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1.发明授权Novel organopolysiloxanes and room temperature curable organopolysiloxane compositions containing the same 失效新颖的有机聚硅氧烷和含有它们的室温可固化的有机聚硅氧烷组合物
公开(公告)号：US4339563A
公开(公告)日：1982-07-13
申请号：US209492
申请日：1980-11-24
申请人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
发明人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
CPC分类号： C08L83/14
摘要： The invention provides a novel and improved room temperature curable organopolysiloxane composition which is very stable over a long period of time if stored under an anhydrous condition but readily curable on exposure to moisture-containing atmosphere without producing no condensation products having toxicity, unpleasant odor or corrosiveness. The composition comprises, as the main component, an organopolysiloxane having at least three alkenyloxy groups bonded to the silicon atom or atoms in the organopolysiloxane molecule through a silhydrocarbylene linkage, e.g. silethylene linkage, and a curing accelerator.
摘要翻译： 本发明提供了一种新颖且改进的室温可固化的有机基聚硅氧烷组合物，其在无水条件下储存时长时间非常稳定，但在暴露于含水气氛中易于固化，而不会产生不具有毒性，令人不快的气味或腐蚀性的缩合产物 。 该组合物包含具有至少三个烯氧基的有机聚硅氧烷，其通过硅亚烃键连接至硅原子或有机聚硅氧烷分子中的原子。 硫化乙烯键和固化促进剂。
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公开(公告)号：US4891434A
公开(公告)日：1990-01-02
申请号：US120249
申请日：1987-11-10
申请人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
发明人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
IPC分类号： C07F7/18 , C08K5/54 , C08K5/5435
CPC分类号： C07F7/1828 , C08K5/5435
摘要： The invention discloses a novel class of organosilane compounds containing 1 to 3 alkenyloxy groups directly bonded to the silicon atom and a 3,4-epoxycyclohexyl-substituted alkyl group bonded to the silicon atom. The compound is prepared by the reaction of 1-vinyl-3,4-epoxycyclohexane and a hydrogen alkenyloxy silane and useful as a coupling agent or an adhesion-improving agent.
摘要翻译： 本发明公开了一类新颖的含有直接与硅原子键合的1〜3个烯氧基的有机硅烷化合物和与硅原子键合的3,4-环氧环己基取代的烷基。 该化合物通过1-乙烯基-3,4-环氧环己烷和氢链烯氧基硅烷的反应制备，可用作偶联剂或粘合改进剂。
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公开(公告)号：US4618646A
公开(公告)日：1986-10-21
申请号：US753319
申请日：1985-07-09
申请人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
发明人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
摘要： The room temperature-curable (RTV) organopolysiloxane composition of the invention comprises, in addition to the conventional components of a diorganopolysiloxane terminated at both molecular chain ends each with a silanolic hydroxy group, a hydrolyzable organosilicon compound having two or more hydrolyzable groups in a molecule and a filler, an organosilicon-modified polyoxyalkylene compound, of which the organosilicon-containing terminal groups have at least one hydrolyzable group so as to pertain to the crosslinking reaction in its part. By virtue of this unique additive component, the composition is quite free from the disadvantage of sagging when the composition is applied to building works and the like and still retains excellent adhesive properties to the substrate surface in contrast to the difficulty in the conventional RTV compositions in which reducing of the phenomenon of sagging and retention of the strong adhesive strength are hardly compatible.
摘要翻译： 本发明的室温固化型（RTV）有机聚硅氧烷组合物除了在分子链末端以硅烷醇羟基封端的二有机聚硅氧烷的常规组分外，还包括在分子中具有两个或多个可水解基团的可水解的有机硅化合物 和有机硅改性的聚氧化烯化合物，其中含有机硅的端基具有至少一个可水解基团以与其部分的交联反应相关的填料。 由于这种独特的添加剂组分，组合物相当于在将组合物施用于建筑工程等时下垂的缺点，并且与常规RTV组合物的难度相比仍然保持对基材表面的优异的粘合性能。 这种减少下垂现象和保持强粘合强度几乎不相容。
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4.发明授权
公开(公告)号：US4323488A
公开(公告)日：1982-04-06
申请号：US130565
申请日：1980-03-14
申请人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
发明人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
IPC分类号： C08G65/336 , C08G77/46 , C08L3/12 , C08L83/12 , C08L91/00
CPC分类号： C08L83/12 , C08G65/336 , C08G77/46 , C08L3/12 , Y10S528/901
摘要： The present invention provides a novel room temperature-curable composition based on a polyoxyalkylene polyether, e.g. polyoxypropylene, admixed with a curing agent which is very stable when kept in a dry atmosphere or in a hermetically sealed condition but is readily cured when exposed to atmospheric air containing moisture into a rubber-like elastomer. The polyoxyalkylene polyether is terminated at both molecular chain ends with organosilyl groups having alkenyloxy groups bonded to the silicon atoms and can be prepared by the addition reaction of an allyl-terminated polyoxyalkylene polyether with an organosilane or organopolysiloxane compound having at least one silicon-bonded hydrogen atom and at least one silicon-bonded alkenyloxy group in a molecule in the presence of a platinum catalyst.
