公开(公告)号：US4100133A

公开(公告)日：1978-07-11

申请号：US802087

申请日：1977-05-31

申请人： William D. Emmons ,  Peter R. Sperry ,  Kayson Nyi

发明人： William D. Emmons ,  Peter R. Sperry ,  Kayson Nyi

IPC分类号： C08K5/33 ,  C09D4/06 ,  C08L31/02

CPC分类号： C08K5/33 ,  C08K5/00 ,  C09D4/06 ,  Y10T428/31935

摘要： This invention is concerned with coating and/or impregnating compositions comprising(a) A copolymer of 5 to 50% by weight of dicyclopentenyl acrylate or methacrylate with 50 to 95% by weight of at least one other monoethylenically unsaturated comonomer.(b) An essentially non-volatile reactive comonomer consisting of dicyclopentenyl acrylate or methacrylate or a mixture thereof, or comprising a mixture of at least 50% by weight of one or both of these monomers with up to 50% by weight of at least one other reactive monomer, such as a (C.sub.10 -C.sub.20)alkyl acrylate or methacrylate, a (C.sub.10 -C.sub.20)alkenyl acrylate or methacrylate, a di(C.sub.4 -C.sub.20)-alkyl fumarate, maleate, or itaconate, or a polyethylenically unsaturated monomer, such as a polyol polymethacrylate, e.g. glycol dimethacrylate, or the analogous diacrylate, or mixtures of two or more such monomers.(c) A polyvalent metal-containing complex or salt that catalyzes the oxidative curing of a) and b), such as cobalt naphthenate, and(d) A volatile oxime stabilizer.Such compositions are characterized by the fact that they can have exceptionally high solids content and rapid cure by air-drying to exceptional properties of hardness and resistance to solvents even without baking.

摘要翻译： 本发明涉及包含（A）5至50重量％的丙烯酸二环戊烯酯或甲基丙烯酸酯与50至95重量％的至少一种其它单烯属不饱和共聚单体的共聚物的涂料和/或浸渍组合物。

公开(公告)号：US4138390A

公开(公告)日：1979-02-06

申请号：US860664

申请日：1977-12-15

申请人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

发明人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

IPC分类号： C08F291/00 ,  C09D4/06 ,  C09D115/02 ,  C08K5/33 ,  C08L31/02

CPC分类号： C09D115/02 ,  C08F291/00 ,  C09D4/06 ,  C08K3/22 ,  C08K5/098 ,  C08K5/33 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

摘要： This invention is concerned with certain vinyl resin coating compositions in which the vinyl resin binder or film-forming component is normally dissolved in an organic solvent which is volatilized after application of the composition to the surface of substrates to be finished. The vinyl resin component is generally of high molecular weight and it is normally difficult to obtain a reasonable viscosity in the coating composition without excessive dilution with organic solvent and the necessity to apply a plurality of coats to obtain the desired protective thickness. The present invention has been found to alleviate or reduce this difficulty in the particular solution coating compositions with which it is concerned, namely thermoplastic vinyl or acrylic polymer solutions, polyvinyl acetals, and chlorinated polyisoprene containing about 64-65% chlorine. In the compositions of the present invention, the vinyl resin is dissolved in an organic liquid vehicle which consists essentially of a non-volatile reactive monomer including dicyclopentenyl acrylate or methacrylate or comprises a predominant proportion of such non-volatile reactive monomer. Also essential components are a siccative, that is, a polyvalent metal-containing complex or salt that catalyzes the oxidative curing of the mixture of the reactive monomer and the film-forming polymeric binder, and a fugitive agent, that is, a volatile oxime stabilizer, for inhibiting the action of the oxidation catalyst. The compositions may also contain pigments, rheology-control agents, pigment-dispersing agents and other components common in the coating art.

