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1.发明授权Hexagonal type barium titanate powder, producing method thereof, dielectric ceramic composition and electronic component 有权六角型钛酸钡粉末，其制造方法，电介质陶瓷组合物和电子部件公开(公告)号：US08373968B2
公开(公告)日：2013-02-12
申请号：US12941439
申请日：2010-11-08
申请人： Tatsuya Ishii , Hidesada Natsui , Takeo Tsukada , Shinichi Yoda , Kentei Yono
发明人： Tatsuya Ishii , Hidesada Natsui , Takeo Tsukada , Shinichi Yoda , Kentei Yono
IPC分类号： H01G4/06
CPC分类号： C01G23/006 , C01G45/125 , C01P2002/52 , C01P2002/72 , C01P2002/76 , C01P2004/51 , C01P2004/52 , C01P2004/53 , C01P2006/12 , C01P2006/40 , C04B35/468 , C04B35/62675 , C04B2235/3206 , C04B2235/3208 , C04B2235/3215 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3241 , C04B2235/3263 , C04B2235/3281 , C04B2235/3298 , C04B2235/3418 , C04B2235/365 , C04B2235/5409 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/6584 , C04B2235/6588 , C04B2235/662 , C04B2235/767 , C04B2235/785 , C04B2235/79 , C04B2235/80 , C04B2235/81
摘要： Dielectric ceramic composition includes a hexagonal type barium titanate as a main component shown by a generic formula (Ba1-αMα)A(Ti1-βMnβ)BO3 and having hexagonal structure wherein an effective ionic radius of 12-coordinated “M” is −20% or more to +20% or less with respect to an effective ionic radius of 12-coordinated Ba2+ and the A, B, α and β satisfy relations of 0.900≦(A/B)≦1.040, 0.003≦α≦0.05, 0.03≦β≦0.2, and as subcomponents, with respect to the main component, certain contents of alkaline earth oxide such as MgO and the like, Mn3O4 and/or Cr2O3, CuO, Al2O3, rare earth element oxide and glass component including SiO2. According to the present invention, it can be provided the hexagonal type barium titanate powder and dielectric ceramic composition which are preferable for producing electronic components such as a capacitor and the like showing high specific permittivity, having advantageous insulation property and sufficient reliability.
摘要翻译： 介电陶瓷组合物包括六方晶系钛酸钡作为主要成分，由通式（Ba1-αMα）A（Ti1-＆bgr; Mn＆bgr））BO3表示，并具有六方结构，其中12配位M的有效离子半径为-20 相对于12配位Ba2 +的有效离子半径和A，B，α和bgr的有效离子半径为％以上〜20％以下。 满足0.900＆nlE的关系;（A / B）＆nlE; 1.040,0.003＆nlE;α＆nlE; 0.05,0.03＆nlE;＆bgr＆nlE; 0.2，作为副成分，对于主要成分，碱土金属氧化物的某些含量 MgO等，Mn 3 O 4和/或Cr 2 O 3，CuO，Al 2 O 3，稀土元素氧化物和包含SiO 2的玻璃成分。 根据本发明，可以提供六方晶系的钛酸钡粉末和电介质陶瓷组合物，该六方晶系钛酸钡粉末和电介质陶瓷组合物优选用于制造具有高比介电常数的诸如电容器等的电子部件，具有有利的绝缘性和足够的可靠性。
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公开(公告)号：US20110059838A1
公开(公告)日：2011-03-10
申请号：US12991601
申请日：2008-05-15
申请人： Kentei Yono , Atsunobu Masuno , Shinichi Yoda , Hidesada Natsui
发明人： Kentei Yono , Atsunobu Masuno , Shinichi Yoda , Hidesada Natsui
IPC分类号： C04B35/468
摘要： Dielectric ceramic composition comprising a barium titanate including barium titanate having hexagonal structure as a main component, and an element “M”, an effective ionic radius of the “M” is within ±20% with respect to an effective ionic radius of 12-coordinated Ba2+ or with respect to an effective ionic radius of 6-coordinated Ti4+, an ionic valence of the “M” is larger than that of the Ba or Ti.
