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    Multimetallic catalyst composite
    1.
    发明授权
    Multimetallic catalyst composite 失效
    多金属催化剂复合材料

    公开(公告)号：US3878125A

    公开(公告)日：1975-04-15

    申请号：US42033673

    申请日：1973-11-29

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： MITSCHE ROY T ,  HAYES JOHN C ,  WILHELM FREDERICK C ,  RAUSCH RICHARD E

    IPC: B01J29/064 ,  B01J29/22 ,  C10G35/095 ,  B01J11/78 ,  B01J11/40

    CPC classification number: C10G35/095 ,  B01J29/064 ,  B01J29/22

    Abstract: A catalytic composite, comprising a combination of catalytically effective amounts of a platinum or palladium component, an iridium component, and a Group IVA metallic component with a carrier material containing alumina and a finely divided, zeolitic crystalline aluminosilicate, is disclosed. A specific example of the catalytic composite disclosed herein is a composite containing 0.01 to 2 wt. % platinum or palladium, 0.01 to 2 wt. % iridium and 0.01 to 5 wt. % germanium, tin or lead combined with a gamma-alumina carrier material having 0.1 to 20 wt. % of the hydrogen form of mordenite uniformly distributed therethrough. Principal utility of these catalytic composites is, broadly, in processes for the conversion of hydrocarbons and, more particularly, in a process for the production of LPG and a high octane reformate.

    Abstract translation: 公开了一种催化复合材料，其包含催化有效量的铂或钯组分，铱组分和IVA族金属组分与含有氧化铝和细碎沸石结晶硅铝酸盐的载体材料的组合。 本文公开的催化复合物的具体实例是含有0.01至2wt。 ％铂或钯，0.01〜2重量％ ％铱和0.01〜5wt。 ％锗，锡或铅与具有0.1-20重量％的γ-氧化铝载体材料组合。 百分数的均匀分布的丝光沸石的氢形式。 这些催化复合材料的主要用途是广泛地用于烃的转化方法，更具体地说，在用于生产LPG和高辛烷值重整油的方法中。

    Hydrogen-consuming process and catalyst therefor
    2.
    发明授权
    Hydrogen-consuming process and catalyst therefor 失效
    氢消耗工艺及其催化剂

    公开(公告)号：US3607728A

    公开(公告)日：1971-09-21

    申请号：US3607728D

    申请日：1969-07-31

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J29/068 ,  C10G47/14 ,  C10G47/18 ,  C10G13/02

    CPC classification number: B01J29/068 ,  C10G47/14 ,  C10G47/18 ,  Y10S585/906 ,  Y10S585/94

    Abstract: A hydrocarbon hydroprocess utilizing a catalytic composite of a porous carrier material, a Group VIII noble metal component and a lead component, in which process there is effected a chemical consumption of hydrogen. A specific example of one such catalyst is a composite of a crystalline aluminosilicate, a platinum component and a lead component, for utilization in a hydrocracking process. Other hydrocarbon hydroprocesses are directed toward the hydrogenation of aromatic nuclei, the ringopening of cyclic hydrocarbons, desulfurization, denitrification, hydrogenation, etc. The catalyst contains 0.01 percent to about 2.0 percent by weight of the noble metal component, and the atomic ratio of lead to noble metal is in the range of 0.05:1 to 0.9:1.

    Hydrocarbon conversion with a multimetallic catalytic composite
    5.
    发明授权
    Hydrocarbon conversion with a multimetallic catalytic composite 失效
    烃转化与多金属催化复合材料

    公开(公告)号：US3892657A

    公开(公告)日：1975-07-01

    申请号：US44813174

    申请日：1974-03-04

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J23/62 ,  B01J37/22 ,  C10G35/09 ,  C10G35/08

    CPC classification number: B01J37/22 ,  B01J23/622 ,  C10G35/09

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a bimetallic acidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, an indium component and a halogen component with a porous carrier material. The platinum group component and halogen component are present in the bimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. percent platinum group metal and about 0.1 to about 3.5 wt. percent halogen. The indium component is present in amounts corresponding to an atomic ratio of indium to platinum group metal of about 0.1:1 to about 1:1. Moreover, the platinum group and indium components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group component is present therein in the corresponding elemental metallic state while substantially all of the indium component is present therein in an oxidation state above that of the corresponding metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and hydrogen stream are contacted with the novel acidic bimetallic catalyst disclosed herein at reforming conditions. Also disclosed is a novel trimetallic catalyst comprising a combination of a Group IVA metallic component with the acidic bimetallic catalyst.

