摘要:
A battery including a separator having a satisfactory ammonia trapping property is speculated to exhibit a less self-discharge and a higher capacity-holding rate. The ammonia trapping property is speculated to be increased with an increasing degree of sulfonation of a constitutive polyolefin fiber. However, a highly sulfonated conventional polyolefin has a deteriorated fiber strength and highly sulfonated portions thereof are peeled or eliminated, and the resulting fiber cannot have a significantly high degree of sulfonation. The invention is therefore intended to provide a separator having an improved ammonia trapping property. The invented separator includes a polyolefin resin fiber having large amounts of introduced sulfonic groups. Specifically, the separator is one containing a fiber obtained by sulfonating a polyolefin resin fiber having an intrinsic viscosity number of 0.2 to 1.0 dl/g, one including a fiber obtained by sulfonating a polyolefin resin fiber and having a BET specific surface area of 0.5 m2/g or more, or one including a fiber obtained by oxidizing a polyolefin fiber and sulfonating the oxidized fiber.
摘要:
An object of the present invention is to provide a thin battery separator having an excellent nitrate group trapping performance and a high piercing strength. The inventive separator for a secondary battery, which can accomplish such an object, is made of a resin composition mainly containing a polyolefin having a hydrophilic functional group, wherein the resin composition has a content (ratio to a total resin amount) of a low-density polyethylene of 20 mass % or less, a piercing strength of 5 to 100 N, a Metsuke of 20 to 75 g/m2, a thickness of 15 to 150 μm, and an unneutralized hydrophilic functional group amount of 1×10−3 to 5×10−2 mol/m2.
摘要翻译:本发明的目的是提供一种具有优异的硝酸盐捕获性能和高穿刺强度的薄电池隔板。 本发明的二次电池用隔膜由能够实现上述目的的二次电池用树脂组合物由主要含有亲水性官能团的聚烯烃构成,其中树脂组合物的含量(总树脂量的总量) 密度聚乙烯为20质量%以下,穿刺强度为5〜100N,Metsuke为20〜75g / m 2,厚度为15〜150μm,未中和的亲水性官能团量为1×10 -3〜 3> 5×10 -2 mol / m 2。
摘要:
A battery including a separator having a satisfactory ammonia trapping property is speculated to exhibit a less self-discharge and a higher capacity-holding rate. The ammonia trapping property is speculated to be increased with an increasing degree of sulfonation of a constitutive polyolefin fiber. However, a highly sulfonated conventional polyolefin has a deteriorated fiber strength and highly sulfonated portions thereof are peeled or eliminated, and the resulting fiber cannot have a significantly high degree of sulfonation. The invention is therefore intended to provide a separator having an improved ammonia trapping property. The invented separator includes a polyolefin resin fiber having large amounts of introduced sulfonic groups. Specifically, the separator is one containing a fiber obtained by sulfonating a polyolefin resin fiber having an intrinsic viscosity number of 0.2 to 1.0 dl/g, one including a fiber obtained by sulfonating a polyolefin resin fiber and having a BET specific surface area of 0.5 m2/g or more, or one including a fiber obtained by oxidizing a polyolefin fiber and sulfonating the oxidized fiber.
摘要:
The present invention relates to a sulfonic acid group-containing polymer excellent in ion conductivity and durability, a method for producing the same, a resin composition containing the sulfonic acid group-containing polymer, a polymer electrolyte membrane, a polymer electrolyte membrane/electrode assembly, and a fuel cell. The sulfonic acid group-containing polymer of the present invention, in a first embodiment, includes a constituent represented by the following chemical formula 1: wherein X represents hydrogen or a monovalent cation species; Y represents a sulfone group or a ketone group; and n represents an arbitrary integer not less than 2.
摘要:
The invention provides a method for producing a polymer electrolyte membrane including (A) a membrane formation step of forming a membrane-form product of an ionic group-containing polymer electrolyte on a support, (B) an acid treatment step of exchanging the ionic group into an acid type by bringing the membrane into contact with an inorganic acid-containing acidic liquid, (C) an acid removal step of removing a free acid in the acid-treated membrane, and (D) a drying step of drying the acid-removed membrane, wherein the steps (B) to (D) are carried out without separating the membrane from the support.
