摘要:
Novel mixtures of long-chain (C10-C20) olefins are functionalized by conversion to aldehydes using an OXO process, or to sulfates, sulfonates, sulfones, sulfides, or sulfoxides by direct sulfonation. The aldehydes may then be hydrogenated to form alcohols, or aminated to form amines or amides. The olefins starting mixture may be acquired as a byproduct of the tetramerization of ethylene in the presence of certain chromium-containing tetramerization catalysts. The functionalized mixtures, and derivatives prepared therefrom such as alkoxylates prepared from the alcohols, may be useful as surfactants that may offer improved performance in many applications, while their preparation based on a byproduct mixture reduces their cost and also reduces waste-handling issues for this non-targeted stream.
摘要:
Disclosed is a monoazo metal complex represented by the formula (1) wherein R1 represents a hydrogen atom, a C1-C4 alkyl group, a C1-C4 alkoxy group, a chlorine atom, a bromine atom or a nitro group; M represents a hydrogen atom, a sodium, a potassium, a magnesium, a calcium, a barium or an aluminum; Mn+ represents a n-valent cation; Metal represents Ni, Fe, Cu, Co or Al; m represents an integer of 1 or 2; and n represents an integer of 1, 2 or 3.
摘要:
A colored composition for color filter contains a pigment carrier made of a transparent resin, a precursor thereof, or a mixture thereof, an organic pigment, and a pigment-dispersing agent comprising a quinoline derivative represented by the following General formula (1) or (2), or an amine or metal salt thereof, and a color filter comprises filter segments formed with the color composition: where X represent a halogen atom selected from chlorine, bromine and iodine; n and m each independently represent the number of halogen atoms X, and are each an integer of 0 to 4.
摘要:
Imadazoline-based amphoacetates of higher purity, containing essentially negligible amounts of unalkylated amido amines, lower amounts of glycolic acid salts and monochloroacetate salts, superior to currently available conventional amphoacetates, are provided. This is demonstrated by their improved surface-active properties. Lower inherent irritation properties may be expected due to improved purity.The higher purity amphoacetates can be obtained via processes utilizing precise pH control during the reaction of imidazoline, or its open-chain derivatives, with alkylating agents, e.g. sodium monochloroacetate. The pH can be controlled by adding the base slowly or automatically in response to a pH metering device to maintain a constant pH, or by a series of staged additions which are calculated to maintain pH within a stated range. The reaction may also be carried out by conducting the initial hydrolysis of the imidazoline ring structure, followed by alkylation. These higher-purity amphoacetates contain essentially fully alkylated products and lower amounts of glycolic acid derivatives, even though a ratio of SMCA to substituted imidazoline, or its open-ring derivative, of less than 1.5:1.0 and close to 1.0:1.0 is used.
摘要:
Novel pigment formulations which comprise at least one organic pigment selected from the class consisting of perylene, perinone, quinacridone, azo, benzimidazolone, anthraquinone or anthanthrone pigments and at least one pigment-dispersing agent of the formula (I) ##STR1## have improved rheological and coloristic properties, in particular in aqueous and nonaqueous coating systems.
摘要:
Linear, unsubstituted quinacridone pigments of the .beta.-phase can be produced in an environmentally friendly manner bya) cyclizing 2,5-dianilinoterephthalic acid in polyphosphoric acid or a polyphosphoric ester to the quinacridone,b) then hydrolyzing the quinacridone with water at a temperature of at least 40.degree. C., preferably at from 60.degree. to 100.degree. C., to obtain a finely divided quinacridone pigment crude which is predominantly in the .alpha.-phase,c) then optionally wet grinding the finely divided quinacridone pigment crude from b) (pre-pigment), andd) then heating the crude pigment from b) or the pre-pigment from c) to a temperature between 120.degree. and 200.degree. C. in the presence of from 0.1 to 1.5 times the amount of an inorganic base, based on the weight of the crude pigment, in an inert liquid medium (solvent finish).To improve the depth and hue of the color, an oxidative treatment with a peroxodisulfate can be carried out subsequently.
摘要:
The invention relates to reaction products prepared from(a) organic polyisocyanates,(b) 0.005 to 0.9 equivalents of a C.sub.6-24 alcohol per equivalent of NCO or latent NCO present in component (a),(c) 0.1 to 0.995 mol of cyanamide per equivalent of NCO or latent NCO present in component (a), and(d) ammonia or a volatile amine as neutralizing agent for the cyanamide groups of component (c),with the proviso that the reaction products are free from polyester and polyether groups and from halogen atoms.
摘要:
Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.
摘要:
The synthesis of quaternary five membered N-n-alkyl-heterocycles, especially of 4-hydroxy-N(1)-n-alkyl-imidazolium, 2,5-substituted N(3)-n-alkyl-thiazolium and substituted N(2) pyrazolium salts are described. The N-surfactants obtained have a very small critical micelle concentration (CMC) of 10.sup.-5 -10.sup.-7 Mol/Liter, and are capable of forming micelles of different sizes and forms depending on the nature of the anions. The N-detergents can be used as pharmaceuticals.
摘要:
The synthesis of quaternary five membered N-n-alkyl-heterocycles, especially of 4-hydroxy-N(1)-n-alkyl-imidazolium, 2,5-substituted N(3)-n-alkyl-thiazolium and substituted N(2) pyrazolium salts are described. The N-surfactants obtained have a very small critical micelle concentration (CMC) of 10.sup.-5 -10.sup.-7 Mol/Liter, and are capable of forming micelles of different sizes and forms depending on the nature of the anions. The N-detergents can be used as pharmaceuticals.