrodes. The resistance adjusting elements are formed such that the cross-section of a heating portion of the heater is substantially the same as that of the main monolithic catalyst.

摘要翻译： 一种电阻调节型加热器，包括蜂窝结构，其上设置有至少两个电极，以向蜂窝结构提供电流以及设置在电极之间的电阻调节元件。 电阻调节元件形成为加热器的加热部分的横截面与主要整体式催化剂的截面基本相同。 催化转化器包括设置在主单片催化剂上游或主要整体催化剂之间的电阻调节加热器。 此外，催化转化器还包括电阻调节加热器，其设置在主单片催化剂的下游。 该电阻调节加热器包括其上载有催化剂的蜂窝结构，其上设置有至少两个电极以向蜂窝结构提供电流，并且在电极之间设置电阻调节元件。 电阻调节元件形成为使得加热器的加热部分的横截面与主要整体式催化剂的截面基本相同。

公开(公告)号：US5229079A

公开(公告)日：1993-07-20

申请号：US852508

申请日：1992-03-17

申请人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

发明人： Takashi Harada ,  Fumio Abe ,  Hiroshige Mizuno

IPC分类号： F01N3/20 ,  H05B3/12

CPC分类号： F01N3/2026 ,  F01N3/2053 ,  H05B3/12 ,  F01N2330/14 ,  Y02T10/26 ,  Y10S55/30

摘要： A catalytic converter suitable for use in controlling automotive exhaust emissions including a honeycomb heater disposed downstream of a main monolithic catalyst or between main monolithic catalysts. The honeycomb heater includes a honeycomb structure with a catalyst carried thereon and with at least two electrodes provided thereon to supply a current thereto. A catalytic converter also includes a monolith catalyst for ignition which is disposed downstream of the honeycomb heater. A catalytic converter includes, in place of the honeycomb heater and the monolithic catalyst, a module which is composed of a catalyzed light-off honeycomb heater or of a honeycomb heater and a light-off monolithic catalyst. The module is removably disposed upstream or downstream of a main monolithic catalyst, or between main monolithic catalysts.

摘要翻译： 一种适用于控制汽车废气排放的催化转化器，包括设置在主要整体式催化剂下游或主要整体式催化剂之间的蜂窝式加热器。 蜂窝式加热器包括蜂窝结构，其上载有催化剂，并且在其上设置有至少两个电极以向其提供电流。 催化转化器还包括设置在蜂窝式加热器下游的用于点火的整料催化剂。 催化转化器包括代替蜂窝式加热器和整体式催化剂的由催化的灭火蜂窝式加热器或蜂窝式加热器和点火式整体式催化剂组成的组件。 模块可拆卸地设置在主整体式催化剂的上游或下游，或主要整体式催化剂之间。