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公开(公告)号：US20050065255A1
公开(公告)日：2005-03-24
申请号：US10504170
申请日：2003-02-17
CPC分类号： H05K1/0373 , C08G61/08 , C08L65/00 , H05K2201/0158 , H05K2201/0209 , H05K2201/0239
摘要： It is an object of the present invention to provide a polymerizable composition and a cured resin composition, linear expansion coefficients of which are significantly improved without impairment of the excellent properties such as heat resistance, mechanical strength and the like of norbornene-based resins. The present invention is a polymerizable composition, which comprises a polymerizable substance containing a norbornene-based monomer or oligomer as a main component, a metathesis polymerization catalyst and silica powder, the weight content of the silica powder being larger than the weight content of the polymerizable substance.
摘要翻译： 本发明的目的是提供一种可聚合组合物和固化树脂组合物，线性膨胀系数显着提高，而不损害降冰片烯系树脂的耐热性，机械强度等优异性能。 本发明是一种聚合性组合物，其含有以降冰片烯系单体或低聚物为主要成分的聚合性物质，易位聚合催化剂和二氧化硅粉末，二氧化硅粉末的重量含量大于可聚合的 物质。
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公开(公告)号：US06977284B2
公开(公告)日：2005-12-20
申请号：US10504170
申请日：2003-02-17
CPC分类号： H05K1/0373 , C08G61/08 , C08L65/00 , H05K2201/0158 , H05K2201/0209 , H05K2201/0239
摘要： It is an object of the present invention to provide a polymerizable composition and a cured resin composition, linear expansion coefficients of which are significantly improved without impairment of the excellent properties such as heat resistance, mechanical strength and the like of norbornene-based resins. The present invention is a polymerizable composition, which comprises a polymerizable substance containing a norbornene-based monomer or oligomer as a main component, a metathesis polymerization catalyst and silica powder, the weight content of the silica powder being larger than the weight content of the polymerizable substance.
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3.发明授权ORGANOMETALLIC COMPOUND HAVING HIGH METATHESIS ACTIVITY AND METHOD FOR PREPARATION THEREOF, METHATHESIS REACTION CATALYST COMPRISING THE COMPOUND, METHOD OF POLYMERIZATION USING THE CATALYST, AND POLYMER PRODUCED BY THE METHOD OF POLYMERIZATION 失效具有高金属活性的有机化合物及其制备方法，包含该化合物的甲硫氨酸反应催化剂，使用催化剂的聚合方法和通过聚合方法生产的聚合物公开(公告)号：US06888018B2
公开(公告)日：2005-05-03
申请号：US10363045
申请日：2001-08-20
申请人： Takeharu Morita , Hiroshi Hiraike , Nobuhiro Goto , Masafumi Nakatani , Fumiyuki Ozawa , Hiroyuki Katayama
发明人： Takeharu Morita , Hiroshi Hiraike , Nobuhiro Goto , Masafumi Nakatani , Fumiyuki Ozawa , Hiroyuki Katayama
CPC分类号： C08G61/08 , C07F15/002 , C07F15/0046
摘要： The present invention provides an organometallic compound represented by the general formula (1) or (2), process for producing the same, metathesis reaction catalyst containing the same, polymerization process using the same catalyst and polymer produced by the same polymerization process:
摘要翻译： 本发明提供由通式（1）或（2）表示的有机金属化合物，其制备方法，含有该有机金属化合物的复分解反应催化剂，使用相同催化剂的聚合方法和通过相同聚合方法制备的聚合物：
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4.发明申请Thermoplastic saturated norbornene based resin film, and method for producing thermoplastic saturated norbornene based resin film 审中-公开热塑性饱和降冰片烯系树脂膜，以及热塑性饱和降冰片烯系树脂膜的制造方法公开(公告)号：US20060036033A1
公开(公告)日：2006-02-16
申请号：US10530172
申请日：2003-10-03
申请人： Katsunori Toyoshima , Takeharu Morita , Hiroshi Hiraike , Masakatsu Tagami , Kentaro Ogino , Katsumi Nishimura
发明人： Katsunori Toyoshima , Takeharu Morita , Hiroshi Hiraike , Masakatsu Tagami , Kentaro Ogino , Katsumi Nishimura
CPC分类号： C08J5/18 , C08J2365/00 , C08L19/00 , C08L21/00 , C08L23/10 , C08L25/10 , C08L45/00 , C08L53/00 , C08L65/00 , C08L2666/08 , C08L2666/04 , C08L2666/06
摘要： It is an object of the invention to provide a thermoplastic saturated norbornene resin film, an optical film, a protective film for a polarizer, a retardation film, a polarizing plate obtainable by this, which realizes the compatibility between excellent physical properties and optical characteristics, and a method of producing a thermoplastic saturated norbornene resin film. The invention relates to a thermoplastic saturated norbornene resin film, which is obtainable by using a thermoplastic saturated norbornene resin composition containing a thermoplastic saturated norbornene resin in an amount of 100 parts by weight and a rubber polymer in an amount of 5 to 40 parts by weight, parallel transmittance being 87% or more.
