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    Process for the formation of direct positive images
    1.
    发明授权
    Process for the formation of direct positive images 失效
    形成直接正面图像的过程

    公开(公告)号：US4954427A

    公开(公告)日：1990-09-04

    申请号：US60790

    申请日：1987-06-12

    申请人： Noriyuki Inoue ,  Tetsuro Kojima ,  Tatsuo Heki ,  Shigeo Hirano

    发明人： Noriyuki Inoue ,  Tetsuro Kojima ,  Tatsuo Heki ,  Shigeo Hirano

    IPC分类号： G03C1/06 ,  G03C1/36 ,  G03C1/485 ,  G03C7/00 ,  G03C7/30 ,  G03C7/407

    CPC分类号： G03C1/48546 ,  G03C1/061 ,  G03C2001/108 ,  Y10S430/141

    摘要： A process for the formation of direct positive images comprising (1) imagewise exposing to light, a light-sensitive material comprising a photographic emulsion layer containing unfogged internal latent image type silver halide particles on at least one support, and (2) developing the light-sensitive material in the presence of a nucleating agent and at least one nucleation accelerator of general formula (I):A--(Y).sub.n R].sub.m (I)wherein A represents a group which is adsorbed by a silver halide; Y represents a divalent linkage group consisting of atoms or atomic groups selected from the group consisting of a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom; R represents an organic group containing at least one of a thioether group, an amino group, an ammonium group, an ether group, and a heterocyclic group; n represents an integer of 0 or 1; and m represents an integer of 1 or 2 to form direct positive images.

    摘要翻译： 一种用于形成直接阳性图像的方法，包括（1）成像曝光，包含在至少一个载体上含有未雾化的内部潜像型卤化银颗粒的照相乳剂层的感光材料，和（2）显影光 在存在成核剂和至少一种通式（I）的成核促进剂的情况下：A-（Y）nR] m（I）其中A表示被卤化银吸附的基团; Y表示由选自氢原子，碳原子，氮原子，氧原子和硫原子的原子或原子团组成的二价连接基团; R表示含有硫醚基，氨基，铵基，醚基和杂环基中的至少一个的有机基团; n表示0或1的整数; m表示1或2的整数，形成直接正像。

    Process for forming direct-positive image
    2.
    发明授权
    Process for forming direct-positive image 失效
    形成直接正像的过程

    公开(公告)号：US4871653A

    公开(公告)日：1989-10-03

    申请号：US67850

    申请日：1987-06-30

    申请人： Noriyuki Inoue ,  Tatsuo Heki ,  Tetsuro Kojima

    发明人： Noriyuki Inoue ,  Tatsuo Heki ,  Tetsuro Kojima

    IPC分类号： G03C1/485 ,  G03C5/305 ,  G03C7/30 ,  G03C7/407

    CPC分类号： G03C1/48546 ,  G03C5/305 ,  Y10S430/141

    摘要： A process for forming a direct-positive image by developing an imagewise exposed photosensitive material, having on a support at least one photographic emulsion layer containing nonprefogged silver halide grains capable of forming an internal latent image, in which development is carried out in the presence of a combination of a nucleating agent and at least one compound having at least one mercapto group selected from a tetrazaindene, a triazaindene, and a pentaazaindene. The hydrogen atom of which mercapto group may optionally be further substituted with an alkali metal atom or an ammonium group. The invention process provides rapid and consistent formation of direct-positive images having high maximum density and low minimum density.

