公开(公告)号：US06677044B2

公开(公告)日：2004-01-13

申请号：US09423895

申请日：1999-11-16

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC分类号： B32B1508

CPC分类号： C08F214/184 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31547 ,  Y10T428/31678

摘要： A composite material having sliding property is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above. The composite material having sliding property which is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.

摘要翻译： 通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料，制造具有滑动性的复合材料，该材料通过（a）将0.05〜30摩尔％的含氟乙烯性聚合物 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。 具有滑动性的复合材料，其通过向基材施加包含具有优异的粘附性的含氟聚合物的材料而不需要复杂的步骤而制备。

公开(公告)号：US06737164B2

公开(公告)日：2004-05-18

申请号：US09380499

申请日：1999-09-03

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC分类号： B32B2708

CPC分类号： A47J36/02 ,  C08F214/20 ,  C08F216/04 ,  C08F220/00 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544

摘要： Composite materials for cooking apparatuses which are produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and are excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain-removing property, chemical resistance, rust-preventing property, antibacterial property, resistance to energy ray and abrasion resistance. The composite materials for cooking apparatuses are produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

摘要翻译： 用于烹饪设备的复合材料是通过向衬底施加包含具有优异粘合性的含氟聚合物的材料而制成的，而不需要复杂的步骤，并且具有优异的耐热性，不粘附性，防污染性 性能，防油和排斥性能，去污性，耐化学腐蚀性，防锈性，抗菌性，耐光能和耐磨性。 用于烹饪设备的复合材料是通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料制造的，所述官能团通过使（a）0.05〜30摩尔％的含氟乙烯性聚合物中的至少一种 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。

公开(公告)号：US06716497B2

公开(公告)日：2004-04-06

申请号：US09424084

申请日：1999-11-19

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC分类号： B32B1710

CPC分类号： B32B17/10018 ,  B32B7/06 ,  B32B15/08 ,  B32B15/20 ,  B32B17/10036 ,  B32B27/08 ,  B32B27/281 ,  B32B27/322 ,  B32B2307/306 ,  C03C17/32 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/1321 ,  Y10T428/3154 ,  Y10T428/31544

摘要： A heat resistant scattering-preventing composite material is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have said functional group. The heat resistant scattering-preventing composite material is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.

摘要翻译： 通过向基材施加包含具有官能团的含氟乙烯性聚合物的材料来制造耐热防散性复合材料，所述官能团通过使（a）0.05〜30摩尔％的氟 - 含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的烯属单体，和（b）70〜99.95摩尔％的含氟乙烯基 不具有所述官能团的单体。 耐热防散射复合材料通过向基材施加包含具有优异的粘合性的含氟聚合物的材料而不需要复杂的步骤来制备。

公开(公告)号：US06645555B1

公开(公告)日：2003-11-11

申请号：US09476360

申请日：2000-01-03

申请人： Takayuki Araki ,  Hisato Sanemasa ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Hisato Sanemasa ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

IPC分类号： B05D136

CPC分类号： C09D127/12 ,  C08F214/18 ,  C08L27/12 ,  C08L2205/02 ,  C09D127/18 ,  C08L2666/04

摘要： To provide a fluorine-containing coating material which gives excellent adhesive strength directly to a substrate such as metal, glass, etc. with maintaining excellent characteristics of the fluorine-containing polymer such as thermal resistance, chemical resistance, non-sticking property and low friction property, and a method for coating the material. The fluorine-containing coating material is prepared by using a fluorine-containing ethylenic polymer having functional group which is obtained by copolymerizing (a-1) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having any one of functional groups selected from hydroxyl, carboxyl, carboxylate salt group, carboxylate ester group or epoxy and (b-1) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

摘要翻译： 为了提供一种含氟涂层材料，其具有优异的粘合强度，直接地保持诸如金属，玻璃等的基底，同时保持含氟聚合物的优异特性，如耐热性，耐化学性，不粘附性和低摩擦 性质和涂覆材料的方法。 含氟涂料通过使用具有官能团的含氟乙烯性聚合物制备，所述含氟乙烯性聚合物通过使（a-1）0.05〜30摩尔％的至少一种含有任意一种官能团的含氟乙烯性单体 选自羟基，羧基，羧酸盐基团，羧酸酯基或环氧基的基团和（b-1）70〜99.95摩尔％的上述无官能团的含氟乙烯性单体中的至少一种。

公开(公告)号：US06500537B1

公开(公告)日：2002-12-31

申请号：US09423045

申请日：2000-01-21

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC分类号： B32B2732

CPC分类号： G03G15/0233 ,  C08F214/184 ,  C09D127/18 ,  C09J127/12 ,  G03G15/1685 ,  G03G15/2057 ,  Y10T428/2878 ,  Y10T428/3154 ,  Y10T428/31931

摘要： A non-sticking composite material for office automation equipment which is produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and is excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain removing property, chemical resistance, rust-preventive property, antibacterial property, resistance to energy ray and abrasion resistance. The non-sticking composite material for office automation equipment is produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group.

