Imaging element comprising solubilized collagen gelatin and hardener
    2.
    发明授权
    Imaging element comprising solubilized collagen gelatin and hardener 失效
    成像元件包括溶解的胶原明胶和硬化剂

    公开(公告)号:US06573037B1

    公开(公告)日:2003-06-03

    申请号:US10158656

    申请日:2002-05-30

    IPC分类号: G03C1047

    CPC分类号: G03C1/047 G03C1/005 G03C1/30

    摘要: An imaging element is described comprising one or more hydrophilic colloid layers which include gelatin as a film forming binder which has been chemically crosslinked with a gelatin hardener, wherein at least 20% of the gelatin of at least one of the one or more hydrophilic colloid layers comprises a gelatin prepared from hydrolysis of ossein using sodium or potassium hydroxide, and the gelatin is chemical crosslinked with a gelatin hardener at a level from 70 to 120 effective &mgr;mole hardener per gram of gelatin. Improvements are obtained in the wet mechanical strength of an imaging element comprising gelatin as a binder, without needing to increase the amount of chemical crosslinker with respect to the gelatin. The invention further enables the use of relatively low molecular weight gelatins without compromising the wet mechanical strength of imaging elements and without needing to increase the amount of crosslinker relative to the amount of gelatin. The invention also enables the selective improvement in the wet mechanical properties of layers with a high ratio of non-binder materials to binder without substantially increasing the amount of chemical crosslinker.

    摘要翻译: 描述了一种成像元件,其包含一个或多个亲水胶体层,其包括明胶作为成膜粘合剂,其已经用明胶固化剂化学交联,其中至少20%的一种或多种亲水胶体层中的至少一种的明胶 包括使用氢氧化钠或氢氧化钾从骨胶原水解制备的明胶,明胶与明胶固化剂进行化学交联,每克明胶的水平为70至120有效的莫美尔硬化剂。 在包含明胶作为粘合剂的成像元件的湿机械强度方面获得了改进,而不需要相对于明胶增加化学交联剂的量。 本发明还使得能够使用相对低分子量的明胶,而不会影响成像元件的湿机械强度,并且不需要相对于明胶量增加交联剂的量。 本发明还能够以非粘合剂材料与粘合剂的高比率选择性地提高层的湿机械性能,而基本上不增加化学交联剂的量。

    Enzyme-activated water-resistant protective overcoat for a photographic element
    3.
    发明授权
    Enzyme-activated water-resistant protective overcoat for a photographic element 失效
    用于照相材料的酶活性防水保护罩

    公开(公告)号:US06187517B1

    公开(公告)日:2001-02-13

    申请号:US09591430

    申请日:2000-06-09

    IPC分类号: G03C516

    摘要: The present invention provides a gelatin-based aqueous-coatable overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight gelatin and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat) having an average diameter of 10 to 500 nm. A proteolytic enzyme is applied to the clement in reactive association with the overcoat layer. A photographic element according to one embodiment of the invention can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.

    摘要翻译: 本发明提供了一种用于照相材料的明胶基水性可涂覆外涂层,其允许照相处理溶液的适当扩散。 外涂层包含10至50重量%的明胶和50至90重量%的平均直径为10至500纳米的疏水颗粒(整个外涂层的干重沉积重量)。 将蛋白水解酶应用于与外涂层反应性缔合的蛋白质。 根据本发明的一个实施方案的照相材料可以使用普通的照相洗印加工设备进行曝光和加工,而无需修改,以便将成像元件与保护性防水层一起提供。

    Method of forming a protective overcoat for imaged elements and related articles
    4.
    发明授权
    Method of forming a protective overcoat for imaged elements and related articles 失效
    形成用于成像元件和相关制品的保护性外涂层的方法

    公开(公告)号:US06395459B1

    公开(公告)日:2002-05-28

    申请号:US09676865

    申请日:2000-09-29

    IPC分类号: G03C176

    摘要: The present invention relates to imaged elements having a protective overcoat that resists fingerprints, common stains, and spills. In particular, a curable overcoat composition is applied to an imaged element that contains a curing agent incorporated into a top layer of the element, resulting in a cured water-resistant or spill resistant overcoat. The invention can be used to protect photographic elements and recording media. In one embodiment of the invention, a UV-curable material and a water-dispersible latex is applied to a photographic print containing a photoinitiator incorporated into the original print.

    摘要翻译: 本发明涉及具有防护指纹,常见污渍和溢出物的保护性外套的成像元件。 特别地,将可固化外涂层组合物施加到成像元件上,所述成像元件含有固化剂,所述固化剂包含在所述元件的顶层中,从而形成固化的防水或防溢出外涂层。 本发明可用于保护照相元件和记录介质。 在本发明的一个实施方案中,将UV可固化材料和水分散性胶乳施加到包含并入原始印刷品中的光引发剂的照片印刷。

    Protective overcoat for an imaging element comprising an enzyme-treated biopolymer
    5.
    发明授权
    Protective overcoat for an imaging element comprising an enzyme-treated biopolymer 失效
    用于包含酶处理的生物聚合物的成像元件的保护性外涂层

    公开(公告)号:US06280912B1

    公开(公告)日:2001-08-28

    申请号:US09665463

    申请日:2000-09-19

    IPC分类号: G03C176

    摘要: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.