摘要翻译： 本发明提供了一种基于聚氧化烯聚醚的新型室温可固化组合物， 聚氧丙烯与固化剂混合，当保持在干燥气氛或密封状态时非常稳定，但当暴露于含有水分的大气中进入橡胶状弹性体时，固化剂容易固化。 聚氧化烯聚醚在两个分子链末端被终止，其中有机甲硅烷基具有与硅原子键合的烯基氧基，并且可以通过烯丙基封端的聚氧化烯聚醚与具有至少一个与硅键合的氢的有机硅烷或有机聚硅氧烷化合物的加成反应来制备 原子和在铂催化剂存在下的分子中至少一个硅键合的烯氧基。
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公开(公告)号：US4294975A
公开(公告)日：1981-10-13
申请号：US151696
申请日：1980-05-20
申请人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
发明人： Toshio Takago , Masatoshi Arai , Koji Futatsumori
CPC分类号： C07F7/1868 , C07F7/025 , C07F7/04 , C07F7/0896 , C08K5/54
摘要： The invention provides a novel class of organosilicon compounds which are hydrogenalkenyloxysilanes represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms and n is a number of zero, 1 or 2. The silane compounds are readily obtained by the dehydrochlorination reaction between a corresponding hydrogen-containing chlorosilane compound and an .alpha., .beta.-unsaturated aldehyde compound or a ketone compound in the presence of an acid acceptor. The compounds are useful as a modifying agent in the silicone technology and also serve as a curing agent.
摘要翻译： 本发明提供了一类新的有机硅化合物，它们是由通式“IMAGE”表示的氢链烷氧基硅烷，其中R 1是具有1至8个碳原子的一价烃基，R 2，R 3和R 4各自为氢原子或一价烃 具有1至8个碳原子的基团，n是0,1或2的数。硅烷化合物通过相应的含氢氯硅烷化合物和α，β-不饱和醛化合物或酮之间的脱氯化氢反应容易地获得 化合物在酸受体的存在下。 该化合物可用作硅氧烷技术中的改性剂，并且还用作固化剂。
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6.发明授权Organosilicon compound and a room temperature curable organopolysiloxane composition formulated therewith 失效有机硅化合物和与之配制的室温可固化的有机聚硅氧烷组合物
公开(公告)号：US4579963A
公开(公告)日：1986-04-01
申请号：US710128
申请日：1985-03-11
申请人： Masatoshi Arai , Koji Futatsumori , Takeo Inoue , Shinichi Sato
发明人： Masatoshi Arai , Koji Futatsumori , Takeo Inoue , Shinichi Sato
CPC分类号： C07F7/1824 , C08L83/04
摘要： The invention provides a novel class of organosilicon compounds useful as a curing agent in a room temperature curable organopolysiloxane composition, which is represented by the general structural formulaR.sub.2 CH--CR.dbd.C(OR)--O--Si(R.sup.1).sub.3-m (O--CR.dbd.CH--R).sub.m,in which each R is a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group independently from the others, R.sup.1, if any, is a substituted or unsubstituted monovalent hydrocarbon group and the suffix m is 2 or 3. The compound can readily be synthesized by the reaction of an .alpha.,.beta.-unsaturated ester compound represented by the general formulaR.sub.2 C.dbd.CR--CO--OR,and an alkenyloxy-containing silane compound represented by the general formulaHSi(R.sup.1).sub.3-m (O--CR.dbd.CH--R).sub.m,in which R.sup.1, R and m each have the meaning as defined above, in the presence of a rhodium compound as a catalyst. The room temperature curable composition is formulated with (a) 100 parts by weight of a diorganopolysiloxane terminated at both molecular chain ends each with a silanolic hydroxy group and having a viscosity in the range from 100 to 1,000,000 centistokes at 25.degree. C.; (b) from 2 to 40 parts by weight of the novel organosilicon compound and (c) from 0.01 to 10 parts by weight of a curing accelerator which is preferably a 2-guanidino-containing organosilicon compound.