摘要翻译： 一种用于办公自动化设备的不粘合复合材料，其通过向基材施加包含具有优异粘合性的含氟聚合物的材料而不需要复杂的步骤并且具有优异的耐热性，不粘附性 防污性，防油斥性，除污性，耐化学腐蚀性，防锈性，抗菌性，耐光能耐受性和耐磨性。 办公自动化设备用的不粘合复合材料是通过将具有官能团的含氟乙烯性聚合物的材料应用于基材而制造的，该材料通过以下方法制备：（a）将0.05〜30摩尔％ 含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的含氟乙烯性单体，和（b）70〜99.95摩尔％的氟 - 含有不具有官能团的烯属单体。

公开(公告)号：US6069215A

公开(公告)日：2000-05-30

申请号：US77939

申请日：1998-06-05

申请人： Takayuki Araki ,  Hisato Sanemasa ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Hisato Sanemasa ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

IPC分类号： B05D1/36 ,  B05D7/00 ,  B05D7/14 ,  C08F214/18 ,  C08L27/12 ,  C09D5/03 ,  C09D127/12 ,  C09D127/18 ,  C08F18/20

CPC分类号： C09D127/12 ,  C08F214/18 ,  C09D127/18 ,  C08L2205/02 ,  C08L27/12

摘要： To provide a fluorine-containing coating material which gives excellent adhesive strength directly to a substrate such as metal, glass, etc. with maintaining excellent characteristics of the fluorine-containing polymer such as thermal resistance, chemical resistance, non-sticking property and low friction property, and a method for coating the material. The fluorine-containing coating material is prepared by using a fluorine-containing ethylenic polymer having functional group which is obtained by copolymerizing (a-1) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having any one of functional groups selected from hydroxyl, carboxyl, carboxylate salt group, carboxylate ester group or epoxy and (b-1) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

摘要翻译： PCT No.PCT / JP96 / 03575 Sec。 371日期：1998年6月5日 102（e）1998年6月5日PCT 1996年12月5日PCT PCT。 公开号WO97 / 21776 日期：1996年6月19日为了提供一种含氟涂层材料，其具有优异的粘合强度，直接对诸如金属，玻璃等的基底，同时保持含氟聚合物的良好特性，例如耐热性，耐化学性， 粘着性和低摩擦性，以及涂布材料的方法。 含氟涂料通过使用具有官能团的含氟乙烯性聚合物制备，所述含氟乙烯性聚合物通过使（a-1）0.05〜30摩尔％的至少一种含有任意一种官能团的含氟乙烯性单体 选自羟基，羧基，羧酸盐基团，羧酸酯基或环氧基的基团和（b-1）70〜99.95摩尔％的上述无官能团的含氟乙烯性单体中的至少一种。

公开(公告)号：US06207236B1

公开(公告)日：2001-03-27

申请号：US09202592

申请日：1998-12-17

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

IPC分类号： B05D302

CPC分类号： C09D127/12 ,  C09D127/18 ,  C08L2666/54

摘要： To provide the water-repellent coating film having excellent transparency, abrasion resistance, weather resistance and water repellency, the method for producing the coating film, the multi-functional composite material provided with the coating film and the coating composition used therefor which has excellent dispersion stability. The coating composition comprises (A) the fluorine-containing ethylenic polymer prepared by copolymerizing a fluorine-containing ethylenic monomer having at least one functional group selected from hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, (B-1) the metal oxide sol, and (C) the solvent.

摘要翻译： 为了提供具有优异的透明性，耐磨性，耐候性和防水性的防水涂膜，涂膜的制备方法，设置有涂膜的多功能复合材料及其所用的涂料组合物具有优异的分散性 稳定性。 涂料组合物包含（A）通过共聚含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的含氟乙烯性单体制备的含氟乙烯性聚合物（B-1 ）金属氧化物溶胶，和（C）溶剂。

公开(公告)号：US06713183B2

公开(公告)日：2004-03-30

申请号：US09077941

申请日：1998-06-05

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Tetsuo Shimizu

IPC分类号： B32B2708

CPC分类号： B32B17/06 ,  B32B7/12 ,  C08F214/267 ,  C09J127/12 ,  C09J127/16 ,  C09J127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31699

摘要： To provide a fluorine-containing adhesive which maintains thermal resistance, chemical resistance, weather resistance and electric insulating property and has strong adhesive property directly to substrates particularly metal and glass, and an adhesive film and laminated article which are obtained by using the fluorine-containing adhesive. There is used a fluorine-containing ethylenic polymer having hydroxyl which is prepared by copolymerizing 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having hydroxyl and 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers copolymerizable with the above-mentioned monomer.