    摘要翻译: 本发明提供了一种用于照相元件的外涂层,其允许照相处理溶液的适当扩散。 外涂层包含10至50重量%的可酶降解的生物聚合物和50至90重量%的疏水颗粒(按整个外涂层的干重沉积重量计)。 在常规照相处理之前,期间或之后将酶施加到元件上。 根据本发明的一个实施例,可以使用正常的照相洗印加工设备对照相元件进行曝光和处理,而无需修改,以便将成像元件与保护性防水层一起提供。

    Hydrolyzed water-resistant protective overcoat for an imaging element
    7.
    发明授权
    Hydrolyzed water-resistant protective overcoat for an imaging element 失效
    用于成像元件的水解防水保护外套

    公开(公告)号:US06190843B1

    公开(公告)日:2001-02-20

    申请号:US09547374

    申请日:2000-04-11

    IPC分类号: G03C176

    摘要: The present invention relates to imaging elements, including photographic elements and recording media, having a protective overcoat that resists fingerprints, common stains, and spills. More particularly, the present invention provides a processing-solution-permeable protective overcoat that is water resistant in the final processed product. The overcoat, before formation of the image, comprises hydrophobic polymeric particles in a gelatin matrix. Subsequent treatment of the overcoat, after formation of the image, to remove the gelatin, causes coalescence of the hydrophobic particles, resulting in the formation of a water-resistant continuous protective overcoat.

    摘要翻译: 本发明涉及包含摄影元件和记录介质的成像元件,其具有防止指纹,常见污渍和溢出物的保护外套。 更具体地说,本发明提供了一种在最终加工产品中具有防水性的加工溶液渗透保护外涂层。 在形成图像之前,外涂层包含明胶基质中的疏水聚合物颗粒。 在形成图像之后,外涂层的后续处理以除去明胶,导致疏水性颗粒的聚结,导致形成耐水的连续保护性外涂层。

    Protective overcoat for an imaging element comprising an enzyme-treated biopolymer
    8.
    发明授权
    Protective overcoat for an imaging element comprising an enzyme-treated biopolymer 失效
    用于包含酶处理的生物聚合物的成像元件的保护性外涂层

    公开(公告)号:US06406838B1

    公开(公告)日:2002-06-18

    申请号:US09898231

    申请日:2001-07-03

    IPC分类号: G03C538

    摘要: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.

    摘要翻译: 本发明提供了一种用于照相元件的外涂层,其允许照相处理溶液的适当扩散。 外涂层包含10至50重量%的可酶降解的生物聚合物和50至90重量%的疏水颗粒(按整个外涂层的干重沉积重量计)。 在常规照相处理之前,期间或之后将酶施加到元件上。 根据本发明的一个实施例,可以使用正常的照相洗印加工设备对照相元件进行曝光和处理,而无需修改,以便将成像元件与保护性防水层一起提供。

    Overcoat material as protecting layer for image recording materials
    10.
    发明授权
    Overcoat material as protecting layer for image recording materials 失效
    外涂层材料作为图像记录材料的保护层

    公开(公告)号:US6130014A

    公开(公告)日:2000-10-10

    申请号:US354055

    申请日:1999-07-15

    摘要: The present invention is a coating composition comprising at least one first water insoluble polymer having a Tg equal to or less than 30.degree. C. and at least one second water insoluble polymer having a Tg equal to or greater than 60.degree. C. wherein the first polymer comprises a monomer at a weight percent of 75 to 100 of the monomer represented by the following formula 1: ##STR1## wherein: X is selected from the group consisting of --Cl, --F, or --CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, n-C.sub.4 H.sub.9, n-C.sub.5 H.sub.11, n-C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl, C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, Cl, F, CN, CF.sub.3, C.sub.2 F.sub.5, n-C.sub.3 F.sub.7, iso-C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5 ; and the second polymer is a microgel particle.

    摘要翻译: 本发明是一种涂料组合物,其包含至少一种Tg等于或小于30℃的第一水不溶性聚合物和Tg等于或大于60℃的至少一种第二水不溶性聚合物。其中第一 聚合物包含以下式1表示的单体的重量百分比为75-100的单体:其中:X选自-Cl,-F或-CN,Y各自独立地选自 由H,Cl,F,CN,CF 3,CH 3,C 2 H 5,n-C 3 H 7,异-C 3 H 7,n-C 4 H 9,n -C 5 H 11,n-C 6 H 13,OCH 3,OC 2 H 5,苯基,C 6 F 5,C 6 Cl 5,CH 2 Cl, ,CF 3,CH 2(CF 3),CH(CF 3)2,COCF 3,COC 2 F 5,COCH 3,COC 2 H 5; C 1 -C 3烷基,C 1 -C 6烷基, 并且第二聚合物是微凝胶颗粒。