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公开(公告)号:US08502007B2
公开(公告)日:2013-08-06
申请号:US12562919
申请日:2009-09-18
申请人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
发明人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
IPC分类号: C07C1/04
CPC分类号: C10J3/00 , B01J21/18 , B01J21/20 , B01J23/04 , B01J23/92 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/009 , B01J37/0201 , B01J38/72 , C10J3/482 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , Y02P20/52 , Y02P20/584
摘要: The invention provides processes for generating a methane-enriched gas from a gas mixture comprising carbon monoxide and hydrogen such as gas streams generated by gasification of an alkali metal catalyst-loaded carbonaceous feedstock, and a char methanation catalyst useful in such processes.
摘要翻译: 本发明提供从包含一氧化碳和氢气的气体混合物产生富甲烷气体的方法,例如通过加载载有碱金属催化剂的碳质原料气化产生的气流,以及可用于这些方法的焦炭甲烷化催化剂。
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公开(公告)号:US08328890B2
公开(公告)日:2012-12-11
申请号:US12562925
申请日:2009-09-18
CPC分类号: C10J3/00 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C10J3/482 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10K3/04 , C10L3/08
摘要: The present invention relates to processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam and an oxygen-rich gas stream. The processes comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and do not recycle carbon monoxide or hydrogen to the catalytic gasifier.
摘要翻译: 本发明涉及通过在蒸汽和富氧气流的存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法。 该方法包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且不将一氧化碳或氢气循环到催化气化器中。
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公开(公告)号:US20100121125A1
公开(公告)日:2010-05-13
申请号:US12562919
申请日:2009-09-18
申请人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
发明人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
IPC分类号: C07C1/04
CPC分类号: C10J3/00 , B01J21/18 , B01J21/20 , B01J23/04 , B01J23/92 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/009 , B01J37/0201 , B01J38/72 , C10J3/482 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , Y02P20/52 , Y02P20/584
摘要: The invention provides processes for generating a methane-enriched gas from a gas mixture comprising carbon monoxide and hydrogen such as gas streams generated by gasification of an alkali metal catalyst-loaded carbonaceous feedstock, and a char methanation catalyst useful in such processes.
摘要翻译: 本发明提供从包含一氧化碳和氢气的气体混合物产生富甲烷气体的方法,例如通过加载载有碱金属催化剂的碳质原料气化产生的气流,以及可用于这些方法的焦炭甲烷化催化剂。
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公开(公告)号:US20100076235A1
公开(公告)日:2010-03-25
申请号:US12562925
申请日:2009-09-18
IPC分类号: C07C1/04
CPC分类号: C10J3/00 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C10J3/482 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10K3/04 , C10L3/08
摘要: The present invention relates to processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam and an oxygen-rich gas stream. The processes comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and do not recycle carbon monoxide or hydrogen to the catalytic gasifier.
摘要翻译: 本发明涉及通过在蒸汽和富氧气流的存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法。 该方法包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且不将一氧化碳或氢气循环到催化气化器中。
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公开(公告)号:US08647402B2
公开(公告)日:2014-02-11
申请号:US12562922
申请日:2009-09-18
申请人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
发明人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
IPC分类号: B23K35/38
CPC分类号: C10J3/00 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C10G2/32 , C10J3/482 , C10J3/721 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , C10L3/102 , C10L9/10
摘要: The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier.
摘要翻译: 本发明涉及用于在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法和连续方法。 在本发明的一个方面,该方法包括在合适的温度和压力下,在吹氧气化器中至少部分地将第一含碳原料与富氧气流一起燃烧,以产生包含氢气,一氧化碳和 过热蒸汽 以及在气化催化剂存在下,在合适的温度和压力下使催化气化器中的第二碳质原料与第一气流反应,形成第二气流,其包含多个包含甲烷,二氧化碳,氢气,一氧化碳和 硫化氢。 该方法可以包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且在某些实施方案中不将一氧化碳或氢气循环到气化器。
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公开(公告)号:US20100120926A1
公开(公告)日:2010-05-13
申请号:US12562921
申请日:2009-09-18
申请人: Earl T. Robinson , Avinash Sirdeshpande , Eli Gal , Vincent G. Reiling , Nicholas Charles Nahas
发明人: Earl T. Robinson , Avinash Sirdeshpande , Eli Gal , Vincent G. Reiling , Nicholas Charles Nahas
IPC分类号: C07C1/04
CPC分类号: C10J3/00 , C01B3/34 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/0445 , C01B2203/045 , C01B2203/0455 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/06 , C01B2203/1058 , C01B2203/1064 , C01B2203/147 , C10J3/482 , C10J3/721 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10K1/004 , C10K1/005 , C10K1/122 , C10K1/143 , C10K1/16 , C10K1/165 , C10K3/04 , C10L3/08
摘要: The present invention relates to processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. The processes comprise using at least one methanation step to convert carbon monoxide and hydrogen in the gaseous products to methane and do not recycle carbon monoxide or hydrogen to the catalytic gasifier.
