Polyurethane dispersion (PUD) with improved isopropanol resistance, flexibility and softness
    4.
    发明授权
    Polyurethane dispersion (PUD) with improved isopropanol resistance, flexibility and softness 有权
    聚氨酯分散体(PUD)具有改善的异丙醇耐力,柔韧性和柔软性

    公开(公告)号:US07045573B2

    公开(公告)日:2006-05-16

    申请号:US10677882

    申请日:2003-10-02

    IPC分类号: C08G18/10

    摘要: Isocyanate-functional polyurethane prepolymers and aqueous dispersions therefrom which are useful for the production of flat materials having excellent resistance to alcoholic solvents are described. The prepolymers are prepared by reacting: A) an isocyanate selected from the group consisting of i) an aliphatic and/or a cycloaliphatic isocyanate, ii) a mixture of an aromatic isocyanate and an aliphatic and/or a cycloaliphatic isocyanate, B) a di- or polyhydroxy compound having a number average molecular weight of from 700 to about 16,000, and C) optionally, a dihydroxy and/or polyhydroxyl compound having a number average molecular weight of less than 700, with the provisos that a) at least one of components A), B or C) has a functionality of more than 2 and b) if both component A) and component B) are difunctional, component C) cannot be a trihydroxy component of the formula: R—(OH)3  where R is a saturated straight chain or branched chain aliphatic group of from 2 to 8 carbon atoms.

    摘要翻译: 描述了可用于生产具有优异的耐酒精性的平坦材料的异氰酸酯官能聚氨酯预聚物及其水分散体。 预聚物通过以下反应制备:A)选自i)脂族和/或脂环族异氰酸酯的异氰酸酯,ii)芳族异氰酸酯和脂族和/或脂环族异氰酸酯的混合物,B)二 - 或数均分子量为700至约16,000的多羟基化合物,和C)任选的数均分子量小于700的二羟基和/或多羟基化合物,条件是a)至少一种 组分A),B或C)具有大于2的官能团,和b)如果组分A)和组分B)均为双官能团,组分C)不能是下式的三羟基组分:<β在线式描述 =“In-line Formulas”end =“lead”?> R-(OH)<3> <?in-line-formula description =“In-line Formulas”end =“tail”?> where R是2至8个碳原子的饱和直链或支链脂族基团。

    Aqueous polyurethane dispersions
    7.
    发明授权
    Aqueous polyurethane dispersions 有权
    水性聚氨酯分散体

    公开(公告)号:US06284836B1

    公开(公告)日:2001-09-04

    申请号:US09411096

    申请日:1999-10-04

    IPC分类号: C08J300

    摘要: Aqueous polyurethane dispersions containing a polyurethane, composed of a) at least one polyol having an average molecular weight, determined as the number average, of 500-6000 g/mol, preferably 1000 to 4000, in particular 1500 to 3000 g/mol, b) at least one polyol, preferably diol, having a molecular weight of less than 500 g/mol, preferably of 61 to 499 g/mol, c) at least one aliphatic polyisocyanate, preferably diisocyanate, d) at least one diol having a molecular weight of less than 450 g/mol, which carries one or more ionic groups and/or one or more potentially ionic groups, preferably at least one carboxyl group, e) at least one amine which is reactive towards NCO groups, carries hydroxyl groups and has an OH functionality of 1 to 6, f) water and optionally g) a monoalcohol, characterized in that the molar ratio of polyol of the component a) to the sum of the polyols b) and d) is 1:1.5 to 1:4, preferably 1:2 to 1:3, the molar ratio of the sum of the polyols a), b) and d) to the polyisocyanate c) is 1:1.1 to 1:2.5, preferably 1:1.2 to 1:1.7, the OH functionality of the polyurethane being 2 to 6, preferably 2 to 4, and the average molecular weight, determined as the number average, of the polyurethane being less than 15,000, preferably from 2500 to 10,000, in particular from 3000 to 7000, g/mol.

    摘要翻译: 含有聚氨酯的水性聚氨酯分散体由以下组成:a)至少一种数均分子量为500-6000g / mol,优选1000-4000,特别是1500-3000g / mol的平均分子量的多元醇,b) 至少一种分子量小于500g / mol,优选61至499g / mol的多元醇,优选二醇,c)至少一种脂族多异氰酸酯,优选二异氰酸酯,d)至少一种具有分子量的二醇 其携带一个或多个离子基团和/或一个或多个潜在的离子基团,优选至少一个羧基,e)至少一个对NCO基团具有反应性的胺,其携带羟基并具有 1至6的OH官能团,f)水和任选地g)一元醇,其特征在于组分a)的多元醇与多元醇b)和d)之和的摩尔比为1:1.5至1:4, 优选1:2至1:3,多元醇a),b)和d)之和与多异氰酸酯的摩尔比 苯甲酸酯c)为1:1.1至1:2.5,优选1:1.2至1:1.7,聚氨酯的OH官能度为2至6,优选2至4,平均分子量为数均分子量 聚氨酯小于15,000,优选2500至10,000,特别是3000至7000g / mol。