摘要翻译： 本发明涉及某些乙烯基树脂涂料组合物，其中乙烯基树脂粘合剂或成膜组分通常溶于有机溶剂中，有机溶剂在将组合物施加到待完成的基材表面后挥发。 乙烯基树脂组分通常具有高分子量，并且通常难以在涂料组合物中获得合理的粘度，而不会用有机溶剂过度稀释，并且需要涂覆多个涂层以获得所需的保护厚度。 已经发现本发明减轻或减少了与其有关的特定溶液涂料组合物，即热塑性乙烯基或丙烯酸类聚合物溶液，聚乙烯醇缩醛和含有约64-65％氯的氯化聚异戊二烯的困难。 在本发明的组合物中，乙烯基树脂溶解在有机液体载体中，其基本上由包含丙烯酸二环戊烯酯或甲基丙烯酸酯的非挥发性反应性单体组成或包含主要部分的这种非挥发性反应性单体。 还必须的组分是一种消音剂，即催化反应性单体和成膜聚合物粘合剂的混合物的氧化固化的多价金属络合物或盐，以及挥发剂，即挥发性肟稳定剂 ，用于抑制氧化催化剂的作用。 组合物还可以含有颜料，流变控制剂，颜料分散剂和涂料领域常见的其它成分。

公开(公告)号：US4131580A

公开(公告)日：1978-12-26

申请号：US851325

申请日：1977-11-14

申请人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

发明人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

IPC分类号： C09D5/02 ,  C08F291/00 ,  C08F299/04 ,  C08G63/48 ,  C09D4/02 ,  C09D4/06 ,  C09D5/00 ,  C09D157/06 ,  C08L33/08 ,  C08L33/12

CPC分类号： C09D4/06 ,  C08F291/00 ,  C08F299/0478 ,  C08G63/48 ,  C09D157/06 ,  Y10T428/31794

摘要： The present invention is concerned with film-forming polymer dispersions, especially in aqueous systems, such as aqueous solutions of polymers of monoethylenically unsaturated monomers as well as latices or dispersions in an aqueous medium of water-insoluble particles of polymers, such as those obtained by emulsion polymerization. It involves the addition to such aqueous polymer systems in order to improve hardness, blocking-resistance and film-formation at room temperature or below, of a non-volatile, reactive monomer comprising dicyclopentenyl acrylacte or methacrylate to serve as an air-curing coalescent.

摘要翻译： 本发明涉及成膜聚合物分散体，特别是在水性体系中，例如单烯属不饱和单体的聚合物的水溶液以及水不溶性聚合物颗粒的水性介质中的胶乳或分散体，例如通过 乳液聚合。 为了提高包含二环戊烯基丙烯酸酯或甲基丙烯酸酯的非挥发性反应性单体在室温或更低温度下的硬度，耐粘连性和成膜性，可用作空气固化聚结剂。

公开(公告)号：US4180645A

公开(公告)日：1979-12-25

申请号：US908426

申请日：1978-05-22

申请人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

发明人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

IPC分类号： C08G18/04 ,  C08G18/32 ,  C08G18/83 ,  C08G18/30 ,  C08G18/22 ,  C08L27/00 ,  C08L75/04

CPC分类号： C08G18/3296 ,  C08G18/04 ,  C08G18/83

摘要： This invention is concerned with autoxidizable coating compositions which contain(a) a member selected from the group consisting of an organic polyisocyanate, a urethane oil, and a uralkyd;(b) at least one non-volatile reactive liquid monomer selected from the group consisting of dicyclopentenyl acrylate and dicyclopentenyl methacrylate; and(c) an effective amount of a polyvalent metal-containing complex or salt that catalyzes the curing of (a) and (b).Use of the non-volatile reactive liquid component enables the production of coating compositions having high application solids content and yet having suitable viscosity for efficient handling. The coatings obtained from the compositions of the present invention combine the typical desirable properties including durability, weather-resistance, etc. of polyurethane coatings and often with unexpected enhancement of the quality of the coatings, such as in respect to toughness, while providing such compositions having higher solids content to facilitate the coating operations therewith.

