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公开(公告)号：US20120208043A1
公开(公告)日：2012-08-16
申请号：US13503959
申请日：2010-10-22
IPC分类号： B32B15/08
CPC分类号： C23C22/60 , C09D5/084 , C23C22/05 , C23C22/64 , C23C22/82 , C23C22/83 , C23C28/00 , C23C2222/20 , Y10T428/12549 , Y10T428/12556 , Y10T428/12569 , Y10T428/12799 , Y10T428/12972 , Y10T428/12979 , Y10T428/265
摘要： There is provided a galvanized steel sheet that has various properties such as corrosion resistance and adhesion and allows for high conductivity at a low contact pressure. A first layer film is formed by applying a surface treatment solution having a pH of 8 to 10 onto the surface of the galvanized steel sheet and drying the surface treatment solution by heating, the surface treatment solution containing a water-soluble zirconium compound, a tetraalkoxysilane, an epoxy group-containing compound, a chelating agent, a silane coupling agent, vanadic acid, and a metal compound in a specific ratio. Subsequently, a second layer film is formed by applying a surface treatment solution containing an organic resin onto the surface of the first layer film and drying the surface treatment solution by heating.
摘要翻译： 提供了具有耐腐蚀性和粘附性等各种性能的镀锌钢板，并且在低接触压力下允许高导电性。 通过在镀锌钢板的表面上涂布pH为8〜10的表面处理液，通过加热干燥表面处理液，形成第一层膜，含有水溶性锆化合物，四烷氧基硅烷 ，含环氧基的化合物，螯合剂，硅烷偶联剂，钒酸和特定比例的金属化合物。 随后，通过将包含有机树脂的表面处理溶液涂覆到第一层膜的表面上并通过加热干燥表面处理溶液来形成第二层膜。
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公开(公告)号：US09051654B2
公开(公告)日：2015-06-09
申请号：US13503959
申请日：2010-10-22
IPC分类号： B32B15/08 , B32B15/18 , C23C22/60 , C23C22/05 , C23C22/64 , C23C22/82 , C09D5/08 , C23C22/83 , C23C28/00
CPC分类号： C23C22/60 , C09D5/084 , C23C22/05 , C23C22/64 , C23C22/82 , C23C22/83 , C23C28/00 , C23C2222/20 , Y10T428/12549 , Y10T428/12556 , Y10T428/12569 , Y10T428/12799 , Y10T428/12972 , Y10T428/12979 , Y10T428/265
摘要： There is provided a galvanized steel sheet that has various properties such as corrosion resistance and adhesion and allows for high conductivity at a low contact pressure. A first layer film is formed by applying a surface treatment solution having a pH of 8 to 10 onto the surface of the galvanized steel sheet and drying the surface treatment solution by heating, the surface treatment solution containing a water-soluble zirconium compound, a tetraalkoxysilane, an epoxy group-containing compound, a chelating agent, a silane coupling agent, vanadic acid, and a metal compound in a specific ratio. Subsequently, a second layer film is formed by applying a surface treatment solution containing an organic resin onto the surface of the first layer film and drying the surface treatment solution by heating.
摘要翻译： 提供了具有耐腐蚀性和粘附性等各种性能的镀锌钢板，并且在低接触压力下允许高导电性。 通过在镀锌钢板的表面上涂布pH为8〜10的表面处理液，通过加热干燥表面处理液，形成第一层膜，含有水溶性锆化合物，四烷氧基硅烷 ，含环氧基的化合物，螯合剂，硅烷偶联剂，钒酸和特定比例的金属化合物。 随后，通过将包含有机树脂的表面处理溶液涂覆到第一层膜的表面上并通过加热干燥表面处理溶液来形成第二层膜。
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公开(公告)号：US20120088122A1
公开(公告)日：2012-04-12
申请号：US13260831
申请日：2010-03-31
CPC分类号： C23C22/60 , C09D5/082 , C09D7/61 , C09D7/65 , C23C2222/20 , Y10T428/12757 , Y10T428/12799 , Y10T428/12806
摘要： A galvanized steel sheet includes a surface-treatment film with 50 to 1200 mg/m2, wherein the surface-treatment film is obtained by applying a surface-treatment agent to a surface of a galvanized steel sheet and drying the surface-treatment agent by heating; and the surface-treatment agent is prepared as a mixture having a pH of 8 to 10 and containing, with specific proportions, a water-soluble zirconium compound, a tetraalkoxysilane, an epoxy-group-containing compound, a chelating agent, a silane coupling agent, vanadic acid, and a metal compound.
