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    Dispersed metal sulfide catalysts for hydroprocessing
    1.
    发明授权
    Dispersed metal sulfide catalysts for hydroprocessing 失效

    公开(公告)号：US5831138A

    公开(公告)日：1998-11-03

    申请号：US912895

    申请日：1997-08-15

    申请人： Teh Chung Ho ,  Stuart Leon Soled ,  Sabato Miseo ,  Gary Brice McVicker ,  Michel Daage ,  Viktor Buchholz

    发明人： Teh Chung Ho ,  Stuart Leon Soled ,  Sabato Miseo ,  Gary Brice McVicker ,  Michel Daage ,  Viktor Buchholz

    IPC分类号： B01J31/22 ,  B01J23/887 ,  B01J23/889 ,  B01J27/051 ,  B01J37/08 ,  B01J37/20 ,  C07B35/02 ,  C10G45/46 ,  C10G45/50 ,  C07C5/10

    CPC分类号： B01J37/086 ,  B01J23/887 ,  B01J23/8878 ,  B01J23/8892 ,  B01J27/051 ,  B01J37/20 ,  C10G45/46 ,  C10G45/50

    摘要： The present invention is directed toward a catalyst composition comprising a catalyst prepared by a process comprising: (a) impregnating an oxide precursor selected from the group consisting of rare earth oxide precursors, yttria precursors and mixtures thereof, onto an inorganic refractory oxide support; (b) drying said support at a temperature of about 100.degree. to about 120.degree. C. followed by calcining said support at a temperature of about 400.degree. to about 600.degree. C.; and (c) compositing or depositing on said support of step (b), a catalyst precursor salt represented by (ML)(Mo.sub.y W.sub.1-y O.sub.4).sub.a wherein M comprises Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1, and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating polydentate ligand; a=1 when chromium is not one of the promoter metals and 0.5.ltoreq.a.ltoreq.3 when Cr is one of the promoter metals. (d) sulfiding said deposited or composited supports of step (c) with an excess amount of sulfur in the form of one or more sulfur bearing compounds and at a temperature of at least about 250.degree. C. to form catalysts. In a preferred embodiment, the process will further comprise decomposing the composited or deposited supports of step (c) in a nonoxidizing atmosphere at a temperature of at least about 250.degree. C. prior to said sulfiding step (d). In a second aspect of the invention there is provided an improved aromatics hydrogenation process.

    Dispersed metal sulfide catalysts for hydroprocessing (LAW105)
    2.
    发明授权
    Dispersed metal sulfide catalysts for hydroprocessing (LAW105) 失效
    用于加氢处理的分散金属硫化物催化剂（LAW105）

    公开(公告)号：US5648577A

    公开(公告)日：1997-07-15

    申请号：US460410

    申请日：1995-06-02

    申请人： Teh Chung Ho ,  Stuart Leon Soled ,  Sabato Miseo ,  Gary Brice McVicker ,  Michel Daage ,  Viktor Buchholz

    发明人： Teh Chung Ho ,  Stuart Leon Soled ,  Sabato Miseo ,  Gary Brice McVicker ,  Michel Daage ,  Viktor Buchholz

    IPC分类号： B01J31/22 ,  B01J23/887 ,  B01J23/889 ,  B01J27/051 ,  B01J37/08 ,  B01J37/20 ,  C07B35/02 ,  C10G45/46 ,  C10G45/50 ,  C07C5/10

    CPC分类号： B01J37/086 ,  B01J23/887 ,  B01J23/8878 ,  B01J23/8892 ,  B01J27/051 ,  B01J37/20 ,  C10G45/46 ,  C10G45/50

    摘要： The present invention is directed toward a catalyst composition prepared by a process comprising: (a) impregnating an oxide precursor selected from the group consisting of rare earth oxide precursors, yttria precursors and mixtures thereof, onto an inorganic refractory oxide support; (b) drying said support at a temperature of about 100.degree. to about 120.degree. C. followed by calcining said support at a temperature of about 400.degree. to about 600.degree. C.; and (c) compositing or depositing on said support of step (b), a catalyst precursor salt represented by (ML)(Mo.sub.y W.sub.1-y O.sub.4).sub.a wherein M comprises Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1, and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating polydentate ligand; a=1 when chromium is not one of the promoter metals and 0.5.ltoreq.a.ltoreq.3 when Cr is one of the promoter metals. (d) sulfiding said deposited or composited support of step (c) with an excess amount of sulfur in the form of one or more sulfur bearing compounds and at a temperature of at least about 250.degree. C. to form catalysts. In a preferred embodiment, the the composited or deposited supports of step (c) may be decomposed in a nonoxidizing atmosphere at a temperature of at least about 250.degree. C. prior to said sulfiding step (d). In a second aspect of the invention there is provided an improved aromatics hydrogenation process.