摘要翻译： 本发明涉及可自动氧化的涂料组合物，其含有（a）选自有机多异氰酸酯，聚氨酯油和uralkyd的成员; （b）至少一种选自丙烯酸二环戊烯酯和甲基丙烯酸二环戊烯酯的非挥发性反应性液体单体; 和（c）有效量的催化（a）和（b）的固化的多价金属络合物或盐。 使用非挥发性反应性液体组分使得能够生产具有高应用固体含量并且具有适当粘度以用于有效处理的涂料组合物。 由本发明组合物获得的涂层结合了聚氨酯涂料的典型期望性质，包括耐久性，耐候性等，并且通常具有意想不到的提高涂层质量（例如韧性），同时提供这种组合物 具有较高的固体含量以便于其涂覆操作。

公开(公告)号：US4071489A

公开(公告)日：1978-01-31

申请号：US665017

申请日：1976-03-08

申请人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

发明人： William D. Emmons ,  Kayson Nyi ,  Peter R. Sperry

IPC分类号： C08F20/00 ,  C08F20/10 ,  C08F283/01 ,  C08F290/00 ,  C08F291/00 ,  C08F299/00 ,  C08F299/04 ,  C08G63/48 ,  C09D4/00 ,  C09D4/02 ,  C09D4/06 ,  C09D157/06 ,  C09D3/66

CPC分类号： C09D4/06 ,  C08F291/00 ,  C08F299/0478 ,  C08G63/48 ,  C09D157/06

摘要： This invention is concerned with coating compositions comprising an unsaturated polyol/polycarboxylic acid alkyd or polyester condensate resin (including drying oil-modified alkyd), the polycarboxylic acid or anhydride precursor(s) of which alkyd may be aromatic, aliphatic, or both. In one preferred embodiment Type A, the polyacid is predominantly or exclusively aliphatic and in another Type B, it is predominantly or exclusively aromatic in character. The alkyd or polyester is carried (dissolved) predominantly or exclusively in a substantially non-volatile reactive liquid consisting essentially of a) dicyclopentenyl acrylate or methacrylate or mixtures thereof or of b) a mixture of such (meth)acrylate with one or more alkyl or alkenyl esters of acrylic or methacrylic acid in which the alkyl and/or alkenyl group contains 10 to 20 carbon atoms. The compositions also contain a polyvalent metal-containing drier or siccative; optionally a volatile agent for inhibiting the action of the drier, i.e., a fugitive stabilizer; they may also contain pigments, rheology control agents, pigment-dispersing agents, and other components.

摘要翻译： 本发明涉及包含不饱和多元醇/多元羧酸醇酸树脂或聚酯缩合物树脂（包括干燥油改性醇酸树脂）的多元羧酸或酸酐前体的涂料组合物，其醇酸树脂可以是芳族的，脂族的或两者的。 在一个优选的实施方案中，A型，多酸主要是或全部是脂族的，而在另一种类型B中，其主要或全部是芳族的。 醇酸或聚酯主要或完全地以基本上不挥发的反应性液体（主要由a）二烯基丙烯酸酯或甲基丙烯酸酯或其混合物或b）这种（甲基）丙烯酸酯与一种或多种烷基的混合物或 丙烯酸或甲基丙烯酸的链烯基酯，其中烷基和/或烯基含有10-20个碳原子。 该组合物还含有多价含金属的干燥剂或干燥剂; 任选地用于抑制干燥剂即挥发性稳定剂的作用的挥发剂; 它们也可以含有颜料，流变控制剂，颜料分散剂和其它组分。

公开(公告)号：US4178425A

公开(公告)日：1979-12-11

申请号：US908415

申请日：1978-05-22

申请人： William D. Emmons ,  Kayson Nyi

发明人： William D. Emmons ,  Kayson Nyi

IPC分类号： C04B26/06 ,  C04B41/48 ,  C08F20/30 ,  C08F283/00 ,  C08F299/04 ,  C08G18/04 ,  C08G18/32 ,  C08G18/63 ,  C09D4/00 ,  C09D4/06 ,  C09D133/14 ,  C09D167/00 ,  C09D167/06 ,  C09D167/08 ,  C08G18/22 ,  C08G18/30 ,  C08L27/00 ,  C08L75/04