摘要翻译： 本发明的目的是提供一种热塑性饱和降冰片烯树脂膜，光学膜，偏振片用保护膜，延迟膜，可获得的偏振片，其实现了优异的物理性质和光学特性之间的相容性， 以及制造热塑性饱和降冰片烯树脂膜的方法。 本发明涉及一种热塑性饱和降冰片烯树脂膜，其可通过使用含有100重量份的热塑性饱和降冰片烯树脂的热塑性饱和降冰片烯树脂组合物和5至40重量份的橡胶聚合物 ，平行透射率为87％以上。
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公开(公告)号：US08063163B2
公开(公告)日：2011-11-22
申请号：US12093801
申请日：2005-11-24
申请人： Wilfried Hatke , Matthias Bruch , Anne-Meike Schauwienold , Udo Manfred Stehling , Hiroyuki Kanai , Hajime Serizawa , Hiroshi Hiraike , Takahiko Sawada , Kazunari Yagi , Isao Higuchi , Katsunori Toyoshima , Takeharu Morita
发明人： Wilfried Hatke , Matthias Bruch , Anne-Meike Schauwienold , Udo Manfred Stehling , Hiroyuki Kanai , Hajime Serizawa , Hiroshi Hiraike , Takahiko Sawada , Kazunari Yagi , Isao Higuchi , Katsunori Toyoshima , Takeharu Morita
IPC分类号： C08F232/08 , C08K5/20 , C08K5/10 , C08F4/642
CPC分类号： C08F210/02 , C08F232/08 , C08K5/0016 , C08L23/0823 , C08F232/00 , C08F2500/25 , C08F2500/12 , C08F2500/26
摘要： A novel cycloolefin copolymer that can be employed in the production of molding with fewer defects, for example, fewer gel particles (fish eyes). There is provided a cycloolefin copolymer comprising 80 to 20 mol % of repeating units derived from an α-olefin monomer and 20 to 80 mol % of repeating units derived from at least one cycloolefin monomer selected from the group consisting of monomer of the general formula (I), monomer of the general formula (II), monomer of the general formula (III), monomer of the general formula (IV) and monomer of the general formula (V), wherein with respect to the repeating units derived from cycloolefin monomer, the proportion thereof being present in the form of dimer (Rd) is 50 mol % or below and the proportion thereof being present in the form of trimer (Rt) 5 mol % or above.
摘要翻译： 一种新型的环烯烃共聚物，其可用于生产具有较少缺陷的模制品，例如较少的凝胶颗粒（鱼眼）。 提供一种环烯烃共聚物，其包含80〜20摩尔％的来源于α-烯烃单体的重复单元和20〜80摩尔％的来源于至少一种环烯烃单体的重复单元，所述环烯烃单体选自通式（ I），通式（II）的单体，通式（III）的单体，通式（IV）的单体和通式（V）的单体），其中相对于衍生自环烯单体的重复单元 ，其比例以二聚体（Rd）的形式存在，为50摩尔％以下，其比例以3摩尔％以上的三聚体（Rt）的形式存在。
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公开(公告)号：US20090163632A1
公开(公告)日：2009-06-25
申请号：US12093801
申请日：2005-11-24
申请人： Wilfried Hatke , Matthias Bruch , Anne-Meike Schauwienold , Udo Manfred Stehling , Hiroyuki Kanai , Hajime Serizawa , Hiroshi Hiraike , Takahiko Sawada , Kazunari Yagi , Isao Higuchi , Katsunori Toyoshima , Takeharu Morita
发明人： Wilfried Hatke , Matthias Bruch , Anne-Meike Schauwienold , Udo Manfred Stehling , Hiroyuki Kanai , Hajime Serizawa , Hiroshi Hiraike , Takahiko Sawada , Kazunari Yagi , Isao Higuchi , Katsunori Toyoshima , Takeharu Morita
IPC分类号： C08K5/10 , C08F132/08 , C08K5/20 , C08L55/00
CPC分类号： C08F210/02 , C08F232/08 , C08K5/0016 , C08L23/0823 , C08F232/00 , C08F2500/25 , C08F2500/12 , C08F2500/26
摘要： A novel cycloolefin copolymer that can be employed in the production of molding with fewer defects, for example, fewer gel particles (fish eyes). There is provided a cycloolefin copolymer comprising 80 to 20 mol % of repeating units derived from an α-olefin monomer and 20 to 80 mol % of repeating units derived from at least one cycloolefin monomer selected from the group consisting of monomer of the general formula (I), monomer of the general formula (II), monomer of the general formula (III), monomer of the general formula (IV) and monomer of the general formula (V), wherein with respect to the repeating units derived from cycloolefin monomer, the proportion thereof being present in the form of dimer (Rd) is 50 mol % or below and the proportion thereof being present in the form of trimer (Rt) 5 mol % or above.
