摘要:
PROCESS FOR PRODUCING SATURATED CARBOXYLIC ACIDS BY THE CATALYTIC HYDROGENATION OF LOW-POLYMERIC PRODUCTS WHICH ARE FORMED DURING THE REACTION OF KETENE WITH KETONES WITH 3 TO 6 CARBON ATOMS OR ALDEHYDES WITH 1 TO 18, PREFERABLY 3 TO 8 CARBON ATOMS, WHICH COMPRISES HEATING THE RAW CATALYST-CONTAINING LOW-POLYMERIC PRODUCT IN A REACTION ZONE IN THE PRESENCE OF A RANEY NICKEL HYDROGENATION CATALYST AT NORMAL PRESSURE AND IN THE LIQUID PHASE AT A GRADUALLY INCREASING RECTION TEMPERATURE WITHIN A RANGE FROM 50 TO 250*C., WHILE CIRCULATING AN EXCESS QUANTITY OF DRY HYDROGEN THROUGH SAID REACTION ZONE.
摘要:
MIXED POLYMERIZATES CONTAINING FROM 80% TO 100% BY WEIGHT OF A COPOLYMERIZATE OF VINYL CHLORIDE AND FUMARIC ACID ESTERS OF ALIPHATIC ALCOHOLS CHARACTERIZED IN THAT AT LEAST PART OF SAID ALIPHATIC ALCOHOLS ARE MONOHYDRIC ALIPHATICALLY-UNSATURATED ALCOHOLS CONTAINING AT LEAST 11 CARBON ATOMS AS WELL AS THE PROCESS OF PREPARING THE MIXED POLYMERIZATES. THE MIXED POLYMERIZATES FORM CLEAR MOLDED BODIES OF HIGH TENSILE STRENGTH AND ELASTICITY.
摘要:
This invention relates to a process for the preparation of an aqueous polymerizate dispersion which comprises the steps of subjecting 100 parts by weight of a monomer mixture consisting of: (a) 40 to 70 parts by weight of vinyl acetate, (b) 15 to 30 parts by weight of a vinyl ester of fatty acids having eight to 18 carbon atoms and (c) 15 to 30 parts by weight of vinylchloride to an aqueous dispersion polymerization in the presence of (1) free-radical forming catalysts, (2) at least one protective colloid and (3) an emulsifier selected from the group consisting of anionic emulsifiers, non-ionic emulsifiers and mixtures thereof, and recovering said aqueous polymerizate dispersion, as well as the aqueous polymerizate dispersions so produced.
摘要:
THIS INVENTION RELATES TO POLYMERIZING AND COPOLYMERIZING VINYL CHLORIDE, IN AQUEOUS EMULSIONS, AND IT HAS FOR ITS OBJECT TO PROVIDE A NOVEL AND IMPROVED PROCESS FOR THIS PURPOSE. IN PARTICULAR, THE INVENTION CONCERNS THE MAKING OF PASTABLE POLYMERIZATES OF VINYL CHLORIDE OR OF PASTABLE COPOLYMERIZATES CONTAINING AT LEAST 80 WEIGHT PERCENT OF POLYVINYL CHLORIDE, I.E. OF VINYL CHLORIDE POLYMERIZATES OR VINYL CHLORIDE COPOLYMERIAZTES WHICH CAN BE DISPERSED IN SOFTENERS, PERHAPS USING AT THE SAME TIME ORGANIC THINNERS WHICH EITHER DO NOT DISSOLVE OR SWELL THE POLYMERIZATES AT ALL OR ONLY A LITTLE, FORMING PASTES OR PLATISOLS OR ORGANOSOLS, BY POLYMERIZING OR COPOLYMERIZING THE VINYL CHLORIDE IN AN AQUEOUS EMULSION, I.E. BY THE POLYMERIZATION OR COPOLYMERIZATION OF VINYL CHLORIDE WHICH IS DISPERSED IN WATER BY MEANS OF EMULSIFIERS.
摘要:
This invention relates to a process for making pastable polymerizates of vinyl chloride or of pastable copolymerizates containing at least 80 weight percent polyvinyl chloride, by polymerizing or copolymerizing vinyl chloride in aqueous emulsion, that is by polymerization or copolymerization of vinyl chloride which is dispersed in water by means of emulsifiers. The process is performed in the presence of water-soluble salts of aliphatic branched saturated monocarboxylic acids containing CH2- groups in the alpha position to the carboxyl groups, with at least 8 carbon atoms per molecule, as emulsifiers. The term ''''pastable'''' polymerizates or copolymerizates'''' means that the polymerizates or copolymerizates can be dispersed in the known manner in plasticizers, if desired by also using organic thinners which dissolve or swell the polymerizates or copolymerizates not at all or only a little, during the formation of pastes or plastisols or organosols.
摘要:
METHOD OF SECURING OBJECTS SUCH AS STACKED PACKAGES OF PAPER, CARDBOARD AND THE LIKE AGAINST SLIPPING, IN WHICH ADJACENT CONTACTING PORTIONS OF SUCH PACKAGES ARE UNITED BY AN ADHESIVE COMPRISING AN AQUEOUS DISPERSION OF A POLYERIZATE OF AN OLEFINIC UNSATURATED COMPOUND WHICH FORMS A FILM AT A TEMPERATURE OF NOT MORE THAN +10*C., IN A HOMOGENEOUS MIXTURE WITH A SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF INORGANIC AND ORGANIC PIGMENTS.