    Abstract translation: 通过在碳氢化合物转化条件下使它们与含有催化有效量的铂族组分，铟组分和卤素组分与多孔载体材料的组合的双金属酸性催化复合物接触来转化碳氢化合物。 铂族组分和卤素组分分别以基于元素计算的量存在于双金属催化剂中，相当于约0.01至约2wt。 百分比的铂族金属和约0.1至约3.5重量％ 百分比卤素。 铟成分以对应于铟与铂族金属的原子比为约0.1:1至约1:1的量存在。 此外，铂组分和铟组分在仔细控制的氧化态下均匀分散在整个多孔载体材料中，使得基本上所有的铂族组分都存在于相应的元素金属状态，而基本上所有的铟组分存在于其中 氧化态高于相应金属的氧化态。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的新型酸性双金属催化剂接触。 还公开了一种新颖的三金属催化剂，其包含IVA族金属组分与酸性双金属催化剂的组合。

    Hydrocarbon conversion with a sulfided bimetallic catalytic composite
    6.
    发明授权
    Hydrocarbon conversion with a sulfided bimetallic catalytic composite 失效
    具有硫化双金属催化复合材料的碳氢化合物转化

    公开(公告)号：US3888763A

    公开(公告)日：1975-06-10

    申请号：US44119874

    申请日：1974-02-11

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J23/644 ,  C10G35/09 ,  C10G35/08 ,  B01J11/74

    CPC classification number: B01J23/6447 ,  C10G35/09

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a sulfided bimetallic acidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a sulfur component, a bismuth component and a halogen component with a porous carrier material. The platinum group component, sulfur component, and halogen component are present in the bimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 1 wt. % sulfur and about 0.1 to about 3.5 wt. % halogen. The bismuth component is present in amounts corresponding to an atomic ratio of bismuth to platinum group metal of about 0.1:1 to about 1:1. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal and bismuth components are present therein in the corresponding elemental metallic states while substantially all the sulfur component is present therein in the form of physically adsorbed or chemisorbed sulfide. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and hydrogen stream are contacted with the novel sulfided bimetallic catalyst disclosed herein at reforming conditions.

    Dehydrogenation method and catalytic composite for use therein
    7.
    发明授权
    Dehydrogenation method and catalytic composite for use therein 失效

    公开(公告)号：US3649565A

    公开(公告)日：1972-03-14

    申请号：US3649565D

    申请日：1969-10-20

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J23/62 ,  B01J37/18 ,  C07C5/333 ,  B01J11/08

    CPC classification number: B01J37/18 ,  B01J23/628 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/62 ,  Y10S585/906

    Abstract: DEHYDROGENATABLE HYDROCARBONS ARE DEHYDROGENATED BY CONTACTING THEM AT DEHYDROGENATION CONDITIONS WITH A CATALYTIC COMPOSITE COMPRISING A COMBINATION OF CATALYTICALLY EFFECTIVE AMOUNTS OF A PLATINUM GROUP COMPONENT AND A LEAD COMPONENT WITH A POROUS CARRIER MATERIAL. A SPECIFIC EXAMPLE OF THE CATALYTIC COMPOSITE DISCLOSED HEREIN IS A COMBINATION OF A PLATINUM COMPONENT, A LEAD COMPONENT AND AN ALKALI OR ALKALINE EARTH COMPONENT WITH A POROUS CARRIER MATERIAL WHEREIN THE PLATINUM AND LEAD COMPONENTS ARE UNIFORMLY DISTRIBUTED THROUGHOUT THE POROUS CARRIER MATERIAL, WHEREIN THE COMPOSITE CONTAINS ABOUT 0.01 TO ABOUT 2 WT. PERCENT OF PLATINUM AND ABOUT 0.01 TO ABOUT 5 WT. PERCENT OF THE ALKALI METAL OR ALKALINE EARTH METAL AND WHEREIN THE LEAD COMPONENT IS PRESENT IN AN AMOUNT SUFFICIENT TO RESULT IN AN ATOMIC RATIO OF LEAD TO PLATINUM OF ABOUT 0.05:1 TO ABOUT 0.6:1.