CPC分类号： C09D167/08 ,  C04B26/06 ,  C04B41/483 ,  C08F20/30 ,  C08F283/00 ,  C08F299/0478 ,  C08G18/04 ,  C08G18/3296 ,  C08G18/637 ,  C09D133/14 ,  C09D167/00 ,  C09D167/06 ,  C09D4/00 ,  C09D4/06

摘要： This invention is concerned with autoxidizable coating compositions which contain(1) a member of the group consisting of an organic polyisocyanate, an isocyanate-modified drying oil, and a uralkyd;(2) at least one non-volatile reactive liquid monomer selected from the group consisting of dicyclopentenyloxyalkyl acrylate and dicyclopentenyloxyalkyl methacrylate; and(3) an effective amount of a polyvalent metal-containing complex or salt that catalyzes the curing of (1) and (2).Use of the non-volatile reactive liquid component enables the production of coating compositions having high application solids content and yet having suitable viscosity for efficient handling. The reduced volatile component improves the environmental aspects of preparing and using the coating compositions while the combining of these materials in the film results in enhancement of the film properties without detriment to the qualities normally desired and attained with the polyurethane type of coating composition.

摘要翻译： 本发明涉及可自动氧化的涂料组合物，其包含（1）由有机多异氰酸酯，异氰酸酯改性的干燥油和uralkyd组成的组中的成员; （2）至少一种选自丙烯酸二环戊烯氧基烷基酯和甲基丙烯酸二环戊烯氧基烷基酯的非挥发性反应性液体单体; 和（3）有效量的催化（1）和（2）的固化的多价金属络合物或盐。 使用非挥发性反应性液体组分使得能够生产具有高应用固体含量并且具有适当粘度以用于有效处理的涂料组合物。 挥发性降低的组分改善了制备和使用涂料组合物的环境方面，而这些材料在膜中的组合导致膜性能的提高，而不损害通常所需的和用聚氨酯类型的涂料组合物达到的质量。

公开(公告)号：US4145503A

公开(公告)日：1979-03-20

申请号：US782129

申请日：1977-03-28

申请人： William D. Emmons ,  Kayson Nyi

发明人： William D. Emmons ,  Kayson Nyi

IPC分类号： C08F20/30 ,  C08F299/06 ,  C08F36/00 ,  C08F4/32 ,  C08F136/00 ,  C08F236/00

CPC分类号： C08F20/30 ,  C08F299/06 ,  Y10S525/92 ,  Y10S525/921 ,  Y10S525/922

摘要： The invention is concerned with novel autoxidizable compositions comprising an unsaturated acid ester of a glycol monodicyclopentenyl ether, a condensation or vinyl addition polymer, a siccative and a volatile stabilizer, which compositions are uniquely adapted to be formulated with high solids and practical viscosity ranges for coating and/or impregnating purposes.

摘要翻译： 本发明涉及包含二醇单环戊烯基醚的不饱和酸酯，缩合或乙烯基加成聚合物，干燥和挥发性稳定剂的新型可自动氧化组合物，该组合物独特地适于配制高固含量和实用粘度范围 和/或浸渍目的。

公开(公告)号：US4261872A

公开(公告)日：1981-04-14

申请号：US908427

申请日：1978-05-22

申请人： William D. Emmons ,  Kayson Nyi

发明人： William D. Emmons ,  Kayson Nyi

IPC分类号： C08F291/00 ,  C08L91/00 ,  C09D133/06 ,  C09D167/06 ,  C09D167/08 ,  C08F36/00 ,  C08K5/16 ,  C08L75/00

CPC分类号： C09D167/08 ,  C08F291/00 ,  C09D133/062 ,  C09D167/06 ,  C08L91/005 ,  Y10S525/921

摘要： The invention is concerned with novel autoxidizable compositions comprising an unsaturated acid ester of a glycol monodicyclopentenyl ether, a condensation or vinyl addition polymer, a siccative and a volatile stabilizer, which compositions are uniquely adapted to be formulated with high solids and practical viscosity ranges for coating and/or impregnating purposes.