摘要翻译： 本发明提供了一种新型的有机硅化合物，其用作室温可固化的有机聚硅氧烷组合物中的固化剂，其由通式结构式R2CH-CR = C（OR）-O-Si（R1）3-m -CR = CH-R）m，其中每个R是氢原子或取代或未取代的单价烃基，其中R 1，如果有的话是取代或未取代的一价烃基，并且后缀m是2或 该化合物可以容易地通过由通式R2C = CR-CO-OR表示的α，β-不饱和酯化合物与由通式HSi（R1）3表示的含烯氧基的硅烷化合物的反应合成 -m（O-CR = CH-R）m，其中R1，R和m各自具有如上定义的含义，在铑化合物作为催化剂存在下。 室温可固化组合物配制为（a）100重量份在两个分子链末端终止的二有机聚硅氧烷，每个分子链端均具有硅烷醇羟基，并且在25℃下的粘度范围为100至1,000,000厘沲。 （b）2〜40重量份的新型有机硅化合物和（c）0.01〜10重量份优选含有2-胍基的有机硅化合物的固化促进剂。
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公开(公告)号：US4577041A
公开(公告)日：1986-03-18
申请号：US749174
申请日：1985-06-26
申请人： Masatoshi Arai , Koji Futatsumori , Takeo Inoue , Shinichi Sato
发明人： Masatoshi Arai , Koji Futatsumori , Takeo Inoue , Shinichi Sato
摘要： The invention provides a novel cyclic organopolysiloxane compound represented by the general formula ##STR1## in which the groups denoted by R, R.sup.1 and R.sup.2 are each typically a monovalent hydrocarbon group having 1 to 8 carbon atoms, m is zero, 1, 2 or 3 and n is 2, 3 or 4 with the proviso that m+n is typically 4. A method for the preparation of the compound is disclosed. The inventive compound is useful as a crosslinking agent of a diorganopolysiloxane terminated at both molecular chain ends each with a silanolic hydroxy group so as to give a room temperature-curable silicone rubber composition free from the problem of emission of toxic or corrosive gases as a byproduct of the crosslinking reaction.
摘要翻译： 本发明提供了由通式“IMAGE”表示的新型环状有机聚硅氧烷化合物，其中由R，R 1和R 2表示的基团各自通常为具有1至8个碳原子的一价烃基，m为0,1,2或3 并且n为2,3或4，条件是m + n通常为4.公开了制备该化合物的方法。 本发明化合物可用作在两个分子链端分别以硅烷醇羟基封端的二有机聚硅氧烷的交联剂，从而得到室温可固化的硅橡胶组合物，不含作为副产物排放有毒或腐蚀性气体的问题 的交联反应。
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公开(公告)号：US4304920A
公开(公告)日：1981-12-08
申请号：US162533
申请日：1980-06-24
申请人： Masatoshi Arai , Koji Futatsumori
发明人： Masatoshi Arai , Koji Futatsumori
IPC分类号： C08K5/00 , C07F7/18 , C08K5/5425 , C08K9/06 , C07F7/04
CPC分类号： C07F7/1828 , C08K5/5425 , C08K9/06
摘要： The invention provides a novel class or organosilane compounds having a methacryloxy group and one or more of alkenyloxy groups bonded to the silicon atom as represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms, m is an integer of 3, 4 or 5 and n is a number of zero, 1 or 2. The organosilane compound, e.g. 3-methacryloxypropyl-containing alkenyloxysilanes can be readily prepared by the addition reaction of allyl methacrylate and a corresponding alkenyloxysilane having a hydrogen atom directly bonded to the silicon atom in the presence of a platinum catalyst. The organosilane compounds are useful as a coupling agent to increase adhesive bonding strength between inorganic and organic materials.