    摘要翻译： 本发明涉及通过包括以下步骤的方法制备的催化剂组合物：（a）将选自稀土氧化物前体，氧化钇前体及其混合物的氧化物前体浸渍到无机难熔氧化物载体上; （b）在约100至约120℃的温度下干燥所述载体，然后在约400至约600℃的温度下煅烧所述载体; 和（c）在步骤（b）的所述载体上合成或沉积由（ML）（MoyW1-yO4）a表示的催化剂前体盐，其中M包含Cr和/或一种或多种选自以下的二价助催化剂金属： Mn，Fe，Co，Ni，Cu，Zn及其混合物，其中y是0至1的任何值，并且其中L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体; 当Cr不是助催化剂金属之一时，a = 1，当Cr是助催化剂金属之一时，a = 1。 （d）将步骤（c）的沉积或复合载体用一种或多种含硫化合物形式的过量的硫硫化并在至少约250℃的温度下硫化以形成催化剂。 在优选的实施方案中，在所述硫化步骤（d）之前，步骤（c）的复合或沉积的载体可以在非氧化气氛中在至少约250℃的温度下分解。 在本发明的第二方面，提供了一种改进的芳族化合物氢化方法。

    Dispersed metal sulfide catalysts for hydroprocessing
    3.
    发明授权
    Dispersed metal sulfide catalysts for hydroprocessing 失效
    用于加氢处理的分散金属硫化物催化剂

    公开(公告)号：US5728644A

    公开(公告)日：1998-03-17

    申请号：US524228

    申请日：1995-09-05

    申请人： Teh Chung Ho ,  Stuart Leon Soled ,  Sabato Miseo ,  Gary Brice Mc Vicker ,  Michel Daage ,  Viktor Buchholz

    发明人： Teh Chung Ho ,  Stuart Leon Soled ,  Sabato Miseo ,  Gary Brice Mc Vicker ,  Michel Daage ,  Viktor Buchholz

    IPC分类号： B01J31/22 ,  B01J23/887 ,  B01J23/889 ,  B01J27/051 ,  B01J37/08 ,  B01J37/20 ,  C07B35/02 ,  C10G45/46 ,  C10G45/50 ,  B01J27/047 ,  B01J23/63 ,  B01J31/00

    CPC分类号： B01J37/086 ,  B01J23/887 ,  B01J23/8878 ,  B01J23/8892 ,  B01J27/051 ,  B01J37/20 ,  C10G45/46 ,  C10G45/50

    摘要： The present invention is directed toward a catalyst composition comprising a catalyst prepared by a process comprising: (a) impregnating an oxide precursor selected from the group consisting of rare earth oxide precursors, yttria precursors and mixtures thereof, onto an inorganic refractory oxide support; (b) drying said support at a temperature of about 100.degree. to about 120.degree. C. followed by calcining said support at a temperature of about 400.degree. to about 600.degree. C.; and (c) compositing or depositing on said support of step (b), a catalyst precursor salt represented by (ML)(Mo.sub.y W.sub.1-y O.sub.4).sub.a wherein M comprises Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1, and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating polydentate ligand; a=1 when chromium is not one of the promoter metals and 0.5.ltoreq.a.ltoreq.3 when Cr is one of the promoter metals. (d) sulfiding said deposited or composited supports of step (c) with an excess amount of sulfur in the form of one or more sulfur bearing compounds and at a temperature of at least about 250.degree. C. to form catalysts. In a preferred embodiment, the process will further comprise decomposing the composited or deposited supports of step (c) in a nonoxidizing atmosphere at a temperature of at least about 250.degree. C. prior to said sulfiding step (d). In a second aspect of the invention there is provided an improved aromatics hydrogenation process.

