公开(公告)号：US07795365B2

公开(公告)日：2010-09-14

申请号：US10529530

申请日：2003-10-01

申请人： Teresa P. Karjala ,  Selim Yalvac ,  Thomas Karjala ,  Daniel D. Vanderlende ,  Brian W. Kolthammer ,  James C. Stevens ,  Charles F. Diehl

发明人： Teresa P. Karjala ,  Selim Yalvac ,  Thomas Karjala ,  Daniel D. Vanderlende ,  Brian W. Kolthammer ,  James C. Stevens ,  Charles F. Diehl

IPC分类号： C08F4/602

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/14 ,  C10M107/02 ,  C10M143/00 ,  C10M2205/00 ,  C10M2205/003 ,  C10M2205/022 ,  C10M2205/0225 ,  C08F4/6592 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F210/06

摘要： The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.

摘要翻译： 本发明涉及通过凝胶渗透色谱法测定的数均分子量（Mn）低于25,000，通过DSC测量的总结晶度小于10的均相液体低分子量乙烯/α-烯烃聚合物 ％，和通过ASTM D97测量的倾点小于50℃。本发明还涉及具有数均分子量（Mn）的均匀的凝胶状低分子量乙烯/α-烯烃聚合物 通过凝胶渗透色谱法，小于25,000，通过DSC测量的总结晶度小于50％，和通过ASTM D97测量的倾点小于90℃。

公开(公告)号：US08846991B2

公开(公告)日：2014-09-30

申请号：US12817962

申请日：2010-06-17

申请人： Teresa P. Karjala ,  Selim Yalvac ,  Thomas Karjala ,  Daniel D. VanderLende ,  Brian W. Kolthammer ,  James C. Stevens ,  Charles F. Diehl

发明人： Teresa P. Karjala ,  Selim Yalvac ,  Thomas Karjala ,  Daniel D. VanderLende ,  Brian W. Kolthammer ,  James C. Stevens ,  Charles F. Diehl

IPC分类号： C07C11/04

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/14 ,  C10M107/02 ,  C10M143/00 ,  C10M2205/00 ,  C10M2205/003 ,  C10M2205/022 ,  C10M2205/0225 ,  C08F4/6592 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F210/06

摘要： The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C.The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.

摘要翻译： 本发明涉及通过凝胶渗透色谱法测定的数均分子量（Mn）低于25,000，通过DSC测量的总结晶度小于10的均相液体低分子量乙烯/α-烯烃聚合物 ％，和通过ASTM D97测量的倾点小于50℃。本发明还涉及具有数均分子量（Mn）的均匀的凝胶状低分子量乙烯/α-烯烃聚合物 通过凝胶渗透色谱法，小于25,000，通过DSC测量的总结晶度小于50％，和通过ASTM D97测量的倾点小于90℃。

公开(公告)号：US08420742B2

公开(公告)日：2013-04-16

申请号：US13347993

申请日：2012-01-11

申请人： Teresa P. Karjala ,  Brian W. Kolthammer

发明人： Teresa P. Karjala ,  Brian W. Kolthammer

IPC分类号： C08L23/08 ,  C08F4/653 ,  C08F4/6592

CPC分类号： C08F210/16 ,  C08F210/02 ,  C08L2314/06 ,  C08L2666/02 ,  C09J123/0815 ,  Y10S526/943 ,  C08F212/08 ,  C08F2500/07 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/04 ,  C08F2500/03

摘要： The present invention relates to an ethylene/α-olefin interpolymer product comprising at least one α-olefin interpolymerized with ethylene and, characterized in at least one aspect, as having improved properties when utilized in a hot melt adhesive formulation. The invention also relates to a process for manufacturing the interpolymer product wherein the process comprises employing two or more single site catalyst systems in at least one reaction environment (or reactor) and wherein the at least two catalyst systems have (a) different comonomer incorporation capabilities or reactivities and/or (b) different termination kinetics, both when measured under the same polymerization conditions. The interpolymer products are useful, for example, in applications such as hot melt adhesives, and also for impact, bitumen and asphalt modification, adhesives, dispersions or latexes and fabricated articles such as, but not limited to, foams, films, sheet, moldings, thermoforms, profiles and fibers.

