公开(公告)号：US4851590A

公开(公告)日：1989-07-25

申请号：US199750

申请日：1988-05-27

申请人： Tohru Miura ,  Katsuju Watanabe ,  Hitoshi Nakayama ,  Masayuki Furuya ,  Teruyuki Nagata

发明人： Tohru Miura ,  Katsuju Watanabe ,  Hitoshi Nakayama ,  Masayuki Furuya ,  Teruyuki Nagata

IPC分类号： C07C37/86

CPC分类号： C07C37/86

摘要： 2,4-Xylenol can be obtained in high yield and high purity from a crude 2,4-xylenol isomer mixture containing 2,5-xylenol by selectively reacting the 2,5-xylenol with an aldehyde in the presence of an aromatic sulfonic acid, thereby converting the 2,5-xylenol into a xylenol-aldehyde condensate and, subsequently, separating the 2,4-xylenol, e.g., by distillation.

公开(公告)号：US4939306A

公开(公告)日：1990-07-03

申请号：US338210

申请日：1989-04-14

申请人： Tohru Miura ,  Teruyuki Nagata ,  Koju Okazaki ,  Masayuki Furuya ,  Emiko Nishida

发明人： Tohru Miura ,  Teruyuki Nagata ,  Koju Okazaki ,  Masayuki Furuya ,  Emiko Nishida

IPC分类号： C07C37/06 ,  C07C37/52 ,  C07C39/15 ,  C07C39/23

CPC分类号： C07C37/06 ,  C07C37/52 ,  C07C39/23 ,  C07C2101/14

摘要： A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.

公开(公告)号：US4894487A

公开(公告)日：1990-01-16

申请号：US228186

申请日：1988-08-04

申请人： Tohru Miura ,  Masayuki Furuya ,  Teruyuki Nagata

发明人： Tohru Miura ,  Masayuki Furuya ,  Teruyuki Nagata

IPC分类号： B01J23/44 ,  C07C27/00 ,  C07C37/00 ,  C07C39/17 ,  C07C67/00

CPC分类号： C07C37/003 ,  C07C2101/14

摘要： This invention relates to a novel preparation process of 4-(4-hydroxyphenyl)-cyclohexanol, which comprises subjecting 4-(4-hydroxphenyl)-3-cyclohexen-1-ol to reduction. 4-(4-Hydroxyphenyl)-cyclohexanol is a compound useful as a monomer for liquid crystalline polyesters and the like.

公开(公告)号：US4877907A

公开(公告)日：1989-10-31

申请号：US338206

申请日：1989-04-14

申请人： Tohru Miura ,  Teruyuki Nagata ,  Koju Okazaki ,  Masayuki Furuya ,  Emiko Nishida

发明人： Tohru Miura ,  Teruyuki Nagata ,  Koju Okazaki ,  Masayuki Furuya ,  Emiko Nishida

IPC分类号： C07C37/06 ,  C07C37/52 ,  C07C39/15 ,  C07C39/23

CPC分类号： C07C37/06 ,  C07C37/52 ,  C07C39/23 ,  C07C2101/14

摘要： A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.

公开(公告)号：US4873374A

公开(公告)日：1989-10-10

申请号：US178301

申请日：1988-04-06

申请人： Tohru Miura ,  Teruyuki Nagata ,  Koju Okazaki ,  Masayuki Furuya ,  Emiko Nishida

发明人： Tohru Miura ,  Teruyuki Nagata ,  Koju Okazaki ,  Masayuki Furuya ,  Emiko Nishida

IPC分类号： C07C37/06 ,  C07C37/52 ,  C07C39/15 ,  C07C39/23

CPC分类号： C07C37/06 ,  C07C37/52 ,  C07C39/23 ,  C07C2101/14

摘要： A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.

公开(公告)号：US4755616A

公开(公告)日：1988-07-05

申请号：US024967

申请日：1987-03-12

申请人： Tohru Miura ,  Teruyuki Nagata

发明人： Tohru Miura ,  Teruyuki Nagata

IPC分类号： B01J27/06 ,  B01J27/00 ,  C07B61/00 ,  C07C51/347 ,  C07C51/353 ,  C07C62/32 ,  C07C67/343 ,  C07C69/753 ,  C07C62/06

CPC分类号： C07C51/347

摘要： Novel 4,4-bis(4-hydroxyphenyl)cyclohexanecarboxylic acid derivatives. These compounds can be prepared by reacting a cyclohexanone-4-carboxylic acid with a phenol.