    摘要翻译： 本发明涉及一种催化剂组合物，其包含通过以下方法制备的催化剂，所述催化剂包括：（a）将选自稀土氧化物前体，氧化钇前体及其混合物的氧化物前体浸渍到无机耐火氧化物载体上; （b）在约100至约120℃的温度下干燥所述载体，然后在约400至约600℃的温度下煅烧所述载体; 和（c）在步骤（b）的所述载体上合成或沉积由（ML）（MoyW1-yO4）a表示的催化剂前体盐，其中M包含Cr和/或一种或多种选自以下的二价助催化剂金属： Mn，Fe，Co，Ni，Cu，Zn及其混合物，其中y是0至1的任何值，并且其中L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体; 当Cr不是助催化剂金属之一时，a = 1，当Cr是助催化剂金属之一时，a = 1。 （d）用一种或多种带硫化合物形式的过量硫磺和至少约250℃的温度硫化所述步骤（c）的沉积或复合载体以形成催化剂。 在优选的实施方案中，该方法还包括在所述硫化步骤（d）之前，在至少约250℃的温度下，在非氧化气氛中分解步骤（c）的复合或沉积的载体。 在本发明的第二方面，提供了一种改进的芳族化合物氢化方法。

    Aromatics hydrogenation with a new class of metal oxides
    5.
    发明授权
    Aromatics hydrogenation with a new class of metal oxides 失效
    芳烃氢化与一类新型的金属氧化物

    公开(公告)号：US5841013A

    公开(公告)日：1998-11-24

    申请号：US857605

    申请日：1997-05-16

    申请人： Teh Chung Ho ,  Charles Ralph Symon ,  Viktor Buchholz ,  Michel Daage

    发明人： Teh Chung Ho ,  Charles Ralph Symon ,  Viktor Buchholz ,  Michel Daage

    IPC分类号： B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J37/08 ,  C07C5/10 ,  C10G45/50 ,  B01J31/00

    CPC分类号： B01J23/883 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J23/8898 ,  B01J37/086 ,  C07C5/10 ,  C10G45/50 ,  B01J23/8878 ,  C07C2531/22

    摘要： The present invention is directed toward a hydrogenation process using a highly active aromatics hydrogenation catalyst. The catalyst is prepared by decomposing a catalyst precursor selected from the group consisting of metal amine molybdates, metal amine tungstates and mixtures thereof, wherein said metal amine catalyst precursor has the general formula ML (Mo.sub.y W.sub.1-y O.sub.4).sub.a where M is Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu and Zn; L is one or more neutral nitrogen-containing ligands at least one of which is a chelating polydentate ligand; 0.ltoreq.y.ltoreq.1; and a=1 for non-chromium containing catalysts and wherein 0.5.ltoreq.a.ltoreq.3 for chromium containing catalysts, at a temperature of about 200.degree. C. to about 400.degree. C. in an inert atmosphere; then reducing at a temperature of about 300.degree. C. to about 450.degree. C. said metal amine catalyst precursor to form a mixed metal oxide catalyst of the formula ML(Mo.sub.y W.sub.1-y O.sub.b).sub.a where M, L and y are as above and b

    摘要翻译： 本发明涉及使用高活性芳烃加氢催化剂的氢化方法。 催化剂是通过分解选自钼酸金属胺，钨酸金属胺及其混合物的催化剂前体制备的，其中所述金属胺催化剂前体具有通式ML（MoyW1-yO4）a，其中M是Cr和/或 一种或多种选自Mn，Fe，Co，Ni，Cu和Zn的二价助催化剂金属; L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体; 0

    Aromatics hydrogenation with a new class of metal oxides
    6.
    发明授权
    Aromatics hydrogenation with a new class of metal oxides 失效
    芳烃氢化与一类新型的金属氧化物

    公开(公告)号：US5767037A

    公开(公告)日：1998-06-16

    申请号：US516890

    申请日：1995-08-18

    申请人： Teh Chung Ho ,  Charles R. Symon ,  Viktor Buchholz ,  Michel Daage

    发明人： Teh Chung Ho ,  Charles R. Symon ,  Viktor Buchholz ,  Michel Daage

    IPC分类号： B01J31/18 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J37/08 ,  B01J37/18 ,  C10G45/46 ,  C10G45/50 ,  C10G65/08 ,  B01J27/051 ,  C07C5/10 ,  C10G47/02

