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公开(公告)号：US06635597B1
公开(公告)日：2003-10-21
申请号：US09463713
申请日：2000-05-12
申请人： Tobin J. Marks , Liting Li , You-Xian Chen , Mark H. McAdon , Peter N. Nickias
发明人： Tobin J. Marks , Liting Li , You-Xian Chen , Mark H. McAdon , Peter N. Nickias
IPC分类号： B01J2102
CPC分类号： C07C17/093 , C07F5/027 , C07F17/00 , C07F17/02 , C08F4/6592 , C08F4/65925 , C08F10/00 , C08F110/02 , C07C25/22 , C08F4/65908 , C08F4/643
摘要： A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 1000 non-hydrogen atoms.
摘要翻译： 一种催化剂活化剂，特别适用于活化金属3-10金属络合物，用于聚合烯属不饱和可聚合单体，特别是烯烃，包括中性（路易斯酸）或电荷分离（阳离子/阴离子对），其包含硼 配体含有含有10至1000个非氢原子的氟化有机基团。
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公开(公告)号：US06268445B1
公开(公告)日：2001-07-31
申请号：US09424277
申请日：1999-11-19
IPC分类号： C08F452
CPC分类号： C07F5/027 , C08F4/6592 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65908
摘要： A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising two Group 13 metal or metalloid atoms and a ligand structure including at least one bridging group connecting ligands on the two Group 13 metal or metalloid atoms.
摘要翻译： 一种催化剂活化剂，特别适用于活化第3-10族金属的金属络合物，用于聚合包含两个第13族金属或准金属原子的烯属不饱和可聚合单体，特别是烯烃，以及包含至少一个连接基团 第13族金属或准金属原子上的配体。
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3.发明授权
公开(公告)号：US5721185A
公开(公告)日：1998-02-24
申请号：US876268
申请日：1992-05-05
IPC分类号： C08F4/60 , C07F17/00 , C08F4/42 , C08F4/64 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2420/02 , C08F4/65908 , C08F4/6592
摘要： A process for preparing addition polymerization catalysts having a limiting charge separated structure corresponding to the formula: LMX.sup.+ XA.sup.-, wherein: L is a derivative of a substituted delocalized .pi.-bonded group imparting a constrained geometry to the metal active site and containing up to 50 nonhydrogen atoms; M is a metal of Group 4 or the Lanthanide series of the Periodic Table of the Elements; X independently each occurrence is hydride or a hydrocarbyl, silyl or germyl group having up to 20 carbon, silicon or germanium atoms; and A.sup.- is an anion of a Lewis acid, A, having relative Lewis acidity greater than or equal to that of phenylbis(perfluorophenyl)borane, said anion being compatible with the metal cation, the steps of the process comprising contacting a derivative of a Group 4 or Lanthanide metal corresponding to the formula: i LMX.sub.2, wherein L, M, and X are as previously defined, with the Lewis acid, A, under conditions to cause abstraction of X and formation of the anion XA.sup.-.
摘要翻译： 一种制备具有对应于下列通式的极限电荷分离结构的加成聚合催化剂的方法：LMX + XA-，其中：L是取代的离域π键合基团的衍生物，其赋予金属活性位点约束几何形状， 50个非氢原子; M是第4族金属或元素周期表的镧系元素; 独立地，每次出现氢化物或具有至多20个碳，硅或锗原子的烃基，甲硅烷基或甲硅烷基; A是具有大于或等于苯基双（全氟苯基）硼烷的相对路易斯酸度的路易斯酸A的阴离子，所述阴离子与金属阳离子相容，所述方法的步骤包括使 在引起X的抽出和形成阴离子XA-的条件下，与路易斯酸A相对应的式4或镧系金属，其中L，M和X如前所定义。
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4.发明授权&agr;-Olefin/vinylidene aromatic monomer and/or hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers 失效α-烯烃/亚乙烯基芳族单体和/或受阻的脂族或脂环族亚乙烯基单体互聚物公开(公告)号：US06191245B1
公开(公告)日：2001-02-20
申请号：US09254251
申请日：1999-03-02
申请人： Richard E. Campbell, Jr. , Mark H. McAdon , Peter N. Nickias , Jasson T. Patton , Oscar D. Redwine , Francis J. Timmers
发明人： Richard E. Campbell, Jr. , Mark H. McAdon , Peter N. Nickias , Jasson T. Patton , Oscar D. Redwine , Francis J. Timmers
IPC分类号： C08F21208
CPC分类号： C08F12/08 , C08F4/65908 , C08F4/65912 , C08F210/02 , C08F2420/02 , C08F2420/04 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F212/08 , C08F2500/12 , C08F2500/03
摘要： The present invention relates to &agr;-olefin/vinyl aromatic monomer interpolymers with characteristic signals in their carbon 13 NMR spectra. In particular, ethylene/styrene copolymers of the present invention have peaks in the carbon 13 NMR spectra which appear in the chemical shift range 43.70-44.25 ppm, preferably from 43.75-44.25 ppm and 38.0-38.5 ppm, said peaks being at least three times the peak to peak noise. The interpolymers are prepared by polymerizing the appropriate mixture of monomers in the presence of a catalyst such as racemic-(dimethylsilanediyl(2-methyl-4-phenylindenyl)) zirconium dichloride. The polymers of the present invention posses increased modulus as determined from both tensile stress/strain and dynamic mechanical data at comparable vinyl aromatic monomer levels.