摘要翻译： 本发明提供了具有甲基丙烯酰氧基和一个或多个与硅原子键合的链烯氧基的新型或有机硅烷化合物，如通式“IMAGE”所示，其中R 1是具有1至8个碳原子的一价烃基， R2，R3和R4各自为氢原子或具有1至8个碳原子的一价烃基，m为3,4或5的整数，n为0,1或2的数。有机硅烷化合物，例如 含有甲基丙烯酰氧基丙基的烯基氧基硅烷可以容易地通过在铂催化剂存在下，通过甲基丙烯酸烯丙酯和具有直接与硅原子键合的氢原子的相应的烯基氧基硅烷的加成反应来制备。 有机硅烷化合物可用作偶联剂以增加无机和有机材料之间的粘合强度。
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公开(公告)号：US4288375A
公开(公告)日：1981-09-08
申请号：US162534
申请日：1980-06-24
申请人： Masatoshi Arai , Koji Futatsumori
发明人： Masatoshi Arai , Koji Futatsumori
IPC分类号： C08K5/00 , C07F7/18 , C08K5/5435 , C08K9/06 , C08L67/00 , C07D303/02
CPC分类号： C07F7/1828 , C08K9/06
摘要： The invention provides a novel class of organosilane compounds having a glycidyloxy group and one or more of alkenyloxy groups bonded to the silicon atom as represented by the general formula ##STR1## in which R.sup.1 is a monovalent hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or a monovalent hydrocarbon group having from 1 to 8 carbon atoms, m is an integer of 3, 4 or 5 and n is a number of zero, 1 or 2. The organosilane compound, e.g. 3-glycidyloxypropyl-containing alkenyloxysilanes can be readily prepared by the addition reaction of glycidyl allyl ether and a corresponding alkenyloxysilane having a hydrogen atom directly bonded to the silicon atom in the presence of a platinum catalyst. The organosilane compounds are useful as a coupling agent to increase adhesive bonding strength between inorganic and organic materials.
摘要翻译： 本发明提供一种具有缩水甘油氧基和一个或多个与硅原子键合的链烯氧基的新一类有机硅烷化合物，如通式“IMAGE”所示，其中R 1是具有1至8个碳原子的一价烃基， R2，R3和R4各自为氢原子或具有1至8个碳原子的一价烃基，m为3,4或5的整数，n为0,1或2的数。有机硅烷化合物，例如 通过在铂催化剂存在下，缩水甘油基烯丙基醚和具有直接与硅原子键合的氢原子的相应的烯基氧基硅烷的加成反应，可以容易地制备含有3-缩水甘油氧基丙烯的烯基氧基硅烷。 有机硅烷化合物可用作偶联剂以增加无机和有机材料之间的粘合强度。
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公开(公告)号：US4302571A
公开(公告)日：1981-11-24
申请号：US127074
申请日：1980-03-04
申请人： Masatoshi Arai , Koji Futatsumori
发明人： Masatoshi Arai , Koji Futatsumori
IPC分类号： C08L71/00 , C08G65/336 , C08L71/02 , C08L83/00 , C08L83/04 , C08L83/12 , D06M15/647 , C08G77/16
CPC分类号： C08L83/12 , C08G65/336 , D06M15/647
摘要： A novel room temperature-curable composition is provided by the invention, of which the base polymer is a polyoxyalkylene polyether terminated at both chain ends with silanolic hydroxy groups. The composition comprises 100 parts by weight of the above silanol-terminated polyoxyalkylene polyether and 1 to 30 parts by weight of an organosilane or organopolysiloxane having, in a molecule, at least two hydrolyzable groups bonded to the silicon atoms which serves as a crosslinking agent. The composition can be stored for a long period of time when kept with exclusion of atmospheric moisture and, when exposed to the atmosphere, is rapidly cured into a rubbery elastomer having good mechanical properties. Tack-free drying of the composition is accelerated when an alkenyloxy-containing silane is used as the above-mentioned silane having hydrolyzable groups in combination with a guanidyl-containing organosilicon compound.
摘要翻译： 本发明提供了一种新的室温可固化组合物，其中基础聚合物是在两个末端用硅烷醇羟基封端的聚氧化烯聚醚。 该组合物包含100重量份的上述硅烷醇封端的聚氧化烯聚醚和1至30重量份的有机硅烷或有机聚硅氧烷，其在分子中具有至少两个与用作交联剂的硅原子键合的可水解基团。 当保持排除大气水分时，组合物可以长时间储存，并且当暴露于大气中时，其迅速固化成具有良好机械性能的橡胶状弹性体。 当使用含烯氧基的硅烷作为上述具有可水解基团的硅烷与含胍基的有机硅化合物组合时，组合物的无粘性干燥加速。
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