摘要翻译： 包含具有六方结构作为主要成分的钛酸钡的钛酸钡和元素“M”的介电陶瓷组合物，“M”的有效离子半径相对于12配位的有效离子半径在±20％以内 Ba2 +或相对于6配位Ti4 +的有效离子半径，“M”的离子价大于Ba或Ti的离子价。
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公开(公告)号：US08293668B2
公开(公告)日：2012-10-23
申请号：US12991601
申请日：2008-05-15
申请人： Kentei Yono , Atsunobu Masuno , Shinichi Yoda , Hidesada Natsui
发明人： Kentei Yono , Atsunobu Masuno , Shinichi Yoda , Hidesada Natsui
IPC分类号： C04B35/468
摘要： Dielectric ceramic composition comprising a barium titanate including barium titanate having hexagonal structure as a main component, and an element “M”, an effective ionic radius of the “M” is within ±20% with respect to an effective ionic radius of 12-coordinated Ba2+ or with respect to an effective ionic radius of 6-coordinated Ti4+, an ionic valence of the “M” is larger than that of the Ba or Ti.
摘要翻译： 包含钛酸钡的电介质陶瓷组合物，包括具有六方结构的钛酸钡作为主要成分，元素M，M的有效离子半径相对于12配位Ba2 +的有效离子半径相对于±20％ 到6配位Ti4 +的有效离子半径，M的离子价态大于Ba或Ti的离子价。
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4.发明授权Method of producing barium-titanium-based oxide glass using containerless solidification process 有权使用无容器凝固法生产钡钛氧化物玻璃的方法公开(公告)号：US08028541B2
公开(公告)日：2011-10-04
申请号：US11369848
申请日：2006-03-08
申请人： Kentei Yono , Takehiko Ishikawa , Yasutomo Arai , Shinichi Yoda
发明人： Kentei Yono , Takehiko Ishikawa , Yasutomo Arai , Shinichi Yoda
CPC分类号： C03C3/127 , C03B5/06 , C03B19/1005 , C03B40/04 , C03C4/00 , C03C4/14 , C03C10/0072
摘要： Disclosed is a method of producing a barium-titanium-based ferroelectric glass using a containerless solidification process, such as an electrostatic levitation process or a gas levitation process, which comprises the steps of levitating a sample 1 of a barium-titanium-based compound by a levitating force of compressed air, heating the sample up to a temperature greater than its melting point (1330° C.) by about 100° C. to allow the sample to be molten, and, after maintaining the molten state for a given time period (at least several second), quenching the sample from a given temperature range (1400 to 1000° C.) at a cooling rate of about 103 K/sec, so as to allow the sample to be solidified while inhibiting nucleation and mixing of impurities from a container. The present invention makes it possible to provide a glass exhibiting an unprecedented, extremely large permittivity.