摘要翻译： 一种新型的环烯烃共聚物，其可用于生产具有较少缺陷的模制品，例如较少的凝胶颗粒（鱼眼）。 提供了一种环烯烃共聚物，其包含80-20摩尔％的衍生自α-烯烃单体的重复单元和20-80摩尔％的源自至少一种环烯烃单体的重复单元，所述环烯烃单体选自通式（ I），通式（II）的单体，通式（III）的单体，通式（IV）的单体和通式（V）的单体），其中相对于衍生自环烯单体的重复单元 ，其比例以二聚体（Rd）的形式存在，为50摩尔％以下，其比例以3摩尔％以上的三聚体（Rt）的形式存在。
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7.发明申请Zero-valence transition metal complex and method of synthesizing organometallic compound from the same as starting material 失效零价过渡金属络合物和与起始原料相同的有机金属化合物的合成方法公开(公告)号：US20060149088A1
公开(公告)日：2006-07-06
申请号：US10543098
申请日：2004-02-13
IPC分类号： C07F15/00
CPC分类号： C07F15/0046
摘要： The present invention relates to a zero-valent transition metal complex which can be used as a starting material for producing a catalyst usable for producing a polyolefin by ring-opening metathesis polymerization of an olefin and an epothilone by ring-closing metathesis reaction, and a method for efficiently producing, at low cost, an organometallic compound useful as a catalyst, using the zero-valent transition metal complex as a starting material. Provided is a method for producing a zero-valent transition metal complex (C), which comprises reacting a divalent transition metal complex (A) with an olefin (B), the complex (A) being selected from the group consisting of a divalent ruthenium complex (A1) and a divalent osmium complex (A2), thereby obtaining a zero-valent transition metal complex (C), wherein the reaction is conducted under reducing conditions and after the reaction, the resultant crude product is extracted at high temperature using a saturated hydrocarbon as an extracting solvent. Also provided is a method for producing an organometallic compound, which comprises reacting the metal complex (C) with a specific compound (D) and a neutral ligand (E) in one step.
摘要翻译： 本发明涉及一种零价过渡金属络合物，其可以用作制备可用于通过闭环复分解反应的烯烃和埃坡霉素的开环易位聚合制备聚烯烃的催化剂的原料，以及 以低成本有效地生产可用作催化剂的有机金属化合物的方法，使用零价过渡金属络合物作为起始原料。 提供了一种制备零价过渡金属络合物（C）的方法，其包括使二价过渡金属络合物（A）与烯烃（B）反应，所述络合物（A）选自二价钌 络合物（A <1> 1）和二价锇络合物（A 2 O 2），从而得到零价过渡金属络合物（C），其中反应在还原条件下进行 反应后，使用饱和烃作为提取溶剂，在高温下提取所得粗产物。 还提供了一种生产有机金属化合物的方法，其包括在一个步骤中使金属络合物（C）与特定化合物（D）和中性配体（E）反应。
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公开(公告)号：US20060030723A1
公开(公告)日：2006-02-09
申请号：US10489604
申请日：2002-09-27
IPC分类号： C07F15/00
CPC分类号： C07F15/0046
摘要： A method for synthesizing an organometallic compound, which is usefully utilized as a catalyst for manufacturing polyolefins by ring-opening metathesis polymerization of an olefin having strain in a molecule such as dicyclopentadiene or synthesizing epothilones by ring-dosing metathesis reaction, by an efficient and low cost synthesis method using a starting material which is easily available due to relatively simple chemical structure, and further without any possibility of coexistence of a vinylhetero compound or a vinyl compound exchanged which tends to accompany as an impurity in the system in conventional methods, characterized by reacting a starting material comprising a zero-valent transition metal complex (A) or a polyvalent transition metal complex (A′), a compound (B) or (B′) shown by the following general formula (1) or (4), respectively, and a neutral ligand (C) or (C′), in one step under non-reducing condition or reducing condition. R1Y1CR2X12 (1) R4Y2CR5X22 (4)
摘要翻译： 一种合成有机金属化合物的方法，其有效地用作通过在诸如二环戊二烯的分子中具有应变的烯烃的开环易位聚合或通过环 - 给料复分解反应合成埃坡霉素来制备聚烯烃的催化剂，通过有效和低的 使用由于相对简单的化学结构容易获得的起始材料的成本合成方法，并且进一步不存在在常规方法中作为杂质伴随作为杂质的乙烯基杂化物或乙烯基化合物交换的任何可能性，其特征在于 使包含零价过渡金属络合物（A）或多价过渡金属络合物（A'）的起始材料，由以下通式（1）或（4）表示的化合物（B）或（B'）反应， 和中性配体（C）或（C'），在非还原条件或还原条件下一步。 <？in-line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 1＆lt; 1＆lt; 1＆lt; CR 2＆ （1）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description = “在线公式”end =“lead”？> R 2 2（4）<？in-line-formula description =“In-line Formulas”end =“tail”？>
