Integrally fired, laminated electromechanical transducing element
    1.
    发明授权
    Integrally fired, laminated electromechanical transducing element 失效
    整体烧制,层压电机转换元件

    公开(公告)号:US06734607B2

    公开(公告)日:2004-05-11

    申请号:US10029005

    申请日:2001-12-28

    IPC分类号: H01L4108

    摘要: An integrally fired, laminated electromechanical transducing element, fabricated using an inexpensive electrode material and having the electrode characteristic at least equivalent to that of the Ag—Pd electrode, is disclosed. Especially, in the integrally fired, laminated electromechanical transducing element according to the invention, (A) the rigidity of the internal electrode layers is low and the internal stress generated at the time of expansion or contraction of the ceramic layers is small, (B) the antimigration characteristic is superior, (C) the charge loss is small, the heat conductivity is high and the heat radiation characteristic is superior, and/or (D) the bonding strength between the ceramic layers and the electrode layers is high. The integrally fired, laminated electromechanical transducing element (1) according to the invention comprises, for example, an integrally fired laminate member fabricated by integrally firing a plurality of the ceramic layers (11) of piezoelectric ceramic or electrostrictive ceramic and the internal electrode layers (21, 22) interposed between the ceramic layers (11). The main component of the internal electrode layers (21, 22) is a base metal having a rigidity of not more than 160 GPa.

    摘要翻译: 公开了一种使用便宜的电极材料制造且具有至少与Ag-Pd电极相当的电极特性的整体烧制的层压电机转换元件。 特别地,在本发明的一体化烧结的层叠型机电转换元件中,(A)内部电极层的刚性低,陶瓷层的膨胀或收缩时产生的内应力小,(B) 抗迁移特性优异,(C)电荷损失小,导热性高,散热特性优异,(D)陶瓷层与电极层的接合强度高。 根据本发明的整体烧制的层压机电换能元件(1)包括例如通过一体地烧制多个压电陶瓷或电致伸缩陶瓷的陶瓷层(11)和内部电极层( 介于陶瓷层(11)之间。 内部电极层(21,22)的主要成分是具有不大于160GPa的刚性的母材。

    Stacked ceramic body and production method thereof

    公开(公告)号:US20060210781A1

    公开(公告)日:2006-09-21

    申请号:US11415314

    申请日:2006-05-02

    IPC分类号: B32B18/00

    摘要: This invention provides a stacked ceramic body that prevents reaction between components of dielectric layers and components of electrode layers of an unsintered stacked body during sintering and in which both components do not easily form a liquid phase, and a production method of such a stacked ceramic body. A print portion 13 is formed on a green sheet 1, 12 containing lead by use of an electrode paste consisting of copper oxide as its main component. A desired number of print sheets 10 are stacked to give an unsintered stacked body 15. Degreasing is conducted in an atmosphere to degrease organic components. The print portion 13 is subjected to reducing treatment in a reducing atmosphere containing hydrogen and is converted to a print portion 13 containing copper as its main component. The unsintered stacked body 15 is sintered in a reducing atmosphere. Dielectric layers containing lead and electrode layers for applying a voltage to the dielectric layers are alternately stacked, and an oxidation portion containing copper is formed in the proximity of a surface of the electrode layer. A thickness of the oxidation portion in a stacking direction is 0.5 to 2 μm and a copper content in the oxidation portion is 1 to 30 wt %.

    Production method for laminate type dielectric device and electrode paste material
    3.
    发明授权
    Production method for laminate type dielectric device and electrode paste material 失效
    层压型电介质器件和电极糊料的生产方法

    公开(公告)号:US07083745B2

    公开(公告)日:2006-08-01

    申请号:US10029006

    申请日:2001-12-28

    摘要: This invention provides a method of producing a laminate type dielectric device free from peeling of an electrode layer and a ceramic layer and from voids in both electrode layer and ceramic layer, and an electrode paste material. The invention relates also to an electrode paste material for constituting electrode layers of a laminate type dielectric device produced by at least the steps of alternately laminating ceramic layers 11 containing a lead element as a constituent component and electrode layers 2, and degreasing and baking the laminate, wherein the electrode paste material contains CuO as a principal component of a starting material of an electrically conductive material, a solvent, a binder, and a cooperative material consisting of at least one kind of the main components constituting the ceramic layer 11.

