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公开(公告)号：US08293827B2
公开(公告)日：2012-10-23
申请号：US12612295
申请日：2009-11-04
IPC分类号： C04B24/26
CPC分类号： C08K3/04 , B60C1/0016 , C08C1/04 , C08J3/20 , C08J2307/02 , C08K3/013 , C08K3/36 , C08L7/00 , C08L89/00 , C08L15/00
摘要： A method for producing a rubber composition, the method including: preparing a modified natural rubber by releasing protein from rubber particles in a natural rubber latex by adding at least one organic compound selected from formaldehyde, paraformaldehyde, formalin, and glyoxal to the above mentioned natural rubber latex and then drying so as to include the released protein therein; and mixing at least one selected from carbon black and silica in this modified natural rubber. Such method reduces viscosity and improves molding processibility of the rubber composition, as well as reducing hysteresis loss.
摘要翻译： 一种橡胶组合物的制造方法，其特征在于，通过向上述天然橡胶中加入至少一种选自甲醛，多聚甲醛，福尔马醛和乙二醛的有机化合物，在天然橡胶胶乳中从橡胶粒子释放蛋白质来制备改性天然橡胶 橡胶胶乳，然后干燥，以便在其中包含释放的蛋白质; 并在该改性天然橡胶中混合选自碳黑和二氧化硅中的至少一种。 这种方法降低了粘度并提高了橡胶组合物的成型加工性，并且降低了滞后损耗。
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公开(公告)号：US20100113684A1
公开(公告)日：2010-05-06
申请号：US12612295
申请日：2009-11-04
IPC分类号： C08L7/00
CPC分类号： C08K3/04 , B60C1/0016 , C08C1/04 , C08J3/20 , C08J2307/02 , C08K3/013 , C08K3/36 , C08L7/00 , C08L89/00 , C08L15/00
摘要： A method for producing a rubber composition, the method including: preparing a modified natural rubber by releasing protein from rubber particles in a natural rubber latex by adding at least one organic compound selected from formaldehyde, paraformaldehyde, formalin, and glyoxal to the above mentioned natural rubber latex and then drying so as to include the released protein therein; and mixing at least one selected from carbon black and silica in this modified natural rubber. Such method reduces viscosity and improves molding processibility of the rubber composition, as well as reducing hysteresis loss.
摘要翻译： 一种橡胶组合物的制造方法，其特征在于，通过向上述天然橡胶中加入至少一种选自甲醛，多聚甲醛，福尔马醛和乙二醛的有机化合物，在天然橡胶胶乳中从橡胶粒子释放蛋白质来制备改性天然橡胶 橡胶胶乳，然后干燥，以便在其中包含释放的蛋白质; 并在该改性天然橡胶中混合选自碳黑和二氧化硅中的至少一种。 这种方法降低了粘度并提高了橡胶组合物的成型加工性，并且降低了滞后损耗。
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3.发明申请RUBBER COMPOSITION CONTAINING MODIFIED CONJUGATED DIENE-BASED POLYMER BONDED TO FULLERENE 失效含有改性共轭二烯基聚合物的橡胶组合物结合到富勒烯公开(公告)号：US20090182069A1
公开(公告)日：2009-07-16
申请号：US12406188
申请日：2009-03-18
CPC分类号： B82Y30/00 , B60C1/00 , C08L19/006
摘要： A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan δ balance.
摘要翻译： 通过在分子中配合含有0.5〜100重量％的具有与其结合的富勒烯的改性共轭二烯系聚合物，重均分子量为50,000以上，优异的加工性的橡胶组合物，优异的平衡性 模量和热积累，优异的冷流动性和优异的tanδ平衡。
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公开(公告)号：US20080146737A1
公开(公告)日：2008-06-19
申请号：US11955216
申请日：2007-12-12
申请人： Makoto Ashiura , Tetsuji Kawazura , Kazuo Arakawa
发明人： Makoto Ashiura , Tetsuji Kawazura , Kazuo Arakawa
IPC分类号： C08L9/00
CPC分类号： C08L23/22 , C08L23/10 , C08L2666/06
摘要： A thermoplastic elastomer composition containing a dynamically cross-linked composition of(A) 10 to 70 parts by weight of a thermoplastic resin,(B) 30 to 90 parts by weight of a modified butyl rubber composition containing a modified butyl rubber modified reacting, to butyl rubber, (a) a compound containing, in the molecule thereof, a nitroxide free radical stable at an ordinary temperature in the presence of oxygen, and (c) a bifunctional or higher functional radical polymerizable monomer, and(C) 0.01 to 15 parts by weight of a cross-linking agent.