摘要翻译: 本发明涉及通过在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法。 该方法包括使用至少一个甲烷化步骤将气态产物中的一氧化碳和氢气转化成甲烷,并且不将一氧化碳或氢气循环到催化气化器中。
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公开(公告)号:US20100287835A1
公开(公告)日:2010-11-18
申请号:US12778552
申请日:2010-05-12
IPC分类号: C01B3/32
CPC分类号: C10J3/00 , C01B3/36 , C01B3/48 , C01B3/50 , C01B32/40 , C01B32/50 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C01B2203/86 , C10J3/86 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1618 , C10J2300/1662 , C10J2300/1687 , C10J2300/1838 , C10J2300/1884 , C10J2300/1892 , C10K1/002 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/007 , C10K1/026 , C10K1/08 , C10K1/101 , C10K1/122 , C10K1/143 , C10K1/146 , C10K1/165 , C10K3/04 , C10L3/08 , Y02P30/30
摘要: The present invention relates to processes for preparing gaseous products, and in particular methane, via the hydromethanation of a carbonaceous feedstock in the presence of steam, syngas, a hydromethanation catalyst and an oxygen-rich gas stream.
摘要翻译: 本发明涉及通过在蒸汽,合成气,氢化甲烷化催化剂和富氧气流的存在下,通过含碳原料的氢化反应来制备气态产物,特别是甲烷的方法。
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公开(公告)号:US08728183B2
公开(公告)日:2014-05-20
申请号:US12778552
申请日:2010-05-12
IPC分类号: C01B3/36
CPC分类号: C10J3/00 , C01B3/36 , C01B3/48 , C01B3/50 , C01B32/40 , C01B32/50 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C01B2203/86 , C10J3/86 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1618 , C10J2300/1662 , C10J2300/1687 , C10J2300/1838 , C10J2300/1884 , C10J2300/1892 , C10K1/002 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/007 , C10K1/026 , C10K1/08 , C10K1/101 , C10K1/122 , C10K1/143 , C10K1/146 , C10K1/165 , C10K3/04 , C10L3/08 , Y02P30/30
摘要: The present invention relates to processes for preparing gaseous products, and in particular methane, via the hydromethanation of a carbonaceous feedstock in the presence of steam, syngas, a hydromethanation catalyst and an oxygen-rich gas stream.
摘要翻译: 本发明涉及通过在蒸汽,合成气,氢化甲烷化催化剂和富氧气流的存在下,通过含碳原料的氢化反应来制备气态产物,特别是甲烷的方法。
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公开(公告)号:US20100071262A1
公开(公告)日:2010-03-25
申请号:US12562922
申请日:2009-09-18
申请人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
发明人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
IPC分类号: C10L3/00
CPC分类号: C10J3/00 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C10G2/32 , C10J3/482 , C10J3/721 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , C10L3/102 , C10L9/10
摘要: The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier.
摘要翻译: 本发明涉及用于在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法和连续方法。 在本发明的一个方面,该方法包括在合适的温度和压力下,在吹氧气化器中至少部分地将第一含碳原料与富氧气流一起燃烧,以产生包含氢气,一氧化碳和 过热蒸汽 以及在气化催化剂存在下,在合适的温度和压力下使催化气化器中的第二碳质原料与第一气流反应,形成第二气流,其包含多个包含甲烷,二氧化碳,氢气,一氧化碳和 硫化氢。 该方法可以包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且在某些实施方案中不将一氧化碳或氢气循环到气化器。
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公开(公告)号:US20090170968A1
公开(公告)日:2009-07-02
申请号:US12342596
申请日:2008-12-23
CPC分类号: C10J3/00 , C10J3/463 , C10J2300/093 , C10J2300/0943 , C10J2300/0973 , C10J2300/0986 , C10J2300/16 , C10J2300/1618 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1823 , C10J2300/1853 , C10J2300/1884 , C10K1/003 , C10K3/006 , C10K3/02 , C10L3/08 , C10L3/102
摘要: The present invention provides processes for making synthesis gas and processes for making syngas-derived products. For example, one aspect of the present invention provides a process for making a synthesis gas stream comprising hydrogen and carbon monoxide, the process comprising (a) providing a carbonaceous feedstock; (b) reacting the carbonaceous feedstock in a gasification reactor in the presence of steam and a gasification catalyst under suitable temperature and pressure to form a raw product gas stream comprising a plurality of gases comprising methane, hydrogen and carbon monoxide; (c) removing steam from and sweetening the raw product gas stream to form a sweetened gas stream; (d) separating and adding steam to the sweetened gas stream to form a first reformer input gas stream having a first steam/methane ratio; and a second reformer input stream having a second steam/methane ratio, in which the first steam/methane ratio is smaller than the second steam/methane ratio; (e) reforming the second reformer input stream to form a recycle gas stream comprising steam, carbon monoxide and hydrogen; (f) introducing the recycle gas stream to the gasification reactor; and (g) reforming the first reformer input stream to form the synthesis gas stream.
摘要翻译: 本发明提供了制备合成气的方法和制备合成气衍生产物的方法。 例如,本发明的一个方面提供了一种制备包含氢气和一氧化碳的合成气流的方法,该方法包括(a)提供碳质原料; (b)在合适的温度和压力下,在蒸汽和气化催化剂的存在下在气化反应器中使碳质原料反应,形成包含甲烷,氢气和一氧化碳的多种气体的原始产物气流; (c)从原料气流中除去蒸汽并使其变质,形成增甜的气流; (d)将蒸汽分离并加入到所述增甜气流中以形成具有第一蒸汽/甲烷比的第一重整器输入气流; 以及第二蒸汽/甲烷比小于第二蒸汽/甲烷比的第二蒸汽/甲烷比的第二重整器输入流; (e)重整所述第二重整器输入流以形成包含蒸汽,一氧化碳和氢气的循环气流; (f)将再循环气流引入气化反应器; 和(g)重整第一重整器输入流以形成合成气流。
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