    摘要翻译： 通过显影成像曝光的感光材料形成直接正像的方法，在载体上具有至少一个含有能够形成内部潜像的非离子卤化银颗粒的照相乳剂层，其中在存在 成核剂和至少一种具有至少一个巯基的化合物的组合，所述巯基选自四嗪，三氮杂茚和五氮杂茚。 巯基可以任选地被碱金属原子或铵基取代的氢原子。 本发明方法提供了快速且一致地形成具有高最大密度和低最小密度的直接正像。

    Method for forming a direct positive image from a material comprising a nucleation accelerator
    3.
    发明授权
    Method for forming a direct positive image from a material comprising a nucleation accelerator 失效
    从包含成核促进剂的材料形成直接正像的方法

    公开(公告)号：US5037726A

    公开(公告)日：1991-08-06

    申请号：US280904

    申请日：1988-12-07

    申请人： Tetsuro Kojima ,  Noriyuki Inoue

    发明人： Tetsuro Kojima ,  Noriyuki Inoue

    IPC分类号： G03C1/485

    CPC分类号： G03C1/48546 ,  Y10S430/141

    摘要： A method for forming a direct positive image having a high Dmax and a low Dmin, which comprises image-wise exposing a photographic light-sensitive material having on a support at least one photographic emulsion layer containing unprefogged internal latent image-type silver halide grains and developing the photographic light-sensitive material after or while fogging to form direct positive image, wherein the aforesaid development is performed in the existence of at least one compound selected from the group consisting of compounds represented by formula (I), (II), (III), (IV), (V) or (VI), acid salts of compounds represented by formula (I) to (IV) provided substituents thereof contain an amino group, and acid salts of compound represented by formula (V) or (VI); ##STR1## wherein symbols are defined as in claim 1.

    摘要翻译： 一种用于形成具有高Dmax和低Dmin的直接正像的方法，该方法包括以下步骤：成像曝光具有载体的照相感光材料，所述照相感光材料至少含有未研磨的内部潜像型卤化银颗粒的照相乳剂层和 在雾化之后或同时显影照相感光材料以形成直接正像，其中上述显影是在存在至少一种选自由式（I），（II），（II），（II） III），（Ⅳ），（Ⅴ）或（Ⅵ）所示，由式（I）至（Ⅳ）表示的化合物的酸盐提供的取代基含有氨基，式（Ⅴ）或 六）; （VI）其中符号如权利要求1中所定义，其中符号被定义为如图1所示。

    Method for forming a direct positive image
    4.
    发明授权
    Method for forming a direct positive image 失效
    形成直接正像的方法

    公开(公告)号：US4968596A

    公开(公告)日：1990-11-06

    申请号：US266605

    申请日：1988-11-02

    申请人： Noriyuki Inoue ,  Shigeo Hirano ,  Tetsuro Kojima ,  Mitsura Yamamoto ,  Satoshi Nagaoka

    发明人： Noriyuki Inoue ,  Shigeo Hirano ,  Tetsuro Kojima ,  Mitsura Yamamoto ,  Satoshi Nagaoka

    IPC分类号： G03C1/485

    CPC分类号： G03C1/48546 ,  Y10S430/141

    摘要： A method for forming a direct positive image comprising the steps of:(a) imagewise exposing a photographic light-sensitive material composed of a support having thereon at least one unprefogged internal latent image type silver halide light-sensitive emulsion layer; and(b) developing the exposed photographic light-sensitive material to form a direct positive image in the presence of at least one nucleating agent represented by formula (N-I); ##STR1## wherein Z.sup.1 represents nonmetal atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring, a 5-membered or 6-membered heterocyclic ring fused with an aromatic ring, or a 5-membered or 6-member heterocyclic ring fused with another heterocyclic ring; R.sup.1 represents an aliphatic group; X represents ##STR2## Q represents a nonmetallic atomic group necessary for forming a 4-membered to 12-membered nonaromatic hydrocarbon ring or a 4-membered to 12-membered nonaromatic heterocyclic ring; provided that at least one of R.sup.1, Z.sup.1 and Q is substituted with an alkynyl group; Y represents a counter ion required for charge balance; and n is a number required for charge balance; or Z.sup.1 contains a heterocyclic quaternary ammonium salt completed by said Z.sup.1 via a linkage group.