摘要翻译： 镀锌钢板包括具有50〜1200mg / m 2的表面处理膜，其中，通过将表面处理剂涂布在镀锌钢板的表面上并通过加热干燥表面处理剂而获得表面处理膜 ; 并且将表面处理剂制备为pH为8至10的混合物，并且特定比例含有水溶性锆化合物，四烷氧基硅烷，含环氧基的化合物，螯合剂，硅烷偶联剂 试剂，钒酸和金属化合物。
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公开(公告)号：US20130302637A1
公开(公告)日：2013-11-14
申请号：US13822748
申请日：2011-09-28
CPC分类号： C23C22/73 , B05D3/0254 , C09D5/08 , C23C22/40 , C23C22/42 , C23C22/44 , C23C2222/20 , Y10T428/12549
摘要： A surface treatment liquid contains a resin emulsion that contains a cationic urethane resin emulsion and/or a nonionic acrylic resin emulsion, a tetraalkoxysilane, at least one silane coupling agent (c) that contains at least one reactive functional group selected from active hydrogen-containing amino group, an epoxy group, a mercapto group, and a methacryloxy group, a chelating agent (d), a vanadic acid compound (e), a titanium compound (f), and water in a specific ratio. The surface treatment liquid has a pH of 3 to 6. The surface treatment liquid is applied to a surface of a zinc-based metal coated steel sheet and dried by heating to form a first layer. Next, a surface treatment liquid containing an organic resin is applied to a surface of the first layer and dried by heating to form a second layer.
摘要翻译： 表面处理液包含含有阳离子聚氨酯树脂乳液和/或非离子丙烯酸树脂乳液，四烷氧基硅烷，至少一种含有至少一个选自活性氢的反应性官能团的硅烷偶联剂（c）的树脂乳液 氨基，环氧基，巯基和甲基丙烯酰氧基，螯合剂（d），钒酸化合物（e），钛化合物（f）和特定比例的水。 表面处理液的pH为3〜6。将表面处理液涂布在锌系金属涂层钢板的表面上，通过加热进行干燥，形成第1层。 接着，将含有有机树脂的表面处理液施加到第一层的表面，通过加热干燥，形成第二层。
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公开(公告)号：US09127366B2
公开(公告)日：2015-09-08
申请号：US13822748
申请日：2011-09-28
IPC分类号： B32B15/04 , B32B15/08 , B32B15/18 , C23C22/73 , C09D5/08 , C23C22/40 , C23C22/42 , C23C22/44 , B05D3/02
CPC分类号： C23C22/73 , B05D3/0254 , C09D5/08 , C23C22/40 , C23C22/42 , C23C22/44 , C23C2222/20 , Y10T428/12549
摘要： A surface treatment liquid contains a resin emulsion that contains a cationic urethane resin emulsion and/or a nonionic acrylic resin emulsion, a tetraalkoxysilane, at least one silane coupling agent (c) that contains at least one reactive functional group selected from active hydrogen-containing amino group, an epoxy group, a mercapto group, and a methacryloxy group, a chelating agent (d), a vanadic acid compound (e), a titanium compound (f), and water in a specific ratio. The surface treatment liquid has a pH of 3 to 6. The surface treatment liquid is applied to a surface of a zinc-based metal coated steel sheet and dried by heating to form a first layer. Next, a surface treatment liquid containing an organic resin is applied to a surface of the first layer and dried by heating to form a second layer.