    Hydrocarbon conversion with a multimetallic catalytic composite
    8.
    发明授权
    Hydrocarbon conversion with a multimetallic catalytic composite 失效

    公开(公告)号：US3900387A

    公开(公告)日：1975-08-19

    申请号：US43630574

    申请日：1974-01-24

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J23/644 ,  B01J27/08 ,  C10G35/09 ,  C10G35/08 ,  B01J11/78 ,  C07C5/28

    CPC classification number: B01J27/08 ,  B01J23/6447 ,  C10G35/09

    Abstract: Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a trimetallic acidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IVA component, a bismuth component and a halogen component with a porous carrier material. The platinum group component, Group IVA metallic component, a halogen component are present in the trimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IVA metal and about 0.1 to about 3.5 wt. % halogen. The bismuth component is present in amounts corresponding to an atomic ratio of bismuth to platinum group metal of about 0.1:1 to about 1:1. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal and bismuth components are present therein in the corresponding elemental metallic states while substantially all of the Group IVA metallic component is present therein in an oxidation state above that of the corresponding metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and hydrogen stream are contacted with the novel trimetallic catalyst disclosed herein at reforming conditions.

    Hydrogen-consuming process and catalyst therefor
    10.
    发明授权
    Hydrogen-consuming process and catalyst therefor 失效
    氢消耗工艺及其催化剂

    公开(公告)号：US3644198A

    公开(公告)日：1972-02-22

    申请号：US3644198D

    申请日：1970-05-11

    Applicant: UNIVERSAL OIL PROD CO

    Inventor： WILHELM FREDERICK C

    IPC: B01J23/89 ,  C07C5/10 ,  C10G49/06 ,  C10G23/02 ,  B01J11/40 ,  C10G23/00

    CPC classification number: C10G49/06 ,  B01J23/8966 ,  C07C5/10 ,  C07C2521/12 ,  C07C2523/14 ,  C07C2523/40 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  C07C2523/89

    Abstract: A hydrocarbon hydroprocess utilizing a catalytic composite of a porous carrier material, a nickel component, a Group VIII noble metal component and a Group IV-A metal component, in which process there is effected a chemical consumption of hydrogen. A specific example of one such catalyst is a composite of a crystalline aluminosilicate, a nickel component, a platinum component, and a germanium component, particularly for utilization in a hydrocracking process. Other hydrocarbon hydroprocesses are directed toward the hydrogenation of aromatic nuclei, the ring-opening of cyclic hydrocarbons, desulfurization, denitrification, hydrogenation, etc. The catalyst contains 0.01 to about 2.0 percent by weight of the noble metal component, 0.01 to about 5.0 percent by weight of the nickel component, and the atomic ratio of the Group IV-A metal component to the noble metal component is in the range of 0.05:1 to 10.0:1.

    Abstract translation: 利用多孔载体材料，镍组分，VIII族贵金属组分和IV-A族金属组分的催化复合物的烃加氢方法，其中进行氢的化学消耗。 一种这样的催化剂的具体实例是结晶硅铝酸盐，镍组分，铂组分和锗组分的复合物，特别是用于加氢裂化过程中。 其它烃加氢反应涉及芳烃氢化，环状烃开环，脱硫，脱氮，氢化等。催化剂含有0.01〜2.0％（重量）的贵金属成分，0.01〜5.0％ 镍成分的重量，IV-A族金属成分与贵金属成分的原子比在0.05:1〜10.0:1的范围内。

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