    摘要翻译: 本发明提供一种不会剥离电极层和陶瓷层以及从电极层和陶瓷层中的空隙剥离的叠层型电介质器件的制造方法和电极糊料。 本发明还涉及用于构成层压型电介质器件的电极层的电极糊材料,该电极浆料材料至少通过交替层叠包含铅元素作为构成成分的陶瓷层11和电极层2,以及对层压体进行脱脂和烘烤 其中,所述电极浆料含有CuO作为导电材料的原料的主要成分,溶剂,粘合剂,以及由构成陶瓷层11的至少一种主要成分构成的配合材料。

    Stacked ceramic body and production method thereof
    5.
    发明授权
    Stacked ceramic body and production method thereof 失效
    堆叠陶瓷体及其制造方法

    公开(公告)号:US07063813B1

    公开(公告)日:2006-06-20

    申请号:US10318359

    申请日:2002-12-13

    IPC分类号: C04B37/00 C04B33/32

    摘要: This invention provides a stacked ceramic body that prevents reaction between components of dielectric layers and components of electrode layers of an unsintered stacked body during sintering and in which both components do not easily form a liquid phase, and a production method of such a stacked ceramic body. A print portion 13 is formed on a green sheet 1, 12 containing lead by use of an electrode paste consisting of copper oxide as its main component. A desired number of print sheets 10 are stacked to give an unsintered stacked body 15. Degreasing is conducted in an atmosphere to degrease organic components. The print portion 13 is subjected to reducing treatment in a reducing atmosphere containing hydrogen and is converted to a print portion 13 containing copper as its main component. The unsintered stacked body 15 is sintered in a reducing atmosphere. Dielectric layers containing lead and electrode layers for applying a voltage to the dielectric layers are alternately stacked, and an oxidation portion containing copper is formed in the proximity of a surface of the electrode layer. A thickness of the oxidation portion in a stacking direction is 0.5 to 2 μm and a copper content in the oxidation portion is 1 to 30 wt %.

    摘要翻译: 本发明提供一种层叠陶瓷体,其在烧结时防止电介质层的成分与未烧结层叠体的电极层的成分之间的反应,并且其中两种成分都不容易形成液相,以及这种层叠陶瓷体的制造方法 。 通过使用以氧化铜为主要成分的电极糊料,在含有铅的生片1,12上形成印刷部13。 堆叠所需数量的打印片材10以得到未烧结的叠层体15。 在大气中进行脱脂以使有机组分脱脂。 打印部分13在含有氢的还原气氛中进行还原处理,并转换成包含铜作为其主要成分的印刷部分13。 未烧结的堆叠体15在还原气氛中烧结。 包含用于向电介质层施加电压的引线和电极层的介电层交替堆叠,并且在电极层的表面附近形成含有铜的氧化部分。 层叠方向的氧化部的厚度为0.5〜2μm,氧化部的铜含量为1〜30重量%。

    Method for fabricating laminate-type dielectric element
    7.
    发明授权
    Method for fabricating laminate-type dielectric element 失效
    叠层型电介质元件的制造方法

    公开(公告)号:US07272876B2

    公开(公告)日:2007-09-25

    申请号:US10700371

    申请日:2003-11-04

    IPC分类号: H01G7/00

    摘要: A method of producing a laminated dielectric element of high quality, free of delamination. A method of producing a laminated dielectric element 1 by alternately laminating dielectric ceramic layers 12 and base metal electrode layers 13, comprising the steps of printing electrodes by applying a paste material for the base metal electrodes onto the surfaces of at least one side of the ceramic green sheets, laminating and press-adhering the ceramic green sheets to fabricate a laminate thereof, dewaxing the laminate, reducing the electrodes to form base metal electrode layers by heating the laminate while flowing an atmospheric gas and by reducing the paste material for the base metal electrodes, and sintering the laminate. In the step of reducing the electrodes, the paste material for the base metal electrodes is so reduced that the amount of the base metal oxide remaining in the base metal electrode layers is not larger than 20% by weight and that the amount of lead liberated from the ceramic material is not larger than 30 atomic % within 5000 Å from the surfaces of the base metal electrode layers.

    摘要翻译: 一种高质量,无分层的叠层电介质元件的制造方法。 通过交替层叠电介质陶瓷层12和基底金属电极层13来制造叠层电介质元件1的方法,包括以下步骤:通过将贱金属电极的糊料施加到陶瓷的至少一侧的表面上来印刷电极 生片,层叠和压制陶瓷生片以制造其层压体,使层压体脱蜡,通过在流过大气气体的同时加热层压体并且通过还原贱金属的糊料来减少电极以形成贱金属电极层 电极,并烧结层压板。 在减少电极的步骤中,用于贱金属电极的糊料材料减少,使得残留在贱金属电极层中的贱金属氧化物的量不大于20重量%,并且从 在贱金属电极层的表面内的陶瓷材料不大于30原子%。