    摘要翻译： 一种用于形成直接正像的方法，包括以下步骤：（a）成像曝光由其上具有至少一个未反光内部潜像型卤化银感光乳剂层的支撑体组成的照相感光材料; 和（b）在存在由式（N-I）表示的至少一种成核剂的情况下，显影曝光的照相感光材料以形成直接正像; （NI）其中Z1表示形成5元或6元杂环所需的非金属原子团，与芳环稠合的5元或6元杂环，或5元或6元杂环， 与另一个杂环稠合的杂环; R1表示脂肪族基团; X表示形成4元〜12元非芳香烃环或4元〜12元非芳香族杂环所必需的非金属原子团; 条件是R1，Z1和Q中的至少一个被炔基取代; Y表示电荷平衡所需的抗衡离子; n是电荷平衡所需的数字; 或Z 1包含通过连接基团由所述Z1完成的杂环季铵盐。

    Process for forming direct positive color image
    7.
    发明授权
    Process for forming direct positive color image 失效
    形成直接正彩色图像的过程

    公开(公告)号：US4933265A

    公开(公告)日：1990-06-12

    申请号：US317142

    申请日：1989-02-23

    申请人： Noriyuki Inoue ,  Tatsuo Heki ,  Tetsuro Kojima ,  Shinji Ueda

    发明人： Noriyuki Inoue ,  Tatsuo Heki ,  Tetsuro Kojima ,  Shinji Ueda

    IPC分类号： C07D235/28 ,  C07D249/12 ,  C07D263/58 ,  C07D285/12 ,  C07D285/125 ,  C07D285/135 ,  C07D521/00 ,  G03C1/485 ,  G03C7/392 ,  G03C7/413

    CPC分类号： C07D263/58 ,  C07D231/12 ,  C07D233/56 ,  C07D235/28 ,  C07D249/08 ,  C07D249/12 ,  C07D285/125 ,  C07D285/135 ,  G03C1/48546 ,  G03C7/3924 ,  G03C7/413

    摘要： A process for forming a direct positive color image is disclosed, the process comprising imagewise exposing a photosensitive material containing at least one emulsion layer of silver halide of internal latent image type, which has not been preliminarily fogged, and a color image-forming coupler; developing said material using a surface developing solution containing an aromatic primary amine color developing agent in the presence of a nucleating agent and/or in the condition that fogging exposure is carried out prior to the developing step or during the developing step; bleaching; and fixing, wherein said color coupler is a compound which is in itself substantially nondiffusible, and capable of forming or releasing a substantially nondiffusible dye upon oxidative coupling with said aromatic primary amine color developing agent and said development processing is carried out at a pH of 11.5 or less using a developing solution containing substantially no benzyl alcohol in the presence of at least one compound selected from the group consisting of the compounds represented by the general formula (I)A[(Y.sup.1).sub.n R].sub.m

    摘要翻译： 公开了一种用于形成直接正彩色图像的方法，该方法包括成像曝光含有至少一种尚未预先雾化的内部潜像型卤化银乳剂层的感光材料和彩色成像耦合器; 在成核剂存在下和/或在显影步骤之前或显影步骤中进行雾化曝光的条件下，使用含有芳族伯胺彩色显影剂的表面显影溶液显影所述材料; 漂; 和固定，其中所述着色剂是本身基本上不可扩散的化合物，并且能够在与所述芳族伯胺显色剂氧化偶联时形成或释放基本上不可扩散的染料，并且所述显影处理在pH为11.5的条件下进行 或更少使用在至少一种选自由通式（I）A [（Y1）nR] m表示的化合物组成的组的存在下，基本上不含苄醇的显影溶液

    Silver halide color photographic lightsensitive material
    8.
    发明授权
    Silver halide color photographic lightsensitive material 失效
    卤化银彩色照相感光材料