摘要翻译： 公开了使用诸如静电悬浮法或气体悬浮法的无容器凝固方法制备钡钛基铁电玻璃的方法，其包括以下步骤：将钡钛基化合物的样品1悬浮在 压缩空气的悬浮力，将样品加热至高于其熔点（1330℃）的温度约100℃，以使样品熔融，并且在将熔融状态保持给定时间之后 时间（至少几秒），以约103K /秒的冷却速率从给定温度范围（1400至1000℃）淬火样品，以使样品固化，同时抑制成核和混合 来自容器的杂质。 本发明使得可以提供呈现前所未有的极大介电常数的玻璃。
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公开(公告)号：US08030232B2
公开(公告)日：2011-10-04
申请号：US13052584
申请日：2011-03-21
CPC分类号： C03C3/253 , C03B19/1005 , C03B40/04 , C03C3/127 , C03C3/21 , C03C2203/10 , G02B6/32 , Y10T428/29
摘要： A titanium-containing oxide glass having a bulky form and substantially having a chemical composition represented by the formula: (M1)1-x(M2)x(Ti1-y1(M3)y1)y2O2 [wherein M1 represents an element selected from Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na and Ca; M2 represents at least one element selected from Mg, Ba, Ca, Sr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na, Sc, Y, Hf, Bi and Ag; M3 represents at least one element selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Al, Si, P, Ga, Ge, In, Sn, Sb and Te; and x, y1, y2 and z satisfy the following requirements: 0≦x≦0.5, 0≦y1
摘要翻译： 具有大体积且基本上具有由式（M1）1-x（M2）x（Ti1-y1（M3）y1）y2O2表示的化学组成的含钛氧化物玻璃[其中M1表示选自Ba ，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Na和Ca; M2表示选自Mg，Ba，Ca，Sr，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Na，Sc，Y， Hf，Bi和Ag; M3表示选自V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Zr，Nb，Mo，Ru，Rh，Pd，Al，Si，P，Ga，Ge，In，Sn， Sb和Te; 并且x，y1，y2和z满足以下要求：当M1表示Ba时，x + y1≠0，0＆nlE; x＆nlE; 0.5,0和nlE; y1 <0.31,1.4
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公开(公告)号：US07960300B2
公开(公告)日：2011-06-14
申请号：US12310944
申请日：2007-09-13
CPC分类号： C03C3/253 , C03B19/1005 , C03B40/04 , C03C3/127 , C03C3/21 , C03C2203/10 , G02B6/32 , Y10T428/29
摘要： A titanium-containing oxide glass having a bulky form and substantially having a chemical composition represented by the formula: (M1)1-x(M2)x(Ti1-y1(M3)y1)y2Oz [wherein M1 represents an element selected from Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na and Ca; M2 represents at least one element selected from Mg, Ba, Ca, Sr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na, Sc, Y, Hf, Bi and Ag; M3 represents at least one element selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Al, Si, P, Ga, Ge, In, Sn, Sb and Te; and x, y1, y2 and z satisfy the following requirements: 0≦x≦0.5, 0≦y1
摘要翻译： 具有大体积且基本上具有由式（M1）1-x（M2）x（Ti1-y1（M3）y1）y2Oz表示的化学组成的含钛氧化物玻璃[其中M1表示选自Ba ，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Na和Ca; M2表示选自Mg，Ba，Ca，Sr，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Na，Sc，Y， Hf，Bi和Ag; M3表示选自V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Zr，Nb，Mo，Ru，Rh，Pd，Al，Si，P，Ga，Ge，In，Sn， Sb和Te; 并且x，y1，y2和z满足以下要求：当M1表示Ba时，x + y1≠0，0＆nlE; x＆nlE; 0.5,0和nlE; y1 <0.31,1.4
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7.发明申请Method of producing barium-titanium-based oxide glass using containerless solidification process 有权使用无容器凝固法生产钡钛氧化物玻璃的方法公开(公告)号：US20060205095A1
公开(公告)日：2006-09-14
申请号：US11369848
申请日：2006-03-08
申请人： Kentei Yono , Takehiko Ishikawa , Yasutomo Arai , Shinichi Yoda
发明人： Kentei Yono , Takehiko Ishikawa , Yasutomo Arai , Shinichi Yoda
IPC分类号： H01L21/00
CPC分类号： C03C3/127 , C03B5/06 , C03B19/1005 , C03B40/04 , C03C4/00 , C03C4/14 , C03C10/0072
摘要： Disclosed is a method of producing a barium-titanium-based ferroelectric glass using a containerless solidification process, such as an electrostatic levitation process or a gas levitation process, which comprises the steps of levitating a sample 1 of a barium-titanium-based compound by a levitating force of compressed air, heating the sample up to a temperature greater than its melting point (1330° C.) by about 100° C. to allow the sample to be molten, and, after maintaining the molten state for a given time period (at least several second), quenching the sample from a given temperature range (1400 to 1000° C.) at a cooling rate of about 103 K/sec, so as to allow the sample to be solidified while inhibiting nucleation and mixing of impurities from a container. The present invention makes it possible to provide a glass exhibiting an unprecedented, extremely large permittivity.