摘要翻译： 本发明涉及一种包含至少一种与乙烯共聚的α-烯烃的乙烯/α-烯烃互聚物产物，其特征在于在至少一个方面当用于热熔粘合剂制剂时具有改进的性能。 本发明还涉及制备互聚物产物的方法，其中该方法包括在至少一个反应环境（或反应器）中采用两个或多个单中心催化剂体系，并且其中所述至少两个催化剂体系具有（a）不同的共聚单体掺入能力 或反应性和/或（b）不同的终止动力学，当在相同的聚合条件下测量时。 互聚物产品可用于例如热熔粘合剂，以及用于冲击，沥青和沥青改性，粘合剂，分散体或胶乳和制造的制品，例如但不限于泡沫，薄膜，片材，模制品 ，热成型，型材和纤维。

公开(公告)号：US20120108777A1

公开(公告)日：2012-05-03

申请号：US13347993

申请日：2012-01-11

申请人： Teresa P. Karjala ,  Brian W. Kolthammer

发明人： Teresa P. Karjala ,  Brian W. Kolthammer

IPC分类号： C08F210/16

CPC分类号： C08F210/16 ,  C08F210/02 ,  C08L2314/06 ,  C08L2666/02 ,  C09J123/0815 ,  Y10S526/943 ,  C08F212/08 ,  C08F2500/07 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/04 ,  C08F2500/03

摘要： The present invention relates to an ethylene/α-olefin interpolymer product comprising at least one α-olefin interpolymerized with ethylene and, characterized in at least one aspect, as having improved properties when utilized in a hot melt adhesive formulation. The invention also relates to a process for manufacturing the interpolymer product wherein the process comprises employing two or more single site catalyst systems in at least one reaction environment (or reactor) and wherein the at least two catalyst systems have (a) different comonomer incorporation capabilities or reactivities and/or (b) different termination kinetics, both when measured under the same polymerization conditions. The interpolymer products are useful, for example, in applications such as hot melt adhesives, and also for impact, bitumen and asphalt modification, adhesives, dispersions or latexes and fabricated articles such as, but not limited to, foams, films, sheet, moldings, thermoforms, profiles and fibers.

摘要翻译： 本发明涉及一种包含至少一种与乙烯共聚的α-烯烃的乙烯/α-烯烃互聚物产物，其特征在于在至少一个方面当用于热熔粘合剂制剂时具有改进的性能。 本发明还涉及制备互聚物产物的方法，其中该方法包括在至少一个反应环境（或反应器）中采用两个或多个单中心催化剂体系，并且其中所述至少两个催化剂体系具有（a）不同的共聚单体掺入能力 或反应性和/或（b）不同的终止动力学，当在相同的聚合条件下测量时。 互聚物产品可用于例如热熔粘合剂，以及用于冲击，沥青和沥青改性，粘合剂，分散体或胶乳和制造的制品，例如但不限于泡沫，薄膜，片材，模制品 ，热成型，型材和纤维。

公开(公告)号：US20100256427A1

公开(公告)日：2010-10-07

申请号：US12817962

申请日：2010-06-17

申请人： Teresa P. Karjala ,  Selim Yalvac ,  Thomas Karjala ,  Daniel D. VanderLende ,  Brian W. Kolthammer ,  James C. Stevens ,  Charles F. Diehl

发明人： Teresa P. Karjala ,  Selim Yalvac ,  Thomas Karjala ,  Daniel D. VanderLende ,  Brian W. Kolthammer ,  James C. Stevens ,  Charles F. Diehl

IPC分类号： C07C11/04 ,  C07C15/04

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/14 ,  C10M107/02 ,  C10M143/00 ,  C10M2205/00 ,  C10M2205/003 ,  C10M2205/022 ,  C10M2205/0225 ,  C08F4/6592 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F210/06

摘要： The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C.The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.

摘要翻译： 本发明涉及通过凝胶渗透色谱法测定的数均分子量（Mn）低于25,000，通过DSC测量的总结晶度小于10的均相液体低分子量乙烯/α-烯烃聚合物 ％，和通过ASTM D97测量的倾点小于50℃。本发明还涉及具有数均分子量（Mn）的均匀的凝胶状低分子量乙烯/α-烯烃聚合物 通过凝胶渗透色谱法，小于25,000，通过DSC测量的总结晶度小于50％，和通过ASTM D97测量的倾点小于90℃。

公开(公告)号：US08119747B2

公开(公告)日：2012-02-21

申请号：US12406227

申请日：2009-03-18

申请人： Teresa P. Karjala ,  Brian W. Kolthammer

发明人： Teresa P. Karjala ,  Brian W. Kolthammer

IPC分类号： C08F4/6592 ,  C08F4/642

CPC分类号： C08F210/16 ,  C08F210/02 ,  C08L2314/06 ,  C08L2666/02 ,  C09J123/0815 ,  Y10S526/943 ,  C08F212/08 ,  C08F2500/07 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/04 ,  C08F2500/03