摘要翻译： 新的4,4-双（4-羟基苯基）环己烷羧酸衍生物。 这些化合物可以通过使环己酮-4-羧酸与苯酚反应来制备。

公开(公告)号：US5084545A

公开(公告)日：1992-01-28

申请号：US379378

申请日：1989-07-13

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura

IPC分类号： G02B1/04 ,  B29C33/60 ,  B29C39/00 ,  B29C39/02 ,  B29D11/00 ,  B29K75/00 ,  B29K105/32 ,  B29L11/00 ,  C08G18/32 ,  C08G18/38 ,  C08G18/42 ,  C08G18/46 ,  C08G18/48 ,  C08G18/50 ,  C08G18/70 ,  C08G18/72 ,  C08G18/76 ,  C08G18/77 ,  C08G18/78

CPC分类号： B29C33/60 ,  C08G18/3203 ,  C08G18/3221 ,  C08G18/381 ,  C08G18/3863 ,  C08G18/3874 ,  C08G18/3876 ,  C08G18/72 ,  C08G18/76 ,  C08G18/775 ,  C08G18/7893

摘要： The present invention relates to a process for producing a resin useful in plastic lenses, to plastic lenses containing the resin and to a process for producing the lenses.

公开(公告)号：US5753730A

公开(公告)日：1998-05-19

申请号：US700508

申请日：1991-05-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

IPC分类号： B29C33/60 ,  C08G18/38 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/04 ,  C08K5/51

CPC分类号： B29C33/60 ,  C08G18/3863 ,  C08G18/3876 ,  C08G18/73 ,  C08G18/75 ,  C08G18/7628 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/041

摘要： One aspect of the present invention relates to a process for preparing plastic lenses having a high-refractive index comprising forming a mixture containing one or more polyisocyanate compounds; one or more active hydrogen compounds selected from the group consisting of a polyol compound having no sulfur atom, a polyol compound having at least one sulfur atom, and a polythiol compound having at least one sulfur atom in addition to the sulfur atom contained in mercapto group and at least one internal releasing agent and then casting and polymerizing the mixture. A second aspect of the present invention relates to a process for preparing a sulfur-containing urethane resin lens is here disclosed which comprises mixing polyisocyanate having two or more isocyanato groups, polythiol having two or more thiol groups and one or more surface active agent selected from the group consisting of fluorine-containing nonionic surface active agents, silicone-containing nonionic surface active agents, alkyl quaternary ammonium salts and acid phosphoric esters and then cast polymerizing the mixture in a mold made of a glass or a metal. Lenses prepared by the processes are also disclosed.

摘要翻译： 本发明的一个方面涉及一种制备具有高折射率的塑料透镜的方法，包括形成含有一种或多种多异氰酸酯化合物的混合物; 一种或多种选自不含硫原子的多元醇化合物的活性氢化合物，至少一个硫原子的多元醇化合物，以及巯基中含有硫原子以外还具有至少一个硫原子的多硫醇化合物 和至少一种内部脱模剂，然后浇铸和聚合该混合物。 本发明的第二方面涉及一种制备含硫聚氨酯树脂透镜的方法，其包括混合具有两个或多个异氰酸酯基的多异氰酸酯，具有两个或更多个硫醇基的多硫醇和一种或多种选自以下的表面活性剂： 由含氟非离子表面活性剂，含硅氧烷的非离子表面活性剂，烷基季铵盐和酸性磷酸酯组成的组，然后将混合物浇铸在由玻璃或金属制成的模具中。 还披露了由该方法制备的镜片。

公开(公告)号：US4814488A

公开(公告)日：1989-03-21

申请号：US111648

申请日：1987-10-23

申请人： Tohru Miura ,  Teruyuki Nagata

发明人： Tohru Miura ,  Teruyuki Nagata

IPC分类号： B01J27/06 ,  B01J27/00 ,  C07B61/00 ,  C07C51/347 ,  C07C51/353 ,  C07C62/32 ,  C07C67/343 ,  C07C69/753 ,  C07C69/76

CPC分类号： C07C51/347

摘要： Novel 4,4-bis(4-hydroxyphenyl)cyclohexanecarboxylic acid derivatives. These compounds can be prepared by reacting a cyclohexanone-4-carboxylic acid with a phenol.

公开(公告)号：US4723046A

公开(公告)日：1988-02-02

申请号：US62674

申请日：1987-06-16

申请人： Teruyuki Nagata ,  Tohru Miura

发明人： Teruyuki Nagata ,  Tohru Miura

IPC分类号： C07C39/21 ,  C07C37/50 ,  C07C37/52 ,  C07C39/15 ,  C07C39/17

CPC分类号： C07C37/50 ,  C07C37/20 ,  C07C39/17 ,  C07C2101/14

摘要： A process for preparing 4,4'-biphenol comprising subjecting 4,4-bis(4-hydroxyphenyl)cyclohexanol to decomposition and dehydrogenation in the presence of a dehydrogenation catalyst.4,4-Bis(4-hydroxyphenyl)cyclohexanol is a novel compound which can be prepared by reacting 4-hydroxycyclohexanone with phenol.