摘要翻译： 一种热塑性弹性体组合物，其含有（A）10〜70重量份热塑性树脂的动态交联组合物，（B）30〜90重量份含有改性丁基橡胶改性反应的改性丁基橡胶组合物， 丁基橡胶，（a）在氧分子中含有在常温下在氧的存在下稳定的氮氧自由基的化合物，（c）双官能以上的官能团的可自由基聚合的单体，（C）0.01〜15 重量份的交联剂。
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公开(公告)号：US20110086981A1
公开(公告)日：2011-04-14
申请号：US12751661
申请日：2010-03-31
申请人： Makoto Ashiura , Tetsuji Kawazura
发明人： Makoto Ashiura , Tetsuji Kawazura
IPC分类号： C08C19/28
CPC分类号： C08J7/16 , B29D30/0654 , B29D2030/0655 , C08J3/245 , C08J3/247 , C08J7/08 , C08J2321/00 , C08J2323/22
摘要： A manufacturing method for a surface-modified rubber molded body is described. An uncross-linked rubber molded body is made of a rubber composition containing an organic peroxide and a modified butyl rubber composition (A) containing a modified butyl rubber (1) where a compound (a) with a stable nitroxide free radical in the molecule at ambient temperature in the presence of oxygen, a radical initiator (b), and a radical polymeric monomer (c) with at least difunctionality are reacted with butyl rubber, or a modified butyl rubber composition (B) where the monomer (c) is added to a modified butyl rubber (2) where the compound (a) and the radical initiator (b) are reacted with butyl rubber. A siloxane compound having a (meth)acryloyl group is applied onto the surface of the uncross-linked rubber molded body. The uncross-linked rubber molded body is then heat-treated.
摘要翻译： 对表面改性橡胶成形体的制造方法进行说明。 未交联的橡胶成型体由含有有机过氧化物和含有改性丁基橡胶（1）的改性丁基橡胶组合物（A）的橡胶组合物制成，其中化合物（a）在分子中具有稳定的氮氧自由基 在氧存在下的环境温度，自由基引发剂（b）和至少具有双官能团的自由基聚合单体（c）与丁基橡胶或其中加入单体（c）的改性丁基橡胶组合物（B）反应 与化合物（a）和自由基引发剂（b）与丁基橡胶反应的改性丁基橡胶（2）。 将具有（甲基）丙烯酰基的硅氧烷化合物施加到未交联的橡胶成型体的表面上。 然后对未交联的橡胶成型体进行热处理。
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6.发明申请公开(公告)号：US20090292044A1
公开(公告)日：2009-11-26
申请号：US12307658
申请日：2007-07-03
申请人： Tetsuji Kawazura , Makoto Ashiura
发明人： Tetsuji Kawazura , Makoto Ashiura
IPC分类号： C08J5/14 , C08F136/02 , C08F136/08 , C08F136/06 , C08F136/14
CPC分类号： C08C19/28 , B60C1/0016 , C08C19/22 , C08F8/30 , C08F279/02 , C08K3/013 , C08K3/36 , C08L15/00 , C08L21/00 , C08L2666/08
摘要： To modify a diene-based rubber whereby the dispersibility of silica and the abrasion resistance or heat buildup resistance are improved.A modified diene-based rubber obtained by adding and reacting, to a diene-based rubber (A), a compound (B) having, in the molecule thereof, a nitroxide free radical stable at an ordinary temperature and in the presence of oxygen, a radical initiator (C) and a radical polymerizable monomer (D) having a functional group in the molecule thereof and a rubber composition and pneumatic tire containing the same.