摘要翻译： 本发明涉及包含二醇单环戊烯基醚的不饱和酸酯，缩合或乙烯基加成聚合物，干燥和挥发性稳定剂的新型可自动氧化组合物，该组合物独特地适于配制高固含量和实用粘度范围 和/或浸渍目的。

公开(公告)号：US4141868A

公开(公告)日：1979-02-27

申请号：US806572

申请日：1977-06-14

申请人： William D. Emmons ,  Kayson Nyi

发明人： William D. Emmons ,  Kayson Nyi

IPC分类号： C04B26/06 ,  C04B41/48 ,  C08F20/30 ,  C08F283/00 ,  C08F299/04 ,  C09D4/00 ,  C09D4/06 ,  C09D133/14 ,  C09D167/00 ,  C09D167/06 ,  C09D167/08 ,  C08L91/00

CPC分类号： C09D167/08 ,  C04B26/06 ,  C04B41/483 ,  C08F20/30 ,  C08F283/00 ,  C08F299/0478 ,  C09D133/14 ,  C09D167/00 ,  C09D167/06 ,  C09D4/00 ,  C09D4/06

摘要： The present invention is concerned with film-forming polymer dispersions, especially in aqueous systems, such as aqueous solutions of polymers of monoethylenically unsaturated monomers as well as latices or dispersions in an aqueous medium of water-insoluble particles of polymers, such as those obtained by emulsion polymerization. It involves the addition to such aqueous polymer systems in order to improve hardness, blocking-resistance, print-resistance and film-formation to yield coherent films at room temperature or below, of a non-volatile, reactive monomer comprising a (meth)acrylic acid ester of a monohydroxy diolether of dicyclopentenyl alcohol to serve as an air-curing coalescent.The designation (meth)acrylic acid is intended to refer to either acrylic acid or methacrylic acid and also generically to both. Similarly, (meth)acrylate, if and when used in the specification and claims herein, is intended to generically refer to an "acrylate" and a "methacrylate".

摘要翻译： 本发明涉及成膜聚合物分散体，特别是在水性体系中，例如单烯属不饱和单体的聚合物的水溶液以及水不溶性聚合物颗粒的水性介质中的胶乳或分散体，例如通过 乳液聚合。 它涉及添加到这种水性聚合物体系中以提高硬度，抗粘连性，耐印刷性和成膜性，从而在室温或更低温度下产生包含（甲基）丙烯酸酯的非挥发性反应性单体的粘结膜 二环戊烯醇的单羟基二油醚的酸酯作为空气固化聚结剂。

公开(公告)号：US4299761A

公开(公告)日：1981-11-10

申请号：US21660

申请日：1979-03-19

申请人： William D. Emmons ,  Kayson Nyi

发明人： William D. Emmons ,  Kayson Nyi

IPC分类号： C04B26/06 ,  C08F20/30 ,  C08J3/20

CPC分类号： C08F20/30 ,  C04B26/06 ,  Y10T428/20 ,  Y10T428/24314

摘要： Polymer concrete compositions of essentially anhydrous character comprising an inert, inorganic particulate or granular material, such as sand, crushed stone or rock, and mixtures thereof, mixed with a monomeric dicyclopentenyloxylalkyl acrylate or methacrylate or mixture thereof to form a paste or slurry suitable upon addition thereto of a polyvalent metal salt drier or siccative, preferably with an organic peroxide free radical initiator to be used to form (or to patch previously formed or laid) concrete floors and road pavements are disclosed.

摘要翻译： 具有基本上无水性的聚合物混凝土组合物，其包含与丙烯酸酯或甲基丙烯酸单体二环戊烯基烷基酯或其混合物混合的惰性无机颗粒或颗粒材料，例如沙子，粉碎的石头或岩石及其混合物，以形成适合于添加的浆料或浆料 公开了多价金属盐干燥器或干燥剂，优选用有机过氧化物自由基引发剂形成（或修补先前形成或铺设的）混凝土地板和道路路面的方法。