摘要翻译： 提供一种维持耐热性，耐化学性，耐候性和电绝缘性的含氟粘合剂，并且具有与基材（特别是金属和玻璃）直接粘合性强的粘合剂，以及通过使用含氟 胶粘剂。 使用具有羟基的含氟乙烯性聚合物，其通过使0.05〜30摩尔％的含有羟基的含氟乙烯性单体和70〜99.95摩尔％的至少一种含氟乙烯性 可与上述单体共聚的单体。

公开(公告)号：US07455934B1

公开(公告)日：2008-11-25

申请号：US09700185

申请日：1999-05-10

申请人： Takayuki Araki ,  Noritoshi Oka ,  Yoshito Tanaka ,  Takayuki Nakamura ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Noritoshi Oka ,  Yoshito Tanaka ,  Takayuki Nakamura ,  Tetsuo Shimizu

IPC分类号： H01M10/08

CPC分类号： H01S5/22 ,  C08J5/2237 ,  C08J2327/12 ,  G02B2006/12097 ,  G02B2006/12176 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067 ,  H01S5/0655 ,  H01S5/20 ,  H01S5/2004 ,  H01S5/2213 ,  H01S5/2218 ,  H01S5/2227

摘要： The invention is a material for a solid polyelectrolyte, comprising a multi-segmented fluoropolymer that comprises a block copolymer and/or a graft copolymer, wherein the copolymer contains one or more blocks essentially consisting of segment A and one or more blocks essentially consisting of segment B, the segment A combines with the segment B, wherein the segment A has a molecular weight of 5,000 to 1,000.000, and the Segment A is a copolymer chain comprising (a) an ethylenicfluoromonomer containing sulfonic acid functional groups each represented by Formula (1) CX2═CX1—(O)n—Rf—SO2Y, wherein X and X1 may be the same or different and are each hydrogen or fluorine; Y is FI, Cl, or OY1 wherein y1 is hydrogen, alkali metal or C1-C5 alkyl; Rf is C1 to C40 divalent fluoroalkylene or C1 to C40 divalent fluoroalkylene having one or more ether bonds; and n is 0 or 1; and (b) at least one type of ethylenic fluoromonomer copolymerizable with the ethylenic fluoromonomer (a) and containing no sulfonic acid functional groups, the segment B is a fluoropolymer containing no sulfonic acid functional groups, has a molecular weight of 3,000 to 1,200,000, and has a crystalline melting point of 100° C. or higher or a glass transition point of 100° C. or higher, wherein the ratio of segment A:segment B in the segmented fluoropolymer is 5:9˜to 98:2 30:70 to 90:10 wt. %.

摘要翻译： 本发明是用于固体聚电解质的材料，其包含多段含氟聚合物，其包含嵌段共聚物和/或接枝共聚物，其中所述共聚物含有一个或多个基本上由片段A组成的嵌段和一个或多个基本上由片段 B，段A与段B结合，其中段A的分子量为5,000〜1,000.000，段A为共聚物链，其包含（a）含有各自由式（1）表示的磺酸官能团的烯键式氟单体， CX 2 - - - - - - - - - - - - - - - - - - - - - - - - - - - - （O） SUP> 1可以相同或不同，分别为氢或氟; Y是FI，Cl或OY 1，其中y 1是氢，碱金属或C 1 -C 5 烷基; Rf是C 1至C 40二价氟代亚烷基或C 1至C 40二价氟代亚烷基，其具有一个或多个醚 债券 并且n为0或1; 和（b）至少一种可与烯属含氟单体（a）共聚并且不含磺酸官能团的烯属含氟单体，段B是不含磺酸官能团的含氟聚合物，分子量为3,000至1,200,000， 具有100℃以上的结晶熔点或100℃以上的玻璃化转变温度，其中分段含氟聚合物中A段：B段的比例为5:9〜98:2 30:70 至90:10重量 ％。

公开(公告)号：US08754140B2

公开(公告)日：2014-06-17

申请号：US12272226

申请日：2008-11-17

申请人： Takayuki Araki ,  Noritoshi Oka ,  Yoshito Tanaka ,  Takayuki Nakamura ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Noritoshi Oka ,  Yoshito Tanaka ,  Takayuki Nakamura ,  Tetsuo Shimizu

IPC分类号： H01M6/18

CPC分类号： H01S5/22 ,  C08J5/2237 ,  C08J2327/12 ,  G02B2006/12097 ,  G02B2006/12176 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067 ,  H01S5/0655 ,  H01S5/20 ,  H01S5/2004 ,  H01S5/2213 ,  H01S5/2218 ,  H01S5/2227

摘要： A material for solid polyelectrolytes which comprises a polymer comprising two or more fluoropolymer segments differing in monomer composition, wherein at least one of the fluoropolymer segments has sulfonic acid type functional groups.

摘要翻译： 一种用于固体聚电解质的材料，其包含包含两个或更多个单体组成不同的含氟聚合物链段的聚合物，其中至少一个含氟聚合物链段具有磺酸型官能团。