摘要： The present invention relates to an ethylene/α-olefin interpolymer product comprising at least one α-olefin interpolymerized with ethylene and, characterized in at least one aspect, as having improved properties when utilized in a hot melt adhesive formulation. The invention also relates to a process for manufacturing the interpolymer product wherein the process comprises employing two or more single site catalyst systems in at least one reaction environment (or reactor) and wherein the at least two catalyst systems have (a) different comonomer incorporation capabilities or reactivities and/or (b) different termination kinetics, both when measured under the same polymerization conditions. The interpolymer products are useful, for example, in applications such as hot melt adhesives, and also for impact, bitumen and asphalt modification, adhesives, dispersions or latexes and fabricated articles such as, but not limited to, foams, films, sheet, moldings, thermoforms, profiles and fibers.

摘要翻译： 本发明涉及一种包含至少一种与乙烯共聚的α-烯烃的乙烯/α-烯烃互聚物产物，其特征在于在至少一个方面当用于热熔粘合剂制剂时具有改进的性能。 本发明还涉及制备互聚物产物的方法，其中该方法包括在至少一个反应环境（或反应器）中采用两个或多个单中心催化剂体系，并且其中所述至少两个催化剂体系具有（a）不同的共聚单体掺入能力 或反应性和/或（b）不同的终止动力学，当在相同的聚合条件下测量时。 互聚物产品可用于例如热熔粘合剂，以及用于冲击，沥青和沥青改性，粘合剂，分散体或胶乳和制造的制品，例如但不限于泡沫，薄膜，片材，模制品 ，热成型，型材和纤维。

公开(公告)号：US06552148B1

公开(公告)日：2003-04-22

申请号：US09506422

申请日：2000-02-17

申请人： Yunwa W. Cheung ,  Martin J. Guest ,  Robert K. Rosen ,  Brian W. Kolthammer

发明人： Yunwa W. Cheung ,  Martin J. Guest ,  Robert K. Rosen ,  Brian W. Kolthammer

IPC分类号： C08F21204

CPC分类号： C08F210/02 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/00 ,  C08F4/65904 ,  C08F212/04 ,  C08F2500/04

摘要： The present invention relates to a thermoplastic interpolymer product comprising an &agr;-olefin interpolymerized with at least one vinyl or vinylidene aromatic monomer and/or at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene aromatic monomer and, in at least one aspect, is characterized as having substantially synergistic thermal properties. The invention also relates to a process for manufacturing the interpolymer product wherein the process employs two or more single site or metallocene catalyst systems in at least one reaction environment and wherein at least two of the catalyst systems have (a) different monomer incorporation capabilities or reactivities and (b) the same or, optionally, different monomer sequencing and/or tacticity characteristics. With unique thermal property attributes, the interpolymer product is useful, for example, for impact, bitumen and asphalt modification, adhesives, dispersions or latexes and fabricated articles such as, but not limited to, foams, films, sheet, moldings, thermoforms, profiles and fibers.

摘要翻译： 本发明涉及包含与至少一种乙烯基或亚乙烯基芳族单体和/或至少一种受阻的脂族或脂环族乙烯基或亚乙烯基芳族单体共聚的α-烯烃的热塑性共聚体产物，并且在至少一个方面，其特征在于 具有基本上协同的热性能。 本发明还涉及制备互聚物产物的方法，其中该方法在至少一个反应环境中使用两个或多个单个位点或茂金属催化剂体系，并且其中至少两个催化剂体系具有（a）不同的单体掺入能力或反应性 和（b）相同或任选不同的单体测序和/或立体特征。 具有独特的热性质属性，互聚物产品可用于例如冲击，沥青和沥青改性，粘合剂，分散体或胶乳和制造的制品，例如但不限于泡沫，薄膜，片材，模制品，热成型体，型材 和纤维。

公开(公告)号：US5965756A

公开(公告)日：1999-10-12

申请号：US949505

申请日：1997-10-14

申请人： Mark H. McAdon ,  Jasson T. Patton ,  Peter N. Nickias ,  Ravi B. Shankar ,  Francis J. Timmers ,  Brian W. Kolthammer ,  Daniel D. VanderLende ,  Steven M. Ueligger

发明人： Mark H. McAdon ,  Jasson T. Patton ,  Peter N. Nickias ,  Ravi B. Shankar ,  Francis J. Timmers ,  Brian W. Kolthammer ,  Daniel D. VanderLende ,  Steven M. Ueligger

IPC分类号： C07F19/00 ,  C07F17/00 ,  C08F4/64 ,  C08F4/659 ,  C08F10/00 ,  C07F7/28

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F210/02 ,  C08F210/16 ,  C08F210/18 ,  C08F2420/02 ,  C08F4/65908 ,  C08F4/65912 ,  Y10S526/943

摘要： Group 4 metal constrained geometry complexes comprising a fused ring indenyl derivative ligand, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.

