Method for the production of thermally cross-linked laser engravable flexographic elements
    2.
    发明授权
    Method for the production of thermally cross-linked laser engravable flexographic elements 有权
    用于生产热交联激光可雕刻柔版印刷元件的方法

    公开(公告)号:US06794115B2

    公开(公告)日:2004-09-21

    申请号:US10250867

    申请日:2003-07-29

    IPC分类号: G03F711

    CPC分类号: B41C1/05 Y10S430/146

    摘要: Laser-engravable flexographic printing elements including a thermally crosslinked, elastomeric, laser-engravable relief-forming layer E are made by producing a multilayer composite which has at least a two-layer composite formed of a depot layer D and an uncrosslinked precursor layer V for the relief-forming layer E which is directly adjacent to the depot layer D. Optionally, the multilayer composite may include further layers, such as support foils or films and/or protective films. The precursor layer V most preferably includes at least one elastomeric binder, and at least one ethylenically unsaturated monomer and, optionally an absorber for laser radiation and/or further additives. The depot layer D most preferably includes at least one elastomeric binder, and at least one thermally decomposing polymerization initiator and, optionally, an absorber for laser radiation and/or further additives. The thermally decomposing polymerization initiators are allowed to diffuse out of the depot layer D into the precursor layer V. If desired the depot layer D may be removed. Thermal crosslinking of the precursor layer V thereby yields the crosslinked elastomeric, laser-engravable, relief-forming layer E.

    摘要翻译: 激光可雕刻柔性版印刷元件,包括热交联的,弹性的,可激光雕刻的浮雕形成层E通过制备多层复合材料制成,所述多层复合材料具有至少两层复合材料,其由贮存层D和未交联的前体层V形成, 形成沉积层E直接邻近贮存层D.任选地,多层复合物可以包括另外的层,例如支撑箔或膜和/或保护膜。 前体层V最优选包括至少一种弹性体粘合剂和至少一种烯属不饱和单体和任选的用于激光辐射的吸收剂和/或其它添加剂。 贮库层D最优选包括至少一种弹性粘合剂和至少一种热分解聚合引发剂和任选的用于激光辐射的吸收剂和/或其它添加剂。 允许热分解聚合引发剂从贮存层D扩散到前体层V中。如果需要,可以除去贮存层D. 前体层V的热交联由此产生交联的弹性体,激光可雕刻的浮雕形成层E.

    Method for laser engraving flexographic printing forms, and printing forms obtained thereby
    3.
    发明授权
    Method for laser engraving flexographic printing forms, and printing forms obtained thereby 有权
    激光雕刻柔版印刷版的方法以及由此获得的印刷形式

    公开(公告)号:US06776095B2

    公开(公告)日:2004-08-17

    申请号:US10297208

    申请日:2002-12-04

    IPC分类号: B41C105

    CPC分类号: B41C1/05 B41N1/12

    摘要: A process for the production of flexographic printing plates by laser engraving, in which the recording layer of a crosslinkable, laser-engravable flexographic printing element is crosslinked by the combination of a full-area crosslinking step with a crosslinking step which only acts at the surface, and a printing relief is engraved into the crosslinked recording layer by means of a laser, and flexographic printing plates obtainable by the process.

    摘要翻译: 通过激光雕刻生产柔性版印刷版的方法,其中可交联的可激光可雕刻柔性版印刷元件的记录层通过全面交联步骤与只在表面上起作用的交联步骤的组合进行交联 并且通过激光将印刷浮雕刻印到交联记录层中,以及通过该方法可获得的柔性版印刷版。

    Preparation of crosslinkable water-soluble or water-dispersible compositions and radiation-sensitive mixtures obtainable therefrom
    8.
    发明授权
    Preparation of crosslinkable water-soluble or water-dispersible compositions and radiation-sensitive mixtures obtainable therefrom 失效
    制备可交联的水溶性或水分散性组合物和由其获得的辐射敏感性混合物

    公开(公告)号:US06368772B1

    公开(公告)日:2002-04-09

    申请号:US09324713

    申请日:1999-06-03

    IPC分类号: G03C173

    CPC分类号: G03F7/0388

    摘要: Process for functionalizing a water-soluble or water-dispersible polymeric organic binder, in which unmodified, water-soluble or water-dispersible polymeric organic binders are reacted with one or more polar aprotic swelling agents which are compatible with the binder, with thorough mixing with one or more compounds which have groups capable of free radical polymerization, compositions obtainable thereby and radiation-sensitive mixtures which contain, as essential components, the above composition, at least one photopolymerization initiator, if required one or more ethylenically unsaturated, photopolymerizable low molecular weight compounds which are compatible with the polymeric binder and further conventional additives and/or assistants, and radiation-sensitive letterpress or relief printing plates which can be produced therefrom.

    摘要翻译: 官能化水溶性或水分散性聚合物有机粘合剂的方法,其中未改性的水溶性或水分散性聚合物有机粘合剂与一种或多种与粘合剂相容的极性非质子溶胀剂反应,与 具有能够进行自由基聚合的基团的一种或多种化合物,由此获得的组合物和含有作为必要组分的上述组合物的辐射敏感性混合物,如果需要,至少一种光聚合引发剂一种或多种烯属不饱和的可光聚合的低分子量 与聚合物粘合剂和其它常规添加剂和/或辅助剂相容的化合物,以及可由其生产的辐射敏感凸版印刷版或凸版印刷版。

    Photosensitive recording element and production of a relief printing
plate
    9.
    发明授权
    Photosensitive recording element and production of a relief printing plate 失效
    感光记录元件和凸版印刷版的制作

    公开(公告)号:US5468596A

    公开(公告)日:1995-11-21

    申请号:US372829

    申请日:1995-01-13

    CPC分类号: G03F7/031

    摘要: A photosensitive recording element comprises(A) a dimensionally stable substrate,(B) a photopolymerizable relief-forming recording layer and, if required, an adhesion-promoting layer arranged between (A) and (B), a release layer (C) applied to that side of the recording layer (B) which faces away from the substrate (A), and, if required, a cover sheet (D) applied thereon, the photopolymerizable relief-forming recording layer (B) containingb.sub.1) at least one polymeric binder,b.sub.2) at least one photopolymerizable olefinically unsaturated monomer which is compatible with b.sub.1),b.sub.3) at least one photopolymerization initiator andb.sub.4) at least one aryl alkyl ketone,and is suitable for the production of relief printing plates.

    摘要翻译: 感光记录元件包括(A)尺寸稳定的基材,(B)可光聚合的凸版形成记录层,如果需要,在(A)和(B)之间布置有粘合促进层,施加剥离层(C) 到达记录层(B)的背离基板(A)的一侧,并且如果需要,涂覆在其上的覆盖片(D),所述光聚合缓冲形成记录层(B)含有b1)至少一个 聚合物粘合剂,b2)至少一种与b1),b3)相容的可光聚合的烯属不饱和单体,b3)至少一种光聚合引发剂和b4)至少一种芳基烷基酮,并且适于制备凸版印刷版。