摘要:
The present invention relates to a sulfonic acid group-containing polymer excellent in ion conductivity and durability, a method for producing the same, a resin composition containing the sulfonic acid group-containing polymer, a polymer electrolyte membrane, a polymer electrolyte membrane/electrode assembly, and a fuel cell. The sulfonic acid group-containing polymer of the present invention, in a first embodiment, includes a constituent represented by the following chemical formula 1: wherein X represents hydrogen or a monovalent cation species; Y represents a sulfone group or a ketone group; and n represents an arbitrary integer not less than 2.
摘要:
A process for producing a syndiotactic α-olefin polymer having high racemic diad fraction and high molecular weight with excellent polymerization activity through a method permitting high-temperature polymerization. The production process comprises polymerizing a monomer that comprises at least one C3-10 α-olefin and a small amount of ethylene, in the presence of an olefin polymerization catalyst comprising a transition metal compound (A) represented by the general formula [1], at least one compound (B) selected from an organoaluminum oxy-compound (b-1), a compound (b-2) that reacts with the transition metal compound (A) to form an ion pair and an organoaluminum compound (b-3), which process for producing a syndiotactic α-olefin polymer satisfies the relationship: 0.001≦PE/PO≦0.030, provided that the molar amounts of ethylene and an α-olefin having 3 to 10 carbon atoms that are fed into a polymerization reactor under a polymerization temperature of not lower than 25° C. are PE and PO, respectively.
摘要翻译:通过允许高温聚合的方法制备具有高的外消旋二单元组分和高分子量的具有优异聚合活性的间同立构α-烯烃聚合物的方法。 该制备方法包括在包含由通式[1]表示的过渡金属化合物(A)的烯烃聚合催化剂存在下聚合包含至少一种C 3-10α-烯烃和少量乙烯的单体, 选自有机铝氧化合物(b-1)中的至少一种化合物(B),与过渡金属化合物(A)反应形成离子对的化合物(b-2)和有机铝化合物(b-3) ),制备间规α-烯烃聚合物的方法满足以下关系:0.001≦̸ PE / PO≦̸ 0.030,条件是进料到聚合反应器中的乙烯和具有3至10个碳原子的α-烯烃的摩尔量 在不低于25℃的聚合温度下分别为PE和PO。
摘要:
A gas detecting apparatus including: a heating resistor exposed to a detected atmosphere, and a control circuit for controlling the heating resistor at two different temperatures, wherein each output voltage from the heating resistor corresponding to the different temperatures is detected when the heating resistor is controlled to the different temperatures, and a state of a gas is obtained based on the detected output voltage. For example, two different offset voltages are set, each potential difference obtained by subtracting each of the offset voltages from corresponding detected output voltages is amplified and the state of the gas is obtained using the amplified potential differences.
摘要:
Disclosed is a proton exchange membrane for use in fuel cells, which not only has improved proton conductivity and resistance to swelling caused by hot water but also has greater durability when used in a fuel cell, as well as a sulfonic acid group-containing segmented block copolymer constituting the proton exchange membrane, a membrane electrode assembly using the proton exchange membrane, and a fuel cell using the membrane electrode assembly. A sulfonic acid group-containing segmented block copolymer, which is a di- or multi-block copolymer including, within a molecule, at least one kind of hydrophilic segment and at least one kind of hydrophobic segment, a 0.5 g/dL solution thereof dissolved in N-methyl-2-pyrrolidone as a solvent showing a logarithmic viscosity measured at 30° C. in the range of 0.5 to 5.0 dL/g, wherein the copolymer has at least one kind of hydrophobic segment represented by Chemical Formula 1, the segment has a structure bound to a group represented by Chemical Formula 2, and the hydrophilic segment has at least one kind of structure represented by Chemical Formula 3 or Chemical Formula 3-2.
摘要:
A power transmission apparatus includes a pulley 1 having a belt attached thereto to transmit the rotating drive force, a hub 2 which connects the pulley to a rotating shaft of a driven device, a bearing 7 which rotatably supports the pulley, and a sleeve ring 5 which is fitted and secured to the pulley and attaches the bearing to the pulley to prevent it relatively moving. The sleeve ring is provided, on its first end opposite to the driven device, with a bent portion 5b against which the bearing abuts to restrict further movement of the bearing. An annular retainer 6 is provided on the portion of the bearing adjacent to the drive device. The bearing is secured to the sleeve ring through the annular retainer by calking a second end 5a of the sleeve ring opposite to the first end. The sleeve ring is provided with a projection 5f which projects in the axial direction from the rear surface of the pulley and a casing 9 is provided with an annular groove 9c which at least partly receives therein the projection.