摘要翻译： 表面处理液包含含有阳离子聚氨酯树脂乳液和/或非离子丙烯酸树脂乳液，四烷氧基硅烷，至少一种含有至少一个选自活性氢的反应性官能团的硅烷偶联剂（c）的树脂乳液 氨基，环氧基，巯基和甲基丙烯酰氧基，螯合剂（d），钒酸化合物（e），钛化合物（f）和特定比例的水。 表面处理液的pH为3〜6。将表面处理液涂布在锌系金属涂层钢板的表面上，通过加热进行干燥，形成第1层。 接着，将含有有机树脂的表面处理液施加到第一层的表面，通过加热干燥，形成第二层。
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6.发明授权Method for manufacturing zinc or zinc alloy coated steel sheet and zinc or zinc alloy coated steel sheet manufactured by the method 有权通过该方法制造锌或锌合金涂层钢板和锌或锌合金涂层钢板的方法公开(公告)号：US09499914B2
公开(公告)日：2016-11-22
申请号：US13822139
申请日：2011-09-29
IPC分类号： C23C28/00 , C09D5/08 , C09D5/24 , C23C22/40 , C23C22/42 , C23C22/44 , C08G18/08 , C09D175/04 , C23C28/02
CPC分类号： C23C28/00 , C08G18/0814 , C09D5/084 , C09D5/24 , C09D175/04 , C23C22/40 , C23C22/42 , C23C22/44 , C23C28/021 , C23C28/025 , C23C2222/20 , Y10T428/12569
摘要： A zinc or zinc alloy coated steel excellent in various properties including corrosion resistance and adhesion properties and, in particular, good conductivity is provided. A method for manufacturing a zinc or zinc alloy coated steel sheet includes: preparing a surface-treatment liquid for a the steel sheet, containing following components, by blending the including: (A) a specific resin emulsion; (B) a tetraalkoxysilane; (C) at least one type of silane coupling agent; (D) a chelating agent; (E) a vanadate compound; (F) a titanium compound; and water; and applying by coating the surface-treatment liquid to a surface of the steel sheet, heating and drying the surface of the steel sheet such that a coating amount per one surface is 200 to 1,000 mg/m2 to form a surface treatment coating film on the surface.
摘要翻译： 提供了具有优异的各种性能的锌或锌合金涂层钢，包括耐腐蚀性和粘附性，特别是良好的导电性。 一种锌或锌合金涂层钢板的制造方法，其特征在于，包括：（A）特定的树脂乳液，配制含有以下成分的钢板用表面处理液， （B）四烷氧基硅烷; （C）至少一种硅烷偶联剂; （D）螯合剂; （E）钒酸盐化合物; （F）钛化合物; 和水; 通过将表面处理液涂布在钢板表面上，对钢板表面进行加热干燥，使得每一面的涂布量为200〜1000mg / m 2，形成表面处理涂膜 表面。
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7.发明申请METHOD FOR MANUFACTURING ZINC OR ZINC ALLOY COATED STEEL SHEET AND ZINC OR ZINC ALLOY COATED STEEL SHEET MANUFACTURED BY THE METHOD 有权用于制造锌合金或锌合金涂层钢板的方法和由方法制造的锌或锌合金涂层钢板公开(公告)号：US20130177779A1
公开(公告)日：2013-07-11
申请号：US13822139
申请日：2011-09-29
IPC分类号： C23C28/00
CPC分类号： C23C28/00 , C08G18/0814 , C09D5/084 , C09D5/24 , C09D175/04 , C23C22/40 , C23C22/42 , C23C22/44 , C23C28/021 , C23C28/025 , C23C2222/20 , Y10T428/12569
摘要： A zinc or zinc alloy coated steel excellent in various properties including corrosion resistance and adhesion properties and, in particular, good conductivity is provided. A method for manufacturing a zinc or zinc alloy coated steel sheet includes: preparing a surface-treatment liquid for a the steel sheet, containing following components, by blending the including: (A) a specific resin emulsion; (B) a tetraalkoxysilane; (C) at least one type of silane coupling agent; (D) a chelating agent; (E) a vanadate compound; (F) a titanium compound; and water; and applying by coating the surface-treatment liquid to a surface of the steel sheet, heating and drying the surface of the steel sheet such that a coating amount per one surface is 200 to 1,000 mg/m2 to form a surface treatment coating film on the surface.