摘要翻译： 本发明涉及在其碳13 NMR谱中具有特征信号的α-烯烃/乙烯基芳族单体互聚物。 特别地，本发明的乙烯/苯乙烯共聚物在化学位移范围43.70-44.25ppm，优选43.75-44.25ppm和38.0-38.5ppm中出现的碳13 NMR谱中具有峰，所述峰为至少三倍 峰值到峰值噪声。 通过在催化剂如外消旋 - （二甲基硅烷二基（2-甲基-4-苯基茚基））二氯化锆存在下聚合合适的单体混合物来制备互聚物。 本发明的聚合物具有增加的模量，其由相应的乙烯基芳族单体水平下的拉伸应力/应变和动态机械数据两者确定。
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公开(公告)号：US6034022A
公开(公告)日：2000-03-07
申请号：US325049
申请日：1999-06-03
申请人： Mark H. McAdon , Jasson T. Patton , Peter N. Nickias , Ravi B. Shankar , Francis J. Timmers , Brian W. S. Kolthammer , Daniel D. VanderLende , Steven M. Ueligger
发明人： Mark H. McAdon , Jasson T. Patton , Peter N. Nickias , Ravi B. Shankar , Francis J. Timmers , Brian W. S. Kolthammer , Daniel D. VanderLende , Steven M. Ueligger
CPC分类号： C07F17/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F2420/02 , C08F4/65908 , C08F4/65912 , Y10S526/943
摘要： Group 4 metal constrained geometry complexes comprising a fused ring indenyl derivative ligand, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.
摘要翻译： 公开了包含稠环茚基衍生物配体的第4族金属约束几何配合物，其催化衍生物，其制备方法及其作为烯烃聚合催化剂组分的用途。
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6.发明授权
公开(公告)号：US5965756A
公开(公告)日：1999-10-12
申请号：US949505
申请日：1997-10-14
申请人： Mark H. McAdon , Jasson T. Patton , Peter N. Nickias , Ravi B. Shankar , Francis J. Timmers , Brian W. Kolthammer , Daniel D. VanderLende , Steven M. Ueligger
发明人： Mark H. McAdon , Jasson T. Patton , Peter N. Nickias , Ravi B. Shankar , Francis J. Timmers , Brian W. Kolthammer , Daniel D. VanderLende , Steven M. Ueligger
CPC分类号： C07F17/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F2420/02 , C08F4/65908 , C08F4/65912 , Y10S526/943
摘要： Group 4 metal constrained geometry complexes comprising a fused ring indenyl derivative ligand, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.
摘要翻译： 公开了包含稠环茚基衍生物配体的第4族金属约束几何配合物，其催化衍生物，其制备方法及其作为烯烃聚合催化剂组分的用途。
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7.发明授权Substituted indenyl containing metal complexes and olefin polymerization process 失效取代的含茚基的金属络合物和烯烃聚合方法
公开(公告)号：US6015868A
公开(公告)日：2000-01-18
申请号：US11895
申请日：1998-02-19
申请人： Peter N. Nickias , Mark H. McAdon , Jasson T. Patton , Bernard P. Friedrichsen , Jorge Soto , James C. Stevens , Daniel D. VanderLende
发明人： Peter N. Nickias , Mark H. McAdon , Jasson T. Patton , Bernard P. Friedrichsen , Jorge Soto , James C. Stevens , Daniel D. VanderLende
CPC分类号： C07F17/00 , B01J31/1608 , B01J31/2295 , C08F10/00 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F2420/02 , C08F4/65908 , C08F4/65912 , Y10S526/943
摘要： Group 4 metal complexes comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, fluoro-substituted hydrocarbyl, hydrocarbyloxy-substituted hydrocarbyl, dialkylamino-substituted hydroacrbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, catalytic derivatives thereof and their use as olefin polymerization catalysts are disclosed.