    CPC分类号： B01J23/8898 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J37/086 ,  B01J37/18 ,  C10G45/46 ,  C10G45/50 ,  C10G65/08

    摘要： The present invention is directed toward a highly active aromatics hydrogenation catalyst and its use. The catalyst composition is prepared by: (a) decomposing a catalyst precursor selected from the group consisting of metal amine molybdates, metal amine tungstates and mixtures thereof, wherein said metal amine catalyst precursor has the general formula ML(Mo.sub.y W.sub.1-y O.sub.4)a where M is Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu and Zn; L is one or more neutral nitrogen containing ligands at least one of which is a chelating polydentate ligand; 0.ltoreq.y.ltoreq.1; and a=1 for non-chromium containing catalysts and wherein 0.5.ltoreq.a.ltoreq.3 for chromium containing catalysts, at a temperature of about 200.degree. to about 400.degree. C. in an inert atmosphere; and (b) reducing at a temperature of about 300.degree. to about 450.degree. C. said metal amine catalyst precursor to form a catalyst. The catalyst as prepared above may be used in an aromatics hydrogenation process. The invention is further directed to the use of such catalysts in aromatics hydrogenation processes.

    摘要翻译： 本发明涉及高活性芳烃氢化催化剂及其用途。 催化剂组合物通过以下步骤制备：（a）分解选自钼酸金属胺，钨酸金属胺及其混合物的催化剂前体，其中所述金属胺催化剂前体具有通式ML（MoyW1-yO4）a其中M 是选自Mn，Fe，Co，Ni，Cu和Zn中的Cr和/或一种或多种二价助催化剂金属; L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体; 0

    Operating method for fluid catalytic cracking involving alternating feed injection
    9.
    发明授权
    Operating method for fluid catalytic cracking involving alternating feed injection 有权
    涉及交替进料注入的流化床催化裂化操作方法

    公开(公告)号：US6156189A

    公开(公告)日：2000-12-05

    申请号：US294951

    申请日：1999-04-20

    申请人： Teh Chung Ho ,  Shun Chong Fung ,  Daniel Paul Leta

    发明人： Teh Chung Ho ,  Shun Chong Fung ,  Daniel Paul Leta

    IPC分类号： C10G11/18 ,  C10G11/00

    CPC分类号： C10G11/18 ,  Y10S208/01

    摘要： The present invention is directed to a Fluid Catalytic Cracking process conducted under fluid catalytic cracking conditions by injecting into at least one reaction zone of a fluid catalytic cracking unit (FCCU) having one or more risers, a plurality of feeds wherein said plurality of feeds comprises at least one feed (.alpha.) and at least another feed (.beta.) wherein said feeds (.alpha.) and (.beta.) (a) differ in Conradson Carbon Residue by at least about 2 wt % points; or (b) differ in hydrogen content by at least about 0.2 wt %; or (c) differ in API gravities by at least about 2 points; or (d) differ in nitrogen content by at least about 50 ppm; or (e) differ in carbon-to-hydrogen ratio by at least about 0.3; or (f) differ in mean boiling point by at least about 200.degree. F; and wherein said feeds (.alpha.) and (.beta.) are alternately injected and wherein said alternate injection maintains said risers in a cyclic steady state, while the rest of the FCC unit is in a steady state.

    摘要翻译： 本发明涉及一种在流化催化裂化条件下进行的流体催化裂化方法，该方法是将具有一个或多个立管的流化催化裂化装置（FCCU）的至少一个反应区注入多个进料，其中所述多个进料包含 至少一种进料（α）和至少另一种进料（β），其中所述进料（α）和（β）（a）在康拉德森碳残余物中不同至少约2重量％ 或（b）氢含量不同至少约0.2wt％; 或（c）API重力差异至少约2分; 或（d）氮含量不同至少约50ppm; 或（e）碳 - 氢比率不等于至少约0.3; 或（f）平均沸点不同至少约200°F; 并且其中所述进料（α）和（β）被交替注入，并且其中所述交替喷射维持所述提升管处于循环稳定状态，而FCC装置的其余部分处于稳定状态。