摘要翻译： 提供了具有优异的各种性能的锌或锌合金涂层钢，包括耐腐蚀性和粘附性，特别是良好的导电性。 一种锌或锌合金涂层钢板的制造方法，其特征在于，包括：（A）特定的树脂乳液，配制含有以下成分的钢板用表面处理液， （B）四烷氧基硅烷; （C）至少一种硅烷偶联剂; （D）螯合剂; （E）钒酸盐化合物; （F）钛化合物; 和水; 通过将表面处理液涂布在钢板表面上，对钢板表面进行加热干燥，使得每一面的涂布量为200〜1000mg / m 2，形成表面处理涂膜 表面。
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8.发明申请公开(公告)号：US20140342180A1
公开(公告)日：2014-11-20
申请号：US14344140
申请日：2012-09-12
申请人： Rie Kaneko , Takeshi Matsuda , Akira Matsuzaki , Yasuhide Oshima
发明人： Rie Kaneko , Takeshi Matsuda , Akira Matsuzaki , Yasuhide Oshima
CPC分类号： C23C22/62 , B05D3/00 , B05D3/02 , C09D5/08 , C09D5/082 , C09D5/084 , C09D5/086 , C23C22/60 , C23C22/74 , C23C2222/20 , Y10T428/12569
摘要： A zinc or zinc alloy coated steel sheet has a surface-treatment film formed thereon in a coating weight per one surface of 100 to 600 mg/m2. The surface-treatment film is obtained by applying, onto a surface of the zinc or zinc alloy coated steel sheet, the surface-treatment solution prepared by mixing the following components at specific ratios, the surface-treatment solution having pH of 8 to 10: a silane compound (A) having a hydrolyzable group, obtained from a silane coupling agent (a1) having a glycidyl group, a tetraalkoxysilane (a2), and a chelating agent (a3); a zirconium carbonate compound (B); a vanadate compound (C); a nitric compound (D); and water, and by subsequently heating and drying the surface-treatment solution thus applied.
摘要翻译： 锌或锌合金涂层钢板在其上形成有表层处理膜，其表面的涂层重量为100〜600mg / m 2。 表面处理膜通过将锌或锌合金涂层钢板的表面涂布在以特定比例混合以下组分而制备的表面处理溶液，pH为8〜10:1的表面处理溶液， 由具有缩水甘油基的硅烷偶联剂（a1），四烷氧基硅烷（a2）和螯合剂（a3）得到的具有可水解基团的硅烷化合物（A） 碳酸锆化合物（B）; 钒酸盐化合物（C）; 硝酸化合物（D）; 和水，然后通过随后加热和干燥所施加的表面处理溶液。
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9.发明授权Surface-treated steel sheet excellent in corrosion resistance, conductivity, and coating appearance 有权耐腐蚀性，导电性和涂装外观优异的表面处理钢板公开(公告)号：US07348068B2
公开(公告)日：2008-03-25
申请号：US10560842
申请日：2004-11-18
申请人： Takeshi Matsuda , Akira Matsuzaki , Kazuhisa Okai
发明人： Takeshi Matsuda , Akira Matsuzaki , Kazuhisa Okai
CPC分类号： C23C28/00 , B32B15/08 , C23C22/42 , Y10T428/12493 , Y10T428/12535 , Y10T428/12569 , Y10T428/12757 , Y10T428/12771 , Y10T428/12799 , Y10T428/12951 , Y10T428/24967 , Y10T428/265
摘要： A surface-treated steel sheet includes a steel sheet; a plating layer containing at least one metal selected from zinc and aluminum; a first layer film containing (α) 1 to 2000 mg/m2 of silica in terms of SiO2, (β) a total of 1 to 1000 mg/m2 of phosphoric acid groups in terms of P, (γ) a total of 0.5 to 800 mg/m2 of at least one metal selected from Mg, Mn, and Al, and (δ) 0.1 to 50 mg/m2 of a tetravalent vanadium compound; and a second layer film formed to a thickness of 0.1 to 5 μm on the first layer film and containing a resin (A) having at least one type of functional group selected from OH and COOH groups, and at least one rust-proofing additive (B) selected from (a) a phosphate, (b) Ca ion-exchanged silica, (c) a molybdate, (d) silicon oxide, and (e) at least one organic compound selected from triazoles, thiols, thiadiazoles, thiazoles, and thiurams.
