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    Insoluble, only slightly swellable polymers containing amino groups, their preparation and their use
    6.
    发明授权
    Insoluble, only slightly swellable polymers containing amino groups, their preparation and their use 失效
    不溶性，仅含有氨基的微溶胀性聚合物，其制备及其用途

    公开(公告)号：US5599898A

    公开(公告)日：1997-02-04

    申请号：US325187

    申请日：1995-04-25

    申请人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz

    发明人： Heinrich Hartmann ,  Walter Denzinger ,  Michael Kroener ,  Claudia Nilz

    IPC分类号： C08F8/00 ,  B01D15/04 ,  B01J20/26 ,  B01J39/20 ,  C08F226/02 ,  C08G69/08 ,  C08G73/10

    CPC分类号： B01J39/20 ,  B01J20/26 ,  C08F226/02

    摘要： Abstract of the Disclosure: Insoluble, only slightly swellable polymers containing amino groups, which can be obtained from popcorn polymers containing units of the structure ##STR1## where R and R.sup.1 are H or C.sub.1 -C.sub.4 -alkyl, by eliminating the group R--CO-- from at least 2% of the incorporated units of the structure I, with the formation of units of the structure II ##STR2## a process for the preparation of the amino-containing popcorn polymers by polymerizing N-vinylcarboxamides and, if desired, other monoethylenically unsaturated monomers copolymerizable therewith with from 0.1 to 10% by weight, based on the monomers used in the polymerization, of a compound containing at least two ethylenically unsaturated non-conjugated double bonds as crosslinking agent, with exclusion of oxygen and polymerization initiators, to form popcorn polymers, and elimination of formyl groups from at least 2% of the copolymerized N-vinylcarboxamides, and the use of the resulting insoluble, only slightly swellable polymers containing amino groups as ion exchangers or adsorber resins for metal ions are described.

    摘要翻译： PCT No.PCT / EP93 / 03019 371日期1995年04月25日 102（e）日期1995年4月25日PCT提交1993年10月29日PCT公布。 公开号WO94 / 11408 日期：1994年5月26日摘要：不溶性的仅含有氨基的轻微溶胀性聚合物，其可以从含有其中R和R 1为H或C 1 -C 4 - 烷基的结构单元（I）的爆米花聚合物获得， 通过从结构I的引入单元的至少2％中除去基团R-CO-，形成结构II（II）的单元，制备含氨基的爆米花聚合物的方法通过 聚合N-乙烯基甲酰胺和（如果需要）可与其共聚的其它单烯属不饱和单体，基于聚合中使用的单体为0.1〜10重量％，含有至少两个烯属不饱和非共轭双键的化合物作为交联剂 排除氧气和聚合引发剂，形成爆米花聚合物，并从至少2％的共聚N-乙烯基甲酰胺中除去甲酰基，并使用所得的不溶性 描述了仅含有氨基作为离子交换剂的微溶胀性聚合物或用于金属离子的吸附树脂。

    Graft polymers containing N-vinyl units, their preparation and their use
    7.
    发明授权
    Graft polymers containing N-vinyl units, their preparation and their use 失效
    含有N-乙烯基单元的接枝聚合物，其制备及其用途

    公开(公告)号：US5753759A

    公开(公告)日：1998-05-19

    申请号：US704772

    申请日：1996-10-24

    申请人： Heinrich Hartmann ,  Walter Denzinger ,  Claudia Nilz

    发明人： Heinrich Hartmann ,  Walter Denzinger ,  Claudia Nilz

    IPC分类号： B01F17/00 ,  B01F17/52 ,  C05G3/00 ,  C08F263/00 ,  C08F265/00 ,  C08F271/00 ,  C09B67/46 ,  C09D17/00 ,  C09K17/20 ,  C11D3/37 ,  D21H17/34

    CPC分类号： C09D17/00 ,  B01F17/005 ,  C05G3/0029 ,  C08F271/00 ,  C09B67/0085 ,  C09K17/20 ,  C11D3/3788 ,  D21H17/34

    摘要： Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25.degree. C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

