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公开(公告)号：US12234329B2
公开(公告)日：2025-02-25
申请号：US17554056
申请日：2021-12-17
Applicant: University of Kansas
Inventor： Bala Subramaniam , Julian R. Silverman , Andrew M. Danby , Thomas Binder , Steffan Green
IPC: C08J3/00
Abstract: Methods of forming lignin prepolymers are provided. In an embodiment, such a method comprises adding an acid to an ozonized reaction mixture, the ozonized reaction mixture comprising ozonized lignin having a backbone, and aromatic monomers cleaved from a lignin, under conditions to react the cleaved aromatic monomers with the backbone of the ozonized lignin to form a lignin prepolymer. The methods may further comprise using the lignin prepolymer to form a lignin resin.
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公开(公告)号：US20230339830A1
公开(公告)日：2023-10-26
申请号：US18194814
申请日：2023-04-03
Applicant: University of Kansas
Inventor： Bala Subramaniam , Hongda Zhu , Timothy A. Jackson
Abstract: A process for oxidizing an alkyl substrate may comprise combining an alkyl substrate (e.g., propane, n-butane) and ozone in a liquid phase medium comprising a branched alkane activator (e.g., isobutane) and a protic additive (e.g., water) under conditions sufficient to oxidize the alkyl substrate to products. The alkyl substrate may be selected from linear and cyclic alkanes.
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公开(公告)号：US20220112339A1
公开(公告)日：2022-04-14
申请号：US17554056
申请日：2021-12-17
Applicant: University of Kansas
Inventor： Bala Subramaniam , Julian R. Silverman , Andrew M. Danby , Thomas Binder , Steffan Green
IPC: C08J3/00
Abstract: Methods of forming lignin prepolymers are provided. In an embodiment, such a method comprises adding an acid to an ozonized reaction mixture, the ozonized reaction mixture comprising ozonized lignin having a backbone, and aromatic monomers cleaved from a lignin, under conditions to react the cleaved aromatic monomers with the backbone of the ozonized lignin to form a lignin prepolymer. The methods may further comprise using the lignin prepolymer to form a lignin resin.
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公开(公告)号：US08801939B2
公开(公告)日：2014-08-12
申请号：US13866414
申请日：2013-04-19
Applicant: University of Kansas , Archer Daniels Midland Company
Inventor： Bala Subramaniam , Daryle Busch , Andrew M. Danby , Thomas P Binder
IPC: C02F1/78
CPC classification number: C01B13/00 , B01D53/1493 , B01D2256/14 , B01D2257/106 , C01B13/10 , C07C37/50 , C07C45/40 , C07C51/34 , C07C67/333 , C07C303/02 , C07D311/78 , C07D323/02 , C07D501/14 , Y02P20/51 , C07C47/02 , C07C47/542 , C07C47/54 , C07C49/185 , C07C47/575 , C07C47/46 , C07C49/04 , C07C53/08 , C07C63/06 , C07C53/126 , C07C69/48 , C07C69/716 , C07C309/08 , C07C39/04
Abstract: A method for increasing ozone concentration in a liquid can include: providing a gas having ozone; introducing the ozone-containing gas into a liquid, wherein the liquid and ozone combination has a temperature between about 0.8 and about 1.5 times the critical temperature of ozone; and increasing isothermally, the pressure of the ozone-containing gas above the liquid to about 0.3 to about 5 times the critical pressure of ozone so as to increase the ozone concentration in the liquid. The temperature is expressed in absolute units (Kelvin or Rankin). The method can be used for removing ozone from a gas or for purifying ozone. The liquid having a high ozone concentration can be used for ozonolysis of a substrate.
Abstract translation: 提高液体中臭氧浓度的方法可以包括：提供具有臭氧的气体; 将含臭氧的气体引入液体中，其中液体和臭氧组合的温度为臭氧临界温度的约0.8至约1.5倍; 并且等温地增加液体上方的含臭氧气体的压力至臭氧的临界压力的约0.3至约5倍，以增加液体中的臭氧浓度。 温度以绝对单位（开尔文或Rankin）表示。 该方法可用于从气体中除去臭氧或净化臭氧。 具有高臭氧浓度的液体可用于底物的臭氧分解。
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公开(公告)号：US10821422B2
公开(公告)日：2020-11-03
申请号：US15776835
申请日：2016-11-17
Applicant: UNIVERSITY OF KANSAS
Inventor： Raghunath V. Chaudhari , Xin Jin , Bala Subramaniam
IPC: B01J23/89 , B01J21/06 , B01J23/44 , B01J23/78 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/06 , B01J37/16 , C07C51/16 , B01J35/00 , B01J37/08 , B01J23/00 , C07C51/235 , C07C51/00
Abstract: In a first aspect, the present invention is directed to a process for forming a metal alloy catalyst. Another aspect of the present invention is directed to a process for oxidizing a substrate that includes contacting a substrate with an oxidant in the presence of a metal alloy catalyst to form one or more carboxylic acids. Suitable substrates include sugars, polyols, furfural alcohols, and polyhydroxycarboxylic acids. The oxidation process may use the alloy catalyst formed from the process of the first aspect of the invention.