摘要翻译： 公开了使用诸如静电悬浮法或气体悬浮法的无容器凝固方法制备钡钛基铁电玻璃的方法，其包括以下步骤：将钡钛基化合物的样品1悬浮在 压缩空气的悬浮力，将样品加热至高于其熔点（1330℃）的温度约100℃，以使样品熔融，并且在将熔融状态保持给定时间之后 （至少几秒钟），以约10 3 K /秒的冷却速率将样品从给定温度范围（1400至1000℃）淬火，以使样品 同时抑制来自容器的杂质的成核和混合。 本发明使得可以提供呈现前所未有的极大介电常数的玻璃。
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8.发明申请Method for producing barium titanium oxide single-crystal piece using containerless processing 有权使用无容器加工制造钡钛氧化物单晶片的方法公开(公告)号：US20050199180A1
公开(公告)日：2005-09-15
申请号：US11044325
申请日：2005-01-28
CPC分类号： C04B35/4682 , C04B35/465 , C04B35/47 , C04B35/472 , C04B2235/3208 , C04B2235/604 , C04B2235/79 , C04B2235/94 , C04B2235/95 , C30B11/00 , C30B11/002 , C30B29/16 , Y10S117/901
摘要： Disclosed is a method for producing a barium titanium oxide single crystal piece with a given structure using a containerless solidification process, which comprises the steps of preparing a material made of a barium titanium oxide, controlling the material to be in a levitated state within a levitation furnace, melting the levitated material using a laser, and solidifying the molten material while maintaining the levitated state. In a specific embodiment, a spherical sample having a composition of BaTiO3 and a weight of about 20 mg is subjected to a rapid solidification and melting process (temperature gradient: about 700 K/sec) 3 times while levitating the sample in 4.5 atm of air atmosphere using an electrostatic levitation furnace. Then, the re-molten sample is maintained at a temperature just below the melting point of the sample for a given time, and then rapidly cooled at a cooling rate of 300 K/sec to obtain a transparent blue barium titanium oxide single crystal. The single crystal exhibits innovative dielectric characteristics having a large relative permittivity (100,000 or more at room temperature) and a low dielectric loss. In addition, the single crystal has excellent temperature stability allowing the relative permittivity to be gently reduced in the range of room temperature to 70 K.
摘要翻译： 公开了一种使用无容器凝固方法制造具有给定结构的钡钛氧化物单晶片的方法，其包括以下步骤：制备由氧化钛钡制成的材料，将材料控制在悬浮状态下处于悬浮状态 使用激光对悬浮物进行熔融，同时固化熔融材料，同时保持悬浮状态。 在具体实施方案中，将具有组成为BaTiO 3和重量约20mg的球形样品经受快速凝固和熔化过程（温度梯度：约700K /秒）3次，同时 使用静电悬浮炉将样品悬浮在空气气氛的4.5atm中。 然后，将再熔融样品保持在正好低于样品熔点的温度一定时间，然后以300K /秒的冷却速度快速冷却，得到透明的蓝色钡钛氧化物单晶。 单晶具有相对介电常数（室温下为100,000或更高）和低介电损耗的创新介电特性。 此外，单晶具有优异的温度稳定性，允许相对介电常数在室温至70K的范围内轻轻降低。
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公开(公告)号：US20100003514A1
公开(公告)日：2010-01-07
申请号：US12310944
申请日：2007-09-13
CPC分类号： C03C3/253 , C03B19/1005 , C03B40/04 , C03C3/127 , C03C3/21 , C03C2203/10 , G02B6/32 , Y10T428/29