摘要翻译： PCT No.PCT / US96 / 16012 Sec。 371日期1998年2月19日 102（e）1998年2月19日PCT PCT 1996年10月3日PCT公布。 公开号WO97 / 15583 日期：1997年5月1日包括在2或3位被取代的茚基与至少一个选自烃基，氟代取代的烃基，烃氧基取代的烃基，二烷基氨基取代的水解酰基，甲硅烷基，甲基和其混合物的基团的金属络合物， 所述茚基基团还通过二价配体基团与金属共价键合，其催化衍生物及其作为烯烃聚合催化剂的用途。
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公开(公告)号：US09415375B2
公开(公告)日：2016-08-16
申请号：US13639105
申请日：2011-03-30
申请人： Daniela Ferrari , Neelesh J. Rane , Adam Chojecki , Gerolamo Budroni , David G. Barton , Mark H. McAdon , Robert J. Gulotty, Jr. , Dean M. Millar , Palanichamy Manikandan
发明人： Daniela Ferrari , Neelesh J. Rane , Adam Chojecki , Gerolamo Budroni , David G. Barton , Mark H. McAdon , Robert J. Gulotty, Jr. , Dean M. Millar , Palanichamy Manikandan
IPC分类号： B01J23/00 , B01J23/648 , B01J23/652 , B01J23/656 , B01J37/02 , B01J21/04
CPC分类号： B01J23/6482 , B01J21/04 , B01J23/002 , B01J23/6525 , B01J23/6562 , B01J23/6567 , B01J37/0205 , B01J2523/00 , B01J2523/13 , B01J2523/55 , B01J2523/68 , B01J2523/74 , B01J2523/827 , B01J2523/48 , B01J2523/824
摘要： Catalyst compositions for producing mixed alcohols from a synthesis gas feed. The catalyst composition comprises a catalytic metal combination on a catalyst support, a first optional promoter and a second optional promoter, where the catalytic metal combination consists essentially of iridium, vanadium, and molybdenum.
摘要翻译： 用于从合成气进料生产混合醇的催化剂组合物。 催化剂组合物包括在催化剂载体上的催化金属组合，第一任选的促进剂和第二任选的促进剂，其中催化金属组合基本上由铱，钒和钼组成。
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9.发明授权Compositions and method of inhibiting polymerization of vinyl-aryl monomers 有权抑制乙烯基 - 芳基单体聚合的组合物和方法公开(公告)号：US08969498B2
公开(公告)日：2015-03-03
申请号：US13811574
申请日：2011-07-27
申请人： Nathan T. Kendall , Kishore K. Kar , Mark H. McAdon , Krzysztof Matyjaszewski , Laura Mueller , Charles D. Dukes
发明人： Nathan T. Kendall , Kishore K. Kar , Mark H. McAdon , Krzysztof Matyjaszewski , Laura Mueller , Charles D. Dukes
摘要： The invention generally relates to a method of inhibiting polymerization of vinyl aryl monomers, a process for increasing number average molecular weight of a polystyrene, and to an inhibitor composition useful therein.
摘要翻译： 本发明一般涉及一种抑制乙烯基芳基单体的聚合的方法，一种增加聚苯乙烯的数均分子量的方法以及其中可用的抑制剂组合物。
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公开(公告)号：US20130029841A1
公开(公告)日：2013-01-31
申请号：US13639105
申请日：2011-03-30
申请人： Daniela Ferrari , Neelesh J. Rane , Adam Chojecki , Gerolamo Budroni , David G. Barton , Mark H. McAdon , Robert J. Gulotty, JR. , Dean M. Millar , Palanichamy Manikandan
发明人： Daniela Ferrari , Neelesh J. Rane , Adam Chojecki , Gerolamo Budroni , David G. Barton , Mark H. McAdon , Robert J. Gulotty, JR. , Dean M. Millar , Palanichamy Manikandan
IPC分类号： B01J23/652 , B01J23/656
CPC分类号： B01J23/6482 , B01J21/04 , B01J23/002 , B01J23/6525 , B01J23/6562 , B01J23/6567 , B01J37/0205 , B01J2523/00 , B01J2523/13 , B01J2523/55 , B01J2523/68 , B01J2523/74 , B01J2523/827 , B01J2523/48 , B01J2523/824
摘要： Catalyst compositions for producing mixed alcohols from a synthesis gas feed. The catalyst composition comprises a catalytic metal combination on a catalyst support, a first optional promoter and a second optional promoter, where the catalytic metal combination consists essentially of iridium, vanadium, and molybdenum.
摘要翻译： 用于从合成气进料生产混合醇的催化剂组合物。 催化剂组合物包括在催化剂载体上的催化金属组合，第一任选的促进剂和第二任选的促进剂，其中催化金属组合基本上由铱，钒和钼组成。
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