    公开(公告)号：US06541192B2

    公开(公告)日：2003-04-01

    申请号：US09989416

    申请日：2001-11-21

    申请人： Yasuhiro Kato ,  Hisashi Mikoshiba ,  Naoto Matsuda ,  Tetsuro Kojima

    发明人： Yasuhiro Kato ,  Hisashi Mikoshiba ,  Naoto Matsuda ,  Tetsuro Kojima

    IPC分类号： G03C108

    CPC分类号： C07D487/04 ,  G03C7/383

    摘要： A silver halide color photographic lightsensitive material comprising at least one layer on a support, wherein the at least one layer contains a coupler represented by formula (I) below wherein X represents a hydrogen atom, halogen atom, arylthio group, carbamoyloxy group, heterocyclic carbonyloxy group, etc., each of R1 and R2 represents an electron-attracting group having a Hammett's substituent constant &sgr;p value of not less than 0.20, the sum of the &sgr;p values of R1 and R2 being not less than 0.65, each of R3 and R4 represents a alkyl group, alkenyl group, alkynyl group, cycloalkyl group, cycloalkenyl group, etc., or alternatively, R3 and R4 may bond together to form a ring structure; and each of R11 to R15 independently represents a hydrogen atom or a substituent.

    摘要翻译： 一种卤化银彩色照相感光材料，其在载体上包含至少一层，其中所述至少一层包含由下式（I）表示的成色剂，其中X表示氢原子，卤素原子，芳硫基，氨基甲酰氧基，杂环羰氧基 等等，R1和R2各自表示哈米特取代基常数sigmap值不小于0.20的吸电子基团，R1和R2的sigmap值之和不小于0.65，R3和R4各自表示 烷基，烯基，炔基，环烷基，环烯基等，或者R3和R4可以键合在一起形成环结构; R 11〜R 15各自独立地表示氢原子或取代基。

    Method for forming images
    9.
    发明授权
    Method for forming images 失效
    图像形成方法

    公开(公告)号：US5278025A

    公开(公告)日：1994-01-11

    申请号：US931508

    申请日：1992-08-21

    申请人： Hisashi Okamura ,  Kazunobu Katoh ,  Tetsuro Kojima

    发明人： Hisashi Okamura ,  Kazunobu Katoh ,  Tetsuro Kojima

    IPC分类号： G03C1/06 ,  G03C1/34 ,  G03C1/43 ,  G03C5/305 ,  G03C5/26 ,  G03C5/30

    CPC分类号： G03C1/061 ,  G03C1/34 ,  G03C1/43 ,  G03C5/305 ,  Y10S430/158

    摘要： A method for forming an image comprising the steps of: (a) imagewise exposing silver halide photographic materials; where said photographic material contains (1) a compound represented by formula (I) ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, or an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and A.sub.1 and A.sub.2 both represent a hydrogen atom, or one of A.sub.1 or A.sub.2 represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group, and (2) a redox compound that can release a development inhibitor when oxidized; and (b) subjecting said imagewise exposed silver halide photographic materials to development-processing where a bath used in said development-processing contains a nucleation development accelerator.

    摘要翻译： 一种用于形成图像的方法，包括以下步骤：（a）成像曝光卤化银照相材料; 其中所述照相材料包含（1）由式（I）表示的化合物（*化学结构*）（I）其中R 1表示脂族基团或芳族基团; R2表示氢原子，烷基或芳基，烷氧基，芳氧基，氨基，氨基甲酰基或氧羰基; G1表示羰基，磺酰基，磺氧基，（*化学结构*）或亚氨基亚甲基; 和A1和A2均表示氢原子，或A1或A2中的一个表示氢原子，另一个表示取代或未取代的烷基磺酰基，取代或未取代的芳基磺酰基或取代或未取代的酰基，（2） 氧化还原化合物，当氧化时可释放显影抑制剂; 和（b）对所述成像曝光的卤化银照相材料进行显影处理，其中所述显影处理中使用的浴含有成核显影促进剂。