摘要翻译： 公开了包含稠环茚基衍生物配体的第4族金属约束几何配合物，其催化衍生物，其制备方法及其作为烯烃聚合催化剂组分的用途。

公开(公告)号：US20120245400A1

公开(公告)日：2012-09-27

申请号：US13514148

申请日：2010-12-14

申请人： Thomas P. Clark ,  Kevin A. Frazier ,  Francis J. Timmers ,  Brian W. Kolthammer

发明人： Thomas P. Clark ,  Kevin A. Frazier ,  Francis J. Timmers ,  Brian W. Kolthammer

IPC分类号： C07C4/06

CPC分类号： C07C11/02 ,  C07C5/2587 ,  C07C6/04 ,  C07C2531/22

摘要： Methods for producing alpha-olefins. The methods include selectively isomerizing an alpha-olefin to a mixture of beta-olefins and ethenolyzing at least a portion of the mixture of beta-olefins to an alpha-olefin.

摘要翻译： α-烯烃的制备方法。 所述方法包括将α-烯烃选择性异构化为β-烯烃的混合物，并将至少一部分β-烯烃的混合物乙烯化至α-烯烃。

公开(公告)号：US08211949B2

公开(公告)日：2012-07-03

申请号：US12211583

申请日：2008-09-16

申请人： Pierre T. Varineau ,  Brian W. Kolthammer ,  Aaron W. Sanders ,  David A. Wilson ,  Kara S. Weber ,  Robert Kirk Thompson ,  Cynthia L. Rand ,  Thomas C. Eisenschmid

发明人： Pierre T. Varineau ,  Brian W. Kolthammer ,  Aaron W. Sanders ,  David A. Wilson ,  Kara S. Weber ,  Robert Kirk Thompson ,  Cynthia L. Rand ,  Thomas C. Eisenschmid

IPC分类号： C09K3/00 ,  C11D1/12 ,  C11D1/68 ,  C11D1/722 ,  C11D1/40 ,  C11D1/825 ,  C07C309/20 ,  C07C209/24 ,  C07C45/50 ,  C07C27/20 ,  B01F17/02 ,  B01F17/16 ,  B01F17/38 ,  B01F17/32 ,  B01D12/00

CPC分类号： C07C2/36 ,  C07C29/16 ,  C07C43/11 ,  C07C209/26 ,  C07C303/06 ,  C07C2531/24 ,  C08F110/02 ,  Y10S516/909 ,  Y10S516/914 ,  Y10S516/92 ,  C07C211/02 ,  C07C309/20 ,  C07C31/125

摘要： Novel mixtures of long-chain (C10-C20) olefins are functionalized by conversion to aldehydes using an OXO process, or to sulfates, sulfonates, sulfones, sulfides, or sulfoxides by direct sulfonation. The aldehydes may then be hydrogenated to form alcohols, or aminated to form amines or amides. The olefins starting mixture may be acquired as a byproduct of the tetramerization of ethylene in the presence of certain chromium-containing tetramerization catalysts. The functionalized mixtures, and derivatives prepared therefrom such as alkoxylates prepared from the alcohols, may be useful as surfactants that may offer improved performance in many applications, while their preparation based on a byproduct mixture reduces their cost and also reduces waste-handling issues for this non-targeted stream.

摘要翻译： 长链（C10-C20）烯烃的新型混合物通过使用OXO方法转化为醛官能化，或通过直接磺化转化为硫酸盐，磺酸盐，砜，硫化物或亚砜。 然后可将醛氢化形成醇，或胺化形成胺或酰胺。 烯烃起始混合物可以在某些含铬四聚催化剂存在下作为乙烯四聚的副产物获得。 官能化混合物和由其制备的衍生物，例如由醇制备的烷氧基化物，可用作可在许多应用中提供改进性能的表面活性剂，而其基于副产物混合物的制备降低了它们的成本，并且还减少了废物处理问题 非目标流。