    摘要翻译： PCT No.PCT / EP95 / 00912 Sec。 371日期1996年10月24日第 102（e）日期1996年10月24日PCT 1995年3月3日PCT PCT。 公开号WO95 / 25759 日期1995年9月28日含有N-乙烯基单元的接枝聚合物，其中接枝碱是一种聚合物，其在每种情况下含有至少5重量％的式（I）的单元（I） 其中R 1和R 2各自为H或C 1 -C 6烷基，单烯属不饱和单体以100:1至1:100的重量比接枝到接枝基上，并且其K值至少为7（根据 H. Fikentscher在25℃和pH7的5重量％水溶液中）通过在聚合物存在下聚合单烯属不饱和单体来制备，每种情况下聚合物含有至少5重量％的式 I和/或II作为接枝基质，重量比为100：1至1：100，并用作颜料分散剂，作为洗涤剂和清洁剂的添加剂，以及用于纸张和土壤稳定剂的强度剂， 肥料压实。

    Process for the preparation of stable water-in-oil emulsions of hydrolyzed polymers of N-vinyl amides and the use thereof
    8.
    发明授权
    Process for the preparation of stable water-in-oil emulsions of hydrolyzed polymers of N-vinyl amides and the use thereof 失效
    N-乙烯基酰胺的水解聚合物的稳定的油包水乳液的制备方法及其用途

    公开(公告)号：US5739190A

    公开(公告)日：1998-04-14

    申请号：US737589

    申请日：1996-11-21

    申请人： Heinrich Hartmann ,  Karl-Heinrich Schneider ,  Walter Denzinger ,  Claudia Nilz ,  Dietmar Monch

    发明人： Heinrich Hartmann ,  Karl-Heinrich Schneider ,  Walter Denzinger ,  Claudia Nilz ,  Dietmar Monch

    IPC分类号： B01F17/52 ,  B01J13/00 ,  C02F1/56 ,  C04B24/26 ,  C08F2/32 ,  C08F8/12 ,  C08F26/02 ,  C08F126/02 ,  C08L39/02 ,  C09K8/32 ,  D21H17/34 ,  D21H21/10 ,  C08K5/10

    CPC分类号： D21H21/10 ,  C02F1/56 ,  C04B24/2652 ,  C08F2/32 ,  C08F26/02 ,  C08F8/12 ,  C09K8/32 ,  Y02W10/37

    摘要： A process for the preparation of a stable water-in-oil emulsion of a hydrolyzed polymer of an N-vinyl amide of the formula ##STR1## in which R and R.sup.1 denote H or C.sub.1 -C.sub.6 alkyl, by the polymerization of a compound of the formula I alone or in admixture with another ethylenically unsaturated monomer in the presence of a polymerization initiator and emulsifier in the form of a water-in-oil emulsion, to form a water-in-oil polymeric emulsion, followed by hydrolysis of the polymer in the form of the water-in-oil polymeric emulsion in the presence of an acid or base and from 1 to 30 wt %, based on the polymer, of an emulsifier, the emulsifier used being a mixture of (a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B)m, (A)-B or (B)-A, in which in each case (a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B).sub.m, (A).sub.n B or (B).sub.n A, in which in each case A is a hydrophobic homopolymer or copolymer having a degree of polymerization of at least 3, B is a hydrophilic homopolymer or copolymer having a degree of polymerization of at least 3, m is equal to or greater than 1, and n is equal to or greater than 2, and (b) from 5 to 95 wt % of another water-in-oil emulsifier having a molar mass below 1000 g/mol.

    摘要翻译： PCT No.PCT / EP95 / 01818 Sec。 371日期：1996年11月21日 102（e）日期1996年11月21日PCT提交1995年5月13日PCT公布。 公开号WO95 / 32227 PCT 日期：1995年11月30日制备式（I）的N-乙烯基酰胺的水解聚合物的稳定的油包水乳液的方法，其中R和R 1表示H或C 1 -C 6烷基 通过在聚合引发剂和油包水乳液形式的乳化剂的存在下单独或与另一种烯属不饱和单体的混合物聚合式I化合物，以形成油包水聚合物 乳液，然后在酸或碱的存在下以油包水型聚合物乳液的形式水解聚合物，并且基于聚合物为1至30重量％的乳化剂，所使用的乳化剂为 （a）5至95重量％的结构（AB）m，（A）-B或（B）-A的嵌段或接枝共聚物的混合物，其中在每种情况下（a）5至95重量％ 结构（AB）m，（A）nB或（B）nA的嵌段或接枝共聚物的％，其中在每种情况下A是具有聚合度的疏水性均聚物或共聚物 至少3，B是具有至少3，m等于或大于1，n等于或大于2的聚合度的亲水均聚物或共聚物，和（b）5至95重量％ 的另一种油包水乳化剂，其摩尔质量低于1000g / mol。

