摘要:
The present invention is a photographic element which includes a support, at least one silver halide emulsion layer superposed on the support and a processing-solution-permeable protective overcoat overlying the silver halide emulsion layer that becomes water-resistant in the final product without lamination or fusing. The present invention is also directed to a method of making a photographic print involving developing the photographic element.
摘要:
An imaging element is described comprising one or more hydrophilic colloid layers which include gelatin as a film forming binder which has been chemically crosslinked with a gelatin hardener, wherein at least 20% of the gelatin of at least one of the one or more hydrophilic colloid layers comprises a gelatin prepared from hydrolysis of ossein using sodium or potassium hydroxide, and the gelatin is chemical crosslinked with a gelatin hardener at a level from 70 to 120 effective &mgr;mole hardener per gram of gelatin. Improvements are obtained in the wet mechanical strength of an imaging element comprising gelatin as a binder, without needing to increase the amount of chemical crosslinker with respect to the gelatin. The invention further enables the use of relatively low molecular weight gelatins without compromising the wet mechanical strength of imaging elements and without needing to increase the amount of crosslinker relative to the amount of gelatin. The invention also enables the selective improvement in the wet mechanical properties of layers with a high ratio of non-binder materials to binder without substantially increasing the amount of chemical crosslinker.
摘要:
The present invention provides a gelatin-based aqueous-coatable overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight gelatin and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat) having an average diameter of 10 to 500 nm. A proteolytic enzyme is applied to the clement in reactive association with the overcoat layer. A photographic element according to one embodiment of the invention can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.
摘要:
The present invention relates to imaged elements having a protective overcoat that resists fingerprints, common stains, and spills. In particular, a curable overcoat composition is applied to an imaged element that contains a curing agent incorporated into a top layer of the element, resulting in a cured water-resistant or spill resistant overcoat. The invention can be used to protect photographic elements and recording media. In one embodiment of the invention, a UV-curable material and a water-dispersible latex is applied to a photographic print containing a photoinitiator incorporated into the original print.
摘要:
The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.
摘要:
The present invention relates to imaging elements, including photographic elements and recording media, having a protective overcoat that resists fingerprints, common stains, and spills. More particularly, the present invention provides a processing-solution-permeable protective overcoat that is water resistant in the final processed product. The overcoat, before formation of the image, comprises hydrophobic polymeric particles in a gelatin matrix. Subsequent treatment of the overcoat, after formation of the image, to remove the gelatin, causes coalescence of the hydrophobic particles, resulting in the formation of a water-resistant continuous protective overcoat.
摘要:
The present invention relates to imaging elements, including photographic elements and recording media, having a protective overcoat that resists fingerprints, common stains, and spills. More particularly, the present invention provides a processing-solution-permeable protective overcoat that is water resistant in the final processed product. The overcoat, before formation of the image, comprises hydrophobic polymeric particles in a gelatin matrix. Subsequent treatment of the overcoat, after formation of the image, to remove the gelatin, causes coalescence of the hydrophobic particles, resulting in the formation of a water-resistant continuous protective overcoat.
摘要:
The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.
摘要:
The present invention is directed to an imaged element that includes a support, at least image-receiving layer superposed on the support and a water-resistant protective overcoat overlying the image-receiving layer that is water-resistance. The present invention is also directed to a method of making a print by application of a UV-curable water-dispersible latex.
摘要:
The present invention is a coating composition comprising at least one first water insoluble polymer having a Tg equal to or less than 30.degree. C. and at least one second water insoluble polymer having a Tg equal to or greater than 60.degree. C. wherein the first polymer comprises a monomer at a weight percent of 75 to 100 of the monomer represented by the following formula 1: ##STR1## wherein: X is selected from the group consisting of --Cl, --F, or --CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, n-C.sub.4 H.sub.9, n-C.sub.5 H.sub.11, n-C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl, C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, Cl, F, CN, CF.sub.3, C.sub.2 F.sub.5, n-C.sub.3 F.sub.7, iso-C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5 ; and the second polymer is a microgel particle.
摘要翻译:本发明是一种涂料组合物,其包含至少一种Tg等于或小于30℃的第一水不溶性聚合物和Tg等于或大于60℃的至少一种第二水不溶性聚合物。其中第一 聚合物包含以下式1表示的单体的重量百分比为75-100的单体:其中:X选自-Cl,-F或-CN,Y各自独立地选自 由H,Cl,F,CN,CF 3,CH 3,C 2 H 5,n-C 3 H 7,异-C 3 H 7,n-C 4 H 9,n -C 5 H 11,n-C 6 H 13,OCH 3,OC 2 H 5,苯基,C 6 F 5,C 6 Cl 5,CH 2 Cl, ,CF 3,CH 2(CF 3),CH(CF 3)2,COCF 3,COC 2 F 5,COCH 3,COC 2 H 5; C 1 -C 3烷基,C 1 -C 6烷基, 并且第二聚合物是微凝胶颗粒。