摘要： A titanium-containing oxide glass having a bulky form and substantially having a chemical composition represented by the formula: (M1)1-x(M2)x(Ti1-y1(M3)y1)y2Oz [wherein M1 represents an element selected from Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na and Ca; M2 represents at least one element selected from Mg, Ba, Ca, Sr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na, Sc, Y, Hf, Bi and Ag; M3 represents at least one element selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Al, Si, P, Ga, Ge, In, Sn, Sb and Te; and x, y1, y2 and z satisfy the following requirements: 0≦x≦0.5, 0≦y1
摘要翻译： 具有大体积且基本上具有由式（M1）1-x（M2）x（Ti1-y1（M3）y1）y2Oz表示的化学组成的含钛氧化物玻璃[其中M1表示选自Ba ，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Na和Ca; M2表示选自Mg，Ba，Ca，Sr，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Na，Sc，Y， Hf，Bi和Ag; M3表示选自V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Zr，Nb，Mo，Ru，Rh，Pd，Al，Si，P，Ga，Ge，In，Sn， Sb和Te; x，y1，y2和z满足以下要求：0 <= x <= 0.5,0 <= y1 <0.31,1.4
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10.发明授权Method for producing barium titanium oxide single-crystal piece using containerless processing 有权使用无容器加工制造钡钛氧化物单晶片的方法公开(公告)号：US07544245B2
公开(公告)日：2009-06-09
申请号：US11044325
申请日：2005-01-28
CPC分类号： C04B35/4682 , C04B35/465 , C04B35/47 , C04B35/472 , C04B2235/3208 , C04B2235/604 , C04B2235/79 , C04B2235/94 , C04B2235/95 , C30B11/00 , C30B11/002 , C30B29/16 , Y10S117/901
摘要： Disclosed is a method for producing a barium titanium oxide single crystal piece with a given structure using a containerless solidification process, which comprises the steps of preparing a material made of a barium titanium oxide, controlling the material to be in a levitated state within a levitation furnace, melting the levitated material using a laser, and solidifying the molten material while maintaining the levitated state. In a specific embodiment, a spherical sample having a composition of BaTiO3 and a weight of about 20 mg is subjected to a rapid solidification and melting process (temperature gradient: about 700 K/sec) 3 times while levitating the sample in 4.5 atm of air atmosphere using an electrostatic levitation furnace. Then, the re-molten sample is maintained at a temperature just below the melting point of the sample for a given time, and then rapidly cooled at a cooling rate of 300 K/sec to obtain a transparent blue barium titanium oxide single crystal. The single crystal exhibits innovative dielectric characteristics having a large relative permittivity (100,000 or more at room temperature) and a low dielectric loss. In addition, the single crystal has excellent temperature stability allowing the relative permittivity to be gently reduced in the range of room temperature to 70 K.
摘要翻译： 公开了一种使用无容器凝固方法制造具有给定结构的钡钛氧化物单晶片的方法，其包括以下步骤：制备由氧化钛钡制成的材料，将材料控制在悬浮状态下处于悬浮状态 使用激光对悬浮物进行熔融，同时固化熔融材料，同时保持悬浮状态。 在具体实施方案中，将具有BaTiO 3组成和重量约20mg的球形样品在快速凝固和熔化过程（温度梯度：约700K /秒）下进行3次，同时使样品在4.5atm空气中悬浮 使用静电悬浮炉。 然后，将再熔融样品保持在正好低于样品熔点的温度一定时间，然后以300K /秒的冷却速度快速冷却，得到透明的蓝色钡钛氧化物单晶。 单晶具有相对介电常数（室温下为100,000或更高）和低介电损耗的创新介电特性。 此外，单晶具有优异的温度稳定性，允许相对介电常数在室温至70K的范围内轻轻降低。
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