摘要翻译： 改性二烯系橡胶，由此提高二氧化硅的分散性和耐磨损性或耐热集聚性。 通过向二烯类橡胶（A），在分子中具有在常温下和氧气存在下稳定的氮氧自由基的化合物（B）加成反应而得到的改性二烯系橡胶， 自由基引发剂（C）和在其分子中具有官能团的自由基聚合性单体（D）和含有该自由基引发剂的橡胶组合物和充气轮胎。
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公开(公告)号：US07589155B2
公开(公告)日：2009-09-15
申请号：US11583722
申请日：2006-10-20
申请人： Makoto Ashiura , Tetsuji Kawazura
发明人： Makoto Ashiura , Tetsuji Kawazura
IPC分类号： C08F251/00
CPC分类号： C08F8/30 , C08F255/10 , C08K5/32 , C08K5/3412 , C08L23/36 , C08L51/04 , C08L51/06 , C08F210/12 , C08L23/22 , C08L2666/02
摘要： A modified butyl rubber composition including a modified butyl rubber obtained by reacting a compound (a) having, in its molecule, a nitroxide free radical stable at an ordinary temperature in the presence of oxygen, a radical initiator (b), and a bifunctional or higher radical polymerizable monomer (c) or a modified butyl rubber composition containing a modified butyl rubber, obtained by reacting a compound (a) having, in its molecule, a nitroxide free radical stable at ordinary temperature in the presence of oxygen and a radical initiator (b), into which a bi- or more-functional radical polymerizable monomer (c) is compounded.
摘要翻译： 一种改性丁基橡胶组合物，其包含通过在其分子中具有在常温下在氧气存在下稳定的氮氧自由基的化合物（a），自由基引发剂（b）和双官能或 高分子自由基聚合性单体（c）或含有改性丁基橡胶的改性丁基橡胶组合物，其通过使在其分子中具有在常温下在氧气和自由基引发剂中具有稳定的氮氧自由基的化合物（a） （b），其中复合了双官能或更多官能的可自由基聚合单体（c）。
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公开(公告)号：US20060155079A1
公开(公告)日：2006-07-13
申请号：US11329082
申请日：2006-01-11
申请人： Makoto Ashiura , Tetsuji Kawazura
发明人： Makoto Ashiura , Tetsuji Kawazura
IPC分类号： C08F10/00
CPC分类号： C08F8/50 , C08F210/12
摘要： A method for modifying a polymer comprising modifying a polymer capable of decomposing with a carbon radical in the molecule thereof by a reaction with a radical initiator and a compound having a nitroxide radical in the molecule thereof to thereby decrease a molecular weight of the polymer and also to thereby introduce an organic group derived from the free radical into the polymer.
摘要翻译： 一种改性聚合物的方法，包括通过与自由基引发剂的反应和在分子中具有硝基氧基的化合物的反应来改变分子中能够用碳自由基分解的聚合物，从而降低聚合物的分子量， 从而将衍生自自由基的有机基团引入到聚合物中。
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公开(公告)号：US06653409B2
公开(公告)日：2003-11-25
申请号：US10080590
申请日：2002-02-25
申请人： Makoto Ashiura , Keisuke Chino , Tetsuji Kawazura
发明人： Makoto Ashiura , Keisuke Chino , Tetsuji Kawazura
IPC分类号： C08F830
CPC分类号： B60C1/00 , C08C19/44 , C08F257/02 , C08F291/00 , C08F293/005 , C08F295/00 , C08L51/003 , C08L53/02
摘要： A radical-modified polymer having a free radical compound stable in the presence of oxygen at an ordinary temperature at the end of the molecule thereof or in the molecular chain thereof and a polymer composition containing the same.
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公开(公告)号：US06642291B2
公开(公告)日：2003-11-04
申请号：US09859488
申请日：2001-05-18
IPC分类号： C08G6348
CPC分类号： C08K5/32 , B60C1/00 , C08K5/3435 , C08L21/00
摘要： A viscoelasticity improving agent for rubber obtained by reacting an alkyllithium compound with a free radical compound having an isocyanate group in the molecule thereof and existing stably at room temperature in the presence of oxygen and a rubber composition.
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