摘要:
A rational technical process for producing dialkylnaphthalenes from petroleum-derived starting materials which exist in abundance is established. The process for producing dialkylnaphthalenes contains the steps (1), (2), (3), and (4): (1) 1st step which is for catalytically hydrodealkylating a stock oil containing a substantial amount of naphthalene and/or alkylnapthalenes, separating a product oil form a product gas, and separating and recovering a fraction composed mainly of naphthalene and/or methylnaphthalene from the product oil; (2) 2nd step which is for catalytically alkylating or catalytically transalkylating the fraction, recovered in the 1st step, composed mainly of naphthalene and/or methylnaphthalene directly without pretreatment for purification, with an alkylating agent or transalkylating agent to prepare alkylnaphthalenes; (3) 3rd step which is for separating and recovering dialkylnaphthalenes from the alkylnaphthalenes obtained in the 2nd step; and (4) 4th step which is for returning at least a part of the residual fraction, after the separation and recovery of dialkylnaphthalenes in the 3rd step, as at least a part of the stock oil in the 1st step and/or at least part of the alkylating agent or transalkylating agent in the 2nd step to the corresponding step.
摘要:
The present invention provides a method for producing .beta.-methylnaphthalene from an inexpensive and easily available feed oil. According to the invention, highly pure .beta.-methylnaphthalene adequate for industrial use can be mass-produced at reduced costs. The method comprises catalytic hydrodealkylation of a feed oil containing an alkyl naphthalene having at least two methyl groups in the presence of a catalyst having at least one metal species of selected from the group consisting of vanadium (V), chromium (Cr), nickel (Ni), rhodium (Rh), platinum (Pt), iridium (Ir), and compounds of these metals as an active component and a carrier therefor containing at least one of alumina and silica as its primary component, with a hydrogen partial pressure of 1 to 50 kgf/cm.sup.2, at a temperature of 450.degree. C. to 650.degree. C., and for a contact time of 3 to 35 seconds. The method of the invention is excellent in that it affords .beta.-methylnaphthalene of a chemical grade with a high yield.
摘要翻译:本发明提供一种从便宜且容易获得的原料油中生产β-甲基萘的方法。 根据本发明,可以以降低的成本批量生产适用于工业用途的高纯度β-甲基萘。 该方法包括在具有选自钒(V),铬(Cr),镍(至少一种)的至少一种金属种类的催化剂存在下,含有具有至少两个甲基的烷基萘的进料油的催化加氢脱烷基化 Ni),铑(Rh),铂(Pt),铱(Ir),以及作为活性成分的这些金属的化合物和其中含有氧化铝和二氧化硅作为其主要成分中的至少一种的载体,氢分压 1〜50kgf / cm 2,温度450〜650℃,接触时间3〜35秒。 本发明的方法优点在于它以高产率提供化学级的β-甲基萘。
摘要:
Catalytic hydrodealkylation by means of a catalyst which comprises microporous particles having a catalytic species carried thereon. Particulars of the microporous particles are disclosed.
摘要:
A catalyst for hydrodealkylation of alkylaromatic compounds which comprises porous alumina particles with coke deposited thereon in the pores, said alumina particles having a pore volume of 0.1 to 1.5 cm.sup.3 /g and a specific surface area of 5 to 500 m.sup.2 /g, the quantity of said coke being 1 to 30% by weight of said alumina particles, and the pore volume and the specific surface area of said catalyst being 0.05 to 1.5 cm.sup.3 /g and 1 to 500 m.sup.2 /g, respectively.
摘要:
A process for producing 2,6-dimethylnaphthalene by subjecting 2,7-dimethylnaphthalene to an isomerization reaction, wherein the isomerization reaction is carried out by the use of a metallosilicate catalyst that comprises a metallosilicate having a main cavity defined by a ten-oxygen-membered ring, that is in the form of aggregates of fine crystals of the metallosilicate, the external surface area of the aggregate as calculated from t-plot analysis made in the nitrogen adsorption method being 25 m2/g or more, and that has been treated to inactivate acid centers present on the external surfaces of the fine crystals until the rate constant basic value N becomes 0.5 or less.
摘要:
An output controlling apparatus for a vehicle generator includes MOSFETs for full-wave rectification of a voltage output by the generator, a MOSFET for turning the flow of a field current on and off and a voltage controller for controlling the MOSFETs to sustain the voltage of a battery at a fixed value. In this configuration, the thermal resistance between the MOSFETs is set at a value smaller than the thermal resistance between the voltage controller and the MOSFETs. In addition, the MOSFETs are fixed on a common good heat conductive substrate to reduce the thermal resistance between the MOSFETs. In this way, the accuracy of the voltage controller is prevented from deteriorating and, at the same time, the maximum temperature of the MOSFETs can be reduced.
摘要:
Molten pitch is mixed and atomized in an inert gas stream having a temperature less than that of the molten pitch, cooled to the ordinary temperature and separated from the gas stream.Fine powder such as carbon, silica alumina and the like is added to at least one step of the process to improve the fluidity of the thusly obtained fine solid pitch spheres. The pitch spheres are easy to storage, handle and transport as they behave like a fluid.
摘要:
In a rotation detection apparatus, a rotation-angle detector detects a rotation angle of a rotating body based on an output signal generated by a resolver. An exciting-signal generation circuit supplies an exciting signal for exiting the resolver to generate the output signal. An abnormality detection circuit detects an abnormality of an exciting-signal output terminal for outputting the exciting signal or an abnormality of an exciting-signal line for transmitting the exciting signal. A power-supply stopping circuit stops a power supply to the exciting-signal generation circuit when the abnormality detection circuit detects an abnormality of the exciting-signal output terminal or detects an abnormality of the exciting-signal line.
摘要:
In a rotation detection apparatus, a rotation-angle detector detects a rotation angle of a rotating body based on an output signal generated by a resolver. An exciting-signal generation circuit supplies an exciting signal for exiting the resolver to generate the output signal. An abnormality detection circuit detects an abnormality of an exciting-signal output terminal for outputting the exciting signal or an abnormality of an exciting-signal line for transmitting the exciting signal. A power-supply stopping circuit stops a power supply to the exciting-signal generation circuit when the abnormality detection circuit detects an abnormality of the exciting-signal output terminal or detects an abnormality of the exciting-signal line.
摘要:
A motor controller including an inverter including plural switching elements that are subjected to PWM control to generate sine waves of plural phases, a motor including a stator coil supplied with the sine waves thus generated so that rotational magnetic field is generated in the stator coil, and a rotor that is rotationally driven by the action of the rotational magnetic field generated by the stator coil, a storage unit for detecting the sine waves of the respective phases generated in the inverter and storing a correction amount for each phase that is calculated on the basis of the detection result so that the sine waves of the respective phases are coincident with one another and a correcting unit for correcting a PWM signal for carrying out the PWM control on the switching elements on the basis of the correction amount thus calculated.