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Patent Agency Ranking
公开(公告)号：US10730814B2
公开(公告)日：2020-08-04
申请号：US16324163
申请日：2017-08-10
Applicant: University of Kansas
Inventor： Bala Subramaniam , Andrew M. Danby , Michael D. Lundin
Abstract: A process for the ozonolysis of an alkane may comprise combining an alkane and ozone in a liquid phase medium comprising CO2 under conditions sufficient to oxidize the alkane to produce one or more non-combustion products. The liquid phase medium may be free of a super acid.
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公开(公告)号：US20190177254A1
公开(公告)日：2019-06-13
申请号：US16324163
申请日：2017-08-10
Applicant: University of Kansas
Inventor： Bala Subramaniam , Andrew M. Danby , Michael D. Lundin
Abstract: A process for the ozonolysis of an alkane may comprise combining an alkane and ozone in a liquid phase medium comprising CO2 under conditions sufficient to oxidize the alkane to produce one or more non-combustion products. The liquid phase medium may be free of a super acid.
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公开(公告)号：US20170145043A1
公开(公告)日：2017-05-25
申请号：US15355507
申请日：2016-11-18
Applicant: University of Kansas
Inventor： Bala Subramaniam , Anand Ramanathan , Kakasaheb Y. Nandiwale , Andrew M. Danby , Raghunath V. Chaudhari
IPC: C07G1/00 , C07C37/52 , C07C29/00 , C07C45/67 , C07C41/18 , C07D307/24 , C07D307/60 , C07D207/34 , C07C67/00
CPC classification number: C07G1/00 , C07C37/52 , C07C41/18 , C07C45/51 , C07C45/673 , C07C51/00 , C07C67/00 , C07D207/34 , C07D307/24 , C07D307/60 , C08H6/00 , C10G1/086 , C10G2300/1014 , C07C59/64 , C07C39/08 , C07C49/84 , C07C69/92 , C07C49/825 , C07C69/734 , C07C49/245
Abstract: Provided is a process for depolymerizing lignin, the process comprising exposing a liquid feed comprising lignin and a solvent to a metal-incorporated solid mesoporous silicate catalyst under conditions sufficient to depolymerize the lignin to produce one or more aromatic monomers.
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公开(公告)号：US20220356137A1
公开(公告)日：2022-11-10
申请号：US17621259
申请日：2020-06-19
Applicant: University of Kansas , Purdue Research Foundation
Inventor： Bala Subramaniam , Anand Ramanathan , Yang Xiao , Arvind Varma
IPC: C07C37/055 , B01J23/648 , B01J23/652 , B01J29/03
Abstract: Methods for gas-phase deoxygenation of a bio-oil are provided. In embodiments, such a method comprises exposing a bio-oil vapor comprising hydrocarbon compounds having oxygenated aromatic groups, to hydrogen gas in the presence of catalyst under conditions to induce deoxygenation of the oxygenated aromatic groups to provide a deoxygenated aromatic species, wherein the catalyst is a transition metal-incorporated mesoporous silicate having platinum deposited thereon and the transition metal is selected from Nb, W, Zr, and combinations thereof. The transition metal-incorporated mesoporous silicate catalysts are also provided.
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公开(公告)号：US09994601B2
公开(公告)日：2018-06-12
申请号：US15355507
申请日：2016-11-18
Applicant: University of Kansas
Inventor： Bala Subramaniam , Anand Ramanathan , Kakasaheb Y. Nandiwale , Andrew M. Danby , Raghunath V. Chaudhari
IPC: C10G1/08 , C08H7/00 , C07G1/00 , C07D207/34 , C07C37/52 , C07C67/00 , C07C41/18 , C07D307/24 , C07D307/60 , C07C45/67 , C07C45/51 , C07C51/00
CPC classification number: C07G1/00 , C07C37/52 , C07C41/18 , C07C45/51 , C07C45/673 , C07C51/00 , C07C67/00 , C07D207/34 , C07D307/24 , C07D307/60 , C08H6/00 , C10G1/086 , C10G2300/1014 , C07C59/64 , C07C39/08 , C07C49/84 , C07C69/92 , C07C49/825 , C07C69/734 , C07C49/245
Abstract: Provided is a process for depolymerizing lignin, the process comprising exposing a liquid feed comprising lignin and a solvent to a metal-incorporated solid mesoporous silicate catalyst under conditions sufficient to depolymerize the lignin to produce one or more aromatic monomers.
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