摘要翻译： 表面处理钢板包括钢板; 含有选自锌和铝中的至少一种金属的镀层; 含有（α）1至2000mg / m 2的二氧化硅（SiO 2）的第一层膜（β）总计为1-1000mg / 按照P，（γ）的总和为0.5〜800mg / m 2的选自Mg，Mn和Al的至少一种金属的磷酸基团， 和（δ）0.1至50mg / m 2的四价钒化合物; 和在第一层膜上形成厚度为0.1至5μm的第二层膜，并且含有具有至少一种选自OH和COOH基团的官能团的树脂（A）和至少一种防锈添加剂（ B）选自（a）磷酸盐，（b）Ca离子交换二氧化硅，（c）钼酸盐，（d）氧化硅和（e）至少一种选自三唑，硫醇，噻二唑，噻唑， 和秋兰姆。
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10.发明申请Surface treated steel plate excellent in corrosion resitance electroconductivity and appearance of coating film 有权表面处理钢板耐腐蚀性优良，导电性好，涂膜外观美观公开(公告)号：US20060177685A1
公开(公告)日：2006-08-10
申请号：US10560842
申请日：2004-11-18
申请人： Takeshi Matsuda , Akira Matsuzaki , Kazuhisa Okai
发明人： Takeshi Matsuda , Akira Matsuzaki , Kazuhisa Okai
CPC分类号： C23C28/00 , B32B15/08 , C23C22/42 , Y10T428/12493 , Y10T428/12535 , Y10T428/12569 , Y10T428/12757 , Y10T428/12771 , Y10T428/12799 , Y10T428/12951 , Y10T428/24967 , Y10T428/265
摘要： The present invention provides a surface-treated steel sheet including a steel sheet; a plating layer provided on at least one of the surfaces of the steel sheet, the plating layer containing at least one metal selected from the group consisting of zinc and aluminum; a first layer film provided on the surface of the plating layer and containing (α) 1 to 2000 mg/m2 of silica in terms of SiO2, (β) a total of 1 to 1000 mg/m2 of phosphoric acid groups in terms of P, (γ) a total of 0.5 to 800 mg/m2 of at least one metal selected from the group consisting of Mg, Mn, and Al in terms of a metal element, and (δ) 0.1 to 50 mg/m2 of a tetravalent vanadium compound in terms of V; and a second layer film formed to a thickness of 0.1 to 5 μm on the first layer film and containing a resin (A) having at least one type of functional group selected from the group consisting of OH and COOH groups, and at least one rust-proofing additive (B) selected from the group consisting of (a) a phosphate, (b) Ca ion-exchanged silica, (c) a molybdate, (d) silicon oxide, and (e) at least one organic compound selected from the group consisting of triazoles, thiols, thiadiazoles, thiazoles, and thiurams. The surface-treated steel sheet has excellent corrosion resistance without containing hexavalent chromium in a coating, and also has excellent conductivity and coating appearance.
摘要翻译： 本发明提供一种包括钢板的表面处理钢板; 设置在所述钢板的至少一个表面上的镀层，所述镀层含有选自锌和铝的至少一种金属; 设置在镀层的表面上的第一层膜，其含有（α）以SiO 2为单位的（α）1至2000mg / m 2的二氧化硅，（β）a 总共1至1000mg / m 2磷酸基团的P，（γ）总计为0.5至800mg / m 2的至少一种金属 选自以金属元素为基准的Mg，Mn和Al组成的组，和以V计的（V）为0.1至50mg / m 2的四价钒化合物; 和在第一层膜上形成厚度为0.1至5μm的第二层膜，并且含有具有至少一种选自OH和COOH基团的官能团的至少一种类型的树脂（A），以及至少一种锈 选自（a）磷酸盐，（b）Ca离子交换二氧化硅，（c）钼酸盐，（d）氧化硅和（e）至少一种选自以下的有机化合物： 由三唑，硫醇，噻二唑，噻唑和秋兰组成的组。 表面处理钢板在涂层中不含六价铬，具有优异的耐腐蚀性，并且还具有优异的导电性和涂层外观。
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