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    Process for forming Ziegler-Natta catalyst for use in polyolefin production
    3.
    发明申请
    Process for forming Ziegler-Natta catalyst for use in polyolefin production 审中-公开
    用于形成用于聚烯烃生产的齐格勒 - 纳塔催化剂的方法

    公开(公告)号：US20050085601A1

    公开(公告)日：2005-04-21

    申请号：US10685643

    申请日：2003-10-15

    申请人： Kayo Vizzini ,  Steven Gray

    发明人： Kayo Vizzini ,  Steven Gray

    IPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/02

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/651 ,  C08F4/6546 ,  C08F4/6557 ,  C08F2500/12 ,  C08F2500/02 ,  C08F2500/23 ,  C08F2500/07 ,  C08F2500/18 ,  C08F2500/04

    摘要： The invention provides a process for forming a catalyst for use in the polymerization of olefins. This process comprises reacting a chlorinating agent with a magnesium alkoxide compound to form a magnesium-titanium-alkoxide adduct, followed by reacting the magnesium-titanium-alkoxide adduct with an alkylchloride compound, e.g., benzoyl chloride, to form a magnesium chloride support. The support is then reacted with titanium tetrachloride to form a highly active catalyst useful for the production of polyolefins.

    摘要翻译： 本发明提供一种形成用于烯烃聚合的催化剂的方法。 该方法包括使氯化剂与烷氧基镁化合物反应以形成镁 - 钛 - 醇盐加合物，然后使镁 - 钛 - 醇盐加合物与烷基氯化物如苯甲酰氯反应，形成氯化镁载体。 然后将载体与四氯化钛反应以形成可用于生产聚烯烃的高活性催化剂。

    Silica supported ziegler-natta catalysts useful for preparing polyolefins
    6.
    发明申请
    Silica supported ziegler-natta catalysts useful for preparing polyolefins 审中-公开
    用于制备聚烯烃的二氧化硅负载的齐格勒 - 纳塔催化剂

    公开(公告)号：US20060252636A1

    公开(公告)日：2006-11-09

    申请号：US11122920

    申请日：2005-05-05

    申请人： Kayo Vizzini ,  Steven Gray ,  Tim Coffy

    发明人： Kayo Vizzini ,  Steven Gray ,  Tim Coffy

    IPC分类号： C08F4/02 ,  B01J31/00

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/025 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/04 ,  C08F2500/24 ,  C08F2500/19

    摘要： A silica supported catalyst system can be prepared that includes the product of admixing a magnesium alkoxide with a group 4, 5, or 6 transition metal complex to form a magnesium transition metal alkoxide adduct having the general formula: MgM(OR)2(OR1)pClq wherein M is a group 4, 5, or 6 transition metal; R is an alkyl or aryl moiety; R1 is a alkyl or aryl moiety having from 1 to 10 carbons, and p and q are 0 or an integer such that p+q equals the highest formal oxidation state of M; contacting the magnesium transition metal alkoxide adduct with a silica template to form a silica supported catalyst precursor; contacting the silica supported catalyst precursor chlorinating agent to form a chlorinated catalyst precursor; and contacting the chlorinated catalyst precursor with an aluminum alkyl to form a silica supported catalyst.

    摘要翻译： 可以制备二氧化硅负载的催化剂体系，其包括将烷氧基镁与基团4,5,5或6过渡金属络合物混合以形成具有以下通式的镁过渡金属醇盐加合物的产物： =“在线公式”end =“lead”？> MgM（OR）2（或<1>） <？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是4,5或6族过渡金属; R是烷基或芳基部分; R 1是具有1至10个碳的烷基或芳基部分，p和q是0或整数，使得p + q等于M的最高形式氧化态; 使镁过渡金属醇盐加合物与二氧化硅模板接触以形成二氧化硅负载的催化剂前体; 使二氧化硅负载的催化剂前体氯化剂接触以形成氯化催化剂前体; 并使氯化催化剂前体与烷基铝接触以形成二氧化硅负载的催化剂。

    Ziegler-Natta catalyst for particle size control
    7.
    发明授权
    Ziegler-Natta catalyst for particle size control 失效
    齐格勒 - 纳塔催化剂用于粒度控制

    公开(公告)号：US07655590B2

    公开(公告)日：2010-02-02

    申请号：US12004814

    申请日：2007-12-20

    申请人： Henry Enriquez ,  Kayo Vizzini ,  Steven Gray

    发明人： Henry Enriquez ,  Kayo Vizzini ,  Steven Gray

    IPC分类号： B01J37/16 ,  B01J37/22

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/6557 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/07 ,  C08F2500/23 ,  C08F2500/04

    摘要： Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A1”, contacting the solution of reaction product “A1” with a reducing agent to form a reduced reaction product “A2”, contacting reduced reaction product “A2” with a second agent to form a solid reaction product “A3”, contacting solid reaction product “A3” with a metal halide to form reaction product “B” and contacting reaction product “B” with an organoaluminum compound to form a catalyst component.