    Graft polymers of polymers containing vinyl ester and/or vinyl alcohol units and ethylenically unsaturated compounds, their preparation and their use
    10.
    发明授权
    Graft polymers of polymers containing vinyl ester and/or vinyl alcohol units and ethylenically unsaturated compounds, their preparation and their use 失效
    含有乙烯基酯和/或乙烯醇单元和烯键式不饱和化合物的聚合物的接枝聚合物，其制备及其应用

    公开(公告)号：US6060566A

    公开(公告)日：2000-05-09

    申请号：US983141

    申请日：1998-01-21

    申请人： Walter Denzinger ,  Martin Rubenacker ,  Claudia Nilz ,  Primoz Lorencak ,  Dietmar Monch ,  Rudolf Schuhmacher ,  Andreas Stange

    发明人： Walter Denzinger ,  Martin Rubenacker ,  Claudia Nilz ,  Primoz Lorencak ,  Dietmar Monch ,  Rudolf Schuhmacher ,  Andreas Stange

    IPC分类号： C08B37/00 ,  C08F8/12 ,  C08F261/04 ,  C08F263/02 ,  C08F283/06 ,  C08F291/00 ,  C09D7/45 ,  D21H17/34 ,  D21H17/37 ,  D21H21/10 ,  D21H21/14 ,  D21H21/16 ,  D21H21/18 ,  C08F263/04 ,  C08L51/04

    CPC分类号： D21H17/37 ,  C08F261/04 ,  C08F263/02 ,  C08F8/12 ,  C08F8/44 ,  D21H21/10 ,  D21H21/146 ,  D21H21/16 ,  D21H21/18

    摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures comprising(a) from 1 to 100% by weight of N-vinylcarboxamides of the formula ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0 to 99% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule,in the presence of(B) polymers which contain units of vinyl esters of saturated C.sub.1 -C.sub.4 -carboxylic acids and/or vinyl alcohol units, or of mixtures which contain these polymers and polymers having at least 3 alkylene oxide units or polytetrahydrofuran,in a weight ratio (A):(B) of from 95:5 to 10:90 and, if required, subsequent elimination of the group ##STR2## from the polymerized monomers (I) of the graft polymer with formation of units of the formula ##STR3## and the graft polymers described above are used in the production of paper, board and cardboard as dry and wet strength agents, as retention and drainage aids and as promoters in diketene sizing and as starch cationization agents, as dispersants for pigments and as creping assistants in the production of tissue papers.

    摘要翻译： PCT No.PCT / EP96 / 02991 Sec。 371日期1998年1月21日 102（e）1998年1月21日PCT PCT 1996年7月9日PCT公布。 第WO97 / 04014号公报 日期1997年2月6日通过（A）单体或单体混合物的自由基聚合获得接枝聚合物，所述单体或单体混合物包含（a）1至100重量％的下式的N-乙烯基甲酰胺其中R 1和R 2各自为H或C 1 -C 6 - 烷基，（b）0至99重量％的可与单体（a）和（c）共聚的其它单烯属不饱和单体，0至5重量％的具有至少两个烯属不饱和的非共轭双键的单体 分子，在（B）包含饱和C 1 -C 4羧酸和/或乙烯醇单元的乙烯基酯单元的聚合物存在下，或包含这些聚合物和具有至少3个烯化氧单元或聚四氢呋喃的聚合物的混合物的存在下， 在95:5至10:90的重量比（A）：（B））中，如果需要，随后从形成下式的单元的接枝聚合物的聚合单体（I）中除去该基团， 上述接枝聚合物用于制备 纸，纸板和纸板作为干和湿强度剂，作为保留和引流助剂以及作为二烯酮上浆和淀粉阳离子化剂的促进剂，作为颜料的分散剂和用于生产薄纸的起皱助剂。