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    Polyhydantoins from unsaturated carboxylic acids and polyiso(thio)cyanates
    4.
    发明授权
    Polyhydantoins from unsaturated carboxylic acids and polyiso(thio)cyanates 失效
    来自不饱和羧酸的聚乙内酰脲和聚（硫代）氰酸酯

    公开(公告)号：US4289868A

    公开(公告)日：1981-09-15

    申请号：US100712

    申请日：1979-12-06

    申请人： Jurgen Lewalter ,  Rudolf Merten ,  Wilfried Zecher ,  Willi Dunwald

    发明人： Jurgen Lewalter ,  Rudolf Merten ,  Wilfried Zecher ,  Willi Dunwald

    IPC分类号： C07D233/72 ,  C08G18/67 ,  C08G18/34 ,  C07D233/80 ,  C08G18/38

    CPC分类号： C07D233/72 ,  C08G18/671 ,  C08G18/6755

    摘要： Poly(thio)hydantoins are prepared by reacting an iso(thio)cyanate having at least two iso(thio)cyanate moieties with a compound of the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and each represents hydrogen, halogen, a C.sub.1 -C.sub.20 aliphatic group, a C.sub.7 -C.sub.20 aliphatic-aromatic group, a C.sub.6 -C.sub.20 aromatic group or a heterocyclic group having from 4 to 16 ring members and at least one N, O or S atom;A represents CN, COR, substituted or unsubstituted C.sub.1 -C.sub.20 aliphatic group, C.sub.7 -C.sub.20 aliphatic-aromatic group, C.sub.6 -C.sub.20 aromatic group or a heterocyclic group having from 4 to 16 ring members and at least one N, O or S atom wherein the substituents are NO.sub.2, COOR.sub.4, CN, CO or OH; R and R.sup.4 are selected from the definition of R.sup.1 and R.sup.2 with the exclusion of halogen;M represents OH or ##STR2## and R.sup.6 represents hydrogen, unsubstituted or substituted C.sub.2 -C.sub.20 aliphatic, C.sub.5 -C.sub.12 cycloaliphatic, C.sub.6 -C.sub.20 aliphatic aromatic, or a C.sub.5 -C.sub.12 aromatic or C.sub.5 -C.sub.12 cycloaliphatic containing a heteroatom N, O or S in the ring, wherein the substituents are at least one halogen, C.sub.1 -C.sub.10 alkyl, or C.sub.6 -C.sub.12 aryl.

    摘要翻译： 聚（硫）乙内酰脲通过使具有至少两个异（硫代）氰酸酯部分的异（硫代）氰酸酯与下式化合物反应制备：其中R 1和R 2相同或不同，各自表示氢，卤素， 具有4至16个环成员和至少一个N，O或S原子的C 1 -C 20脂族基团，C 7 -C 20脂族 - 芳族基团，C 6 -C 20芳族基团或杂环基团; A表示CN，COR，取代或未取代的C 1 -C 20脂族基团，C 7 -C 20脂族 - 芳族基团，C 6 -C 20芳族基团或具有4至16个环成员和至少一个N，O或S原子的杂环基，其中 取代基是NO 2，COOR 4，CN，CO或OH; R和R4选自R1和R2的定义，不包括卤素; M代表OH或者R 6代表氢，未取代或取代的C 2 -C 20脂族C 5 -C 12脂环族C 6 -C 20脂族芳族或C 5 -C 12芳族或C 5 -C 12脂环族基，其含有杂原子N，O或S 在环中，其中取代基是至少一个卤素，C 1 -C 10烷基或C 6 -C 12芳基。