    摘要翻译： 本文描述了催化剂组分，形成催化剂组合物的方法，利用催化剂组合物的聚合方法和由此形成的聚合物。 所述方法通常包括提供二烷氧基镁化合物，使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液，使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”，将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A3”，使固体反应产物“A3”与金属卤化物接触以形成反应产物“B”并使反应产物“B” 与有机铝化合物形成催化剂组分。

    Ziegler-Natta catalyst for particle size control
    8.
    发明申请
    Ziegler-Natta catalyst for particle size control 失效
    齐格勒 - 纳塔催化剂用于粒度控制

    公开(公告)号：US20090163680A1

    公开(公告)日：2009-06-25

    申请号：US12004814

    申请日：2007-12-20

    申请人： Henry Enriquez ,  Kayo Vizzini ,  Steven Gray

    发明人： Henry Enriquez ,  Kayo Vizzini ,  Steven Gray

    IPC分类号： C08F4/76

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/6557 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/07 ,  C08F2500/23 ,  C08F2500/04

    摘要： Catalyst components, methods of forming catalyst compositions, polymerization processes utilizing the catalyst compositions and polymers formed thereby are described herein. The methods generally include providing a magnesium dialkoxide compound, contacting the magnesium dialkoxide compound with a first agent to form a solution of a reaction product “A1”, contacting the solution of reaction product “A1” with a reducing agent to form a reduced reaction product “A2”, contacting reduced reaction product “A2” with a second agent to form a solid reaction product “A3”, contacting solid reaction product “A3” with a metal halide to form reaction product “B” and contacting reaction product “B” with an organoaluminum compound to form a catalyst component.

    摘要翻译： 本文描述了催化剂组分，形成催化剂组合物的方法，利用催化剂组合物的聚合方法和由此形成的聚合物。 所述方法通常包括提供二烷氧基镁化合物，使二烷氧基镁化合物与第一试剂接触以形成反应产物“A1”的溶液，使反应产物“A1”的溶液与还原剂接触以形成还原反应产物 “A2”，将还原的反应产物“A2”与第二试剂接触以形成固体反应产物“A3”，使固体反应产物“A3”与金属卤化物接触以形成反应产物“B”并使反应产物“B” 与有机铝化合物形成催化剂组分。

    Promoter system for polymerization processes and polymers formed therefrom
    9.
    发明申请
    Promoter system for polymerization processes and polymers formed therefrom 审中-公开
    用于聚合方法的促进剂体系和由其形成的聚合物

    公开(公告)号：US20080051535A1

    公开(公告)日：2008-02-28

    申请号：US11508772

    申请日：2006-08-23

    申请人： Kayo Vizzini ,  Steven Gray

    发明人： Kayo Vizzini ,  Steven Gray

    IPC分类号： C08F4/44

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/6493 ,  C08F4/6557

    摘要： Polymerization processes and polymers formed therefrom are described herein. Such processes generally include providing a catalyst system, introducing the catalyst system to a reaction zone, introducing 1-chlorobutane to the reaction zone, introducing an olefin monomer to the reaction zone, contacting the olefin monomer with the catalyst system in the presence of the 1-chlorobutane to form a polyolefin and withdrawing the polyolefin from the reaction zone. The catalyst system is generally formed from a process including contacting a magnesium dialkoxide compound with a first agent to form a first compound, contacting the first compound with a plurality of halogenating/titanating agents to form a reaction product and contacting the reaction product with an activating agent to form the catalyst system.

    摘要翻译： 本文描述了聚合方法和由其形成的聚合物。 这样的方法通常包括提供催化剂体系，将催化剂体系引入反应区，将1-氯丁烷引入反应区，将烯烃单体引入反应区，使烯烃单体与催化剂体系在1 - 氯丁烷以形成聚烯烃并从反应区抽出聚烯烃。 催化剂体系通常由包括使二烷氧基镁化合物与第一试剂接触以形成第一化合物的方法形成，使第一化合物与多种卤化/钛化剂接触以形成反应产物并使反应产物与活化的 试剂形成催化剂体系。