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9.发明授权Zero-valent transition metal complex and method for producing an organometallic compound using the same as a starting material 失效零价过渡金属络合物及使用其制造作为起始原料的有机金属化合物的方法公开(公告)号：US07361776B2
公开(公告)日：2008-04-22
申请号：US10543098
申请日：2004-02-13
CPC分类号： C07F15/0046
摘要： The present invention relates to a zero-valent transition metal complex which can be used as a starting material for producing a catalyst usable for producing a polyolefin by ring-opening metathesis polymerization of an olefin and an epothilone by ring-closing metathesis reaction, and a method for efficiently producing, at low cost, an organometallic compound useful as a catalyst, using the zero-valent transition metal complex as a starting material. Provided is a method for producing a zero-valent transition metal complex (C), which comprises reacting a divalent transition metal complex (A) with an olefin (B), the complex (A) being selected from the group consisting of a divalent ruthenium complex (A1) and a divalent osmium complex (A2), thereby obtaining a zero-valent transition metal complex (C), wherein the reaction is conducted under reducing conditions and after the reaction, the resultant crude product is extracted at high temperature using a saturated hydrocarbon as an extracting solvent. Also provided is a method for producing an organometallic compound, which comprises reacting the metal complex (C) with a specific compound (D) and a neutral ligand (E) in one step.
摘要翻译： 本发明涉及一种零价过渡金属络合物，其可以用作制备可用于通过闭环复分解反应的烯烃和埃坡霉素的开环易位聚合制备聚烯烃的催化剂的原料，以及 以低成本有效地生产可用作催化剂的有机金属化合物的方法，使用零价过渡金属络合物作为起始原料。 提供了一种制备零价过渡金属络合物（C）的方法，其包括使二价过渡金属络合物（A）与烯烃（B）反应，所述络合物（A）选自二价钌 络合物（A <1> 1）和二价锇络合物（A 2 O 2），从而得到零价过渡金属络合物（C），其中反应在还原条件下进行 反应后，使用饱和烃作为提取溶剂，在高温下提取所得粗产物。 还提供了一种生产有机金属化合物的方法，其包括在一个步骤中使金属络合物（C）与特定化合物（D）和中性配体（E）反应。
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公开(公告)号：US07098355B2
公开(公告)日：2006-08-29
申请号：US10489604
申请日：2002-09-27
CPC分类号： C07F15/0046
摘要： A method for synthesizing an organometallic compound, which is usefully utilized as a catalyst for manufacturing polyolefins by ring-opening metathesis polymerization of an olefin having strain in a molecule such as dicyclopentadiene or synthesizing epothilones by ring-dosing metathesis reaction, by an efficient and low cost synthesis method using a starting material which is easily available due to relatively simple chemical structure, and further without any possibility of coexistence of a vinylhetero compound or a vinyl compound exchanged which tends to accompany as an impurity in the system in conventional methods, characterized by reacting a starting material comprising a zero-valent transition metal complex (A) or a polyvalent transition metal complex (A′), a compound (B) or (B′) shown by the following general formula (1) or (4), respectively, and a neutral ligand (C) or (C′), in one step under non-reducing condition or reducing condition. R1Y1CR2X12 (1) R4Y2CR5X22 (4)
摘要翻译： 一种合成有机金属化合物的方法，其有效地用作通过在诸如二环戊二烯的分子中具有应变的烯烃的开环易位聚合或通过环 - 给料复分解反应合成埃坡霉素来制备聚烯烃的催化剂，通过有效和低的 使用由于相对简单的化学结构容易获得的起始材料的成本合成方法，并且进一步不存在在常规方法中作为杂质伴随作为杂质的乙烯基杂化物或乙烯基化合物交换的任何可能性，其特征在于 使包含零价过渡金属络合物（A）或多价过渡金属络合物（A'）的起始材料，由以下通式（1）或（4）表示的化合物（B）或（B'）反应， 和中性配体（C）或（C'），在非还原条件或还原条件下一步。 <？in-line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 1＆lt; 1＆lt; 1＆lt; CR 2＆ （1）<？in-line-formula description =“In-Line Formulas”end =“tail”？> <？in-line-formula description = “在线公式”end =“lead”？> R 2 2（4）<？in-line-formula description =“In-line Formulas”end =“tail”？>
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