公开(公告)号：US4097396A

公开(公告)日：1978-06-27

申请号：US819986

申请日：1977-07-28

申请人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Edward J. Shuster ,  Frederick Louis Schmitt

发明人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Edward J. Shuster ,  Frederick Louis Schmitt

IPC分类号： C11B9/00 ,  C11D3/50 ,  C11D9/44

CPC分类号： C11B9/0011 ,  C07C323/00 ,  C07C327/00

摘要： Perfumed articles which are soaps or detergents containing alpha oxo sulfides having the structure: ##STR1## wherein R is methyl or hydrogen and X is a ketone having the structure: ##STR2## and Y is one of methyl, methallyl having the structure: ##STR3## 1-propyl, 2-methyl-1-propyl and acetyl which have imparted thereto sweet, green, floral, herbal, vegetative, basil-like, minty, melony, grapefruit, fruity and alliaceous aromas with yara, neroli and/or verdima-like nuances.

摘要翻译： 具有以下结构的肥皂或洗涤剂的含有α-氧代硫化物的香料制品：其中R是甲基或氢，X是具有以下结构的酮：Y和Y是具有以下结构的甲基，甲代烯丙基之一：

公开(公告)号：US4065408A

公开(公告)日：1977-12-27

申请号：US723534

申请日：1976-09-15

申请人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Edward J. Shuster ,  Frederick Louis Schmitt

发明人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Edward J. Shuster ,  Frederick Louis Schmitt

IPC分类号： C11B9/00 ,  C11D3/50

CPC分类号： C11B9/0011 ,  C07C323/00 ,  C07C327/00

摘要： Perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing .alpha.-oxy(oxo) sulfides having the structure: ##STR1## wherein R is methyl or hydrogen; X is one of ##STR2## and Y is one of methyl, methallyl (having the structure: ##STR3## 1-propyl, 2-methyl-1-propyl and acetyl which impart thereto sweet, green, floral, herbal, vegetative, basil-like, minty, melony, grapefruit, fruity and alliaceous armoas with yara, neroli and/or verdima-like nuances.

摘要翻译： 香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下结构的α-氧代（氧代）硫化物）的古龙香水制品：其中R是甲基或氢; X是之一，Y是甲基，甲代烯丙基（具有以下结构：具有以下结构：赋予甜，绿，花，草药，营养，罗勒的1-丙基，2-甲基-1-丙基和乙酰基 类似，微小的，融合的，葡萄柚的，水果和亚利桑那的安息带与雅加，橙花和/或verdima的细微差别。

公开(公告)号：US4094824A

公开(公告)日：1978-06-13

申请号：US819961

申请日：1977-07-28

申请人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Edward J. Shuster ,  Frederick Louis Schmitt

发明人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Edward J. Shuster ,  Frederick Louis Schmitt

IPC分类号： C11B9/00 ,  C11D3/50

CPC分类号： C11B9/0011 ,  C07C323/00 ,  C07C327/00

摘要： Perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing .alpha.-oxy(oxo) sulfides having the structure: ##STR1## wherein R is methyl or hydrogen; X is one of ##STR2## and Y is one of methyl, methallyl (having the structure: ##STR3## 1-propyl, 2-methyl-1-propyl and acetyl which impart thereto sweet, green, floral, herbal, vegetative, basil-like, minty, melony, grapefruit, fruity and alliaceous aromas with yara, neroli and/or verdima-like nuances.

摘要翻译： 香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下结构的α-氧代（氧代）硫化物）的古龙香水制品：其中R是甲基或氢; X是之一，Y是甲基，甲代烯丙基（具有以下结构：具有以下结构：赋予甜，绿，花，草药，营养，罗勒的1-丙基，2-甲基-1-丙基和乙酰基 类似，微小，融合，葡萄柚，水果和亚麻香气与雅加，橙花和/或verdima的细微差别。

公开(公告)号：US4070308A

公开(公告)日：1978-01-24

申请号：US723529

申请日：1976-09-15

申请人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Frederick Louis Schmitt

发明人： William J. Evers ,  Howard H. Heinsohn, Jr. ,  Frederick Louis Schmitt

IPC分类号： C11B9/00

CPC分类号： C11B9/0011 ,  C07C323/00

摘要： Perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing .alpha.-oxy(oxo)mercaptans having the structure: ##STR1## wherein R is any of ethyl, 1-propyl, 2-propyl or 1-butyl; and X is one of: ##STR2## which imparts thereto grapefruit-like, green fruity, concord grape and buchu-leaf oil-like aromas.

摘要翻译： 香料和香料组合物和香料制品，包括肥皂，洗涤剂，粉末以及含有具有以下结构的α-氧代（氧代）硫醇的古龙水：其中R是乙基，1-丙基，2-丙基或1-丁基 ; X是以下之一：或，赋予葡萄柚样，绿色水果，和谐葡萄和buchu-leaf油样香气。

公开(公告)号：US4119576A

公开(公告)日：1978-10-10

申请号：US851724

申请日：1977-11-15

申请人： Mark A. Sprecker ,  Manfred Hugo Vock ,  Frederick Louis Schmitt ,  John B. Hall ,  James Milton Sanders

发明人： Mark A. Sprecker ,  Manfred Hugo Vock ,  Frederick Louis Schmitt ,  John B. Hall ,  James Milton Sanders

IPC分类号： A23G3/00 ,  A23G3/36 ,  A23G4/00 ,  A23G4/06 ,  A23G4/12 ,  A24B15/30 ,  A24B15/34 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C07C403/00 ,  C11B9/00

CPC分类号： A23G3/36 ,  A23G4/06 ,  A23G4/126 ,  A24B15/30 ,  A24B15/34 ,  C07C403/16 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C11B9/0015 ,  C11B9/0034 ,  C11D3/0084 ,  C07C2101/14

摘要： Processes and compositions are described for the use in perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as perfume and perfumed article aroma imparting materials of 1-butanoyl-3,3-dimethylcyclohexane having the formula: ##STR1## Addition of the 1-butanoyl-3,3-dimethylcyclohexane (also referred to herein as 1-(3,3-dimethylcyclohexyl)-butan-1-one) to perfumes, colognes and perfumed articles produces fruity, berry and herbaceous aromas with green and tobacco nuances.

摘要翻译： 描述了用于香料和香料制品香气增强，增强和赋予组合物的方法和组合物，以及具有下式的1-丁酰基-3,3-二甲基环己烷的香料和香料制品香气赋予材料：添加1 - 丁酰基-3,3-二甲基环己烷（本文也称为1-（3,3-二甲基环己基）丁烷-1-酮）与香水，古龙水和香料制品产生具有绿色和烟草细微差别的水果，浆果和草本香气。

公开(公告)号：US4089986A

公开(公告)日：1978-05-16

申请号：US834399

申请日：1977-09-19

申请人： Kenneth K. Light ,  Manfred Hugo Vock ,  Edward J. Shuster ,  Frederick Louis Schmitt

发明人： Kenneth K. Light ,  Manfred Hugo Vock ,  Edward J. Shuster ,  Frederick Louis Schmitt

IPC分类号： C07C69/02 ,  A23G4/00 ,  A23G4/06 ,  A23L27/20 ,  A61K8/33 ,  A61K8/34 ,  A61K8/35 ,  A61K8/37 ,  A61Q13/00 ,  C07C27/00 ,  C07C31/137 ,  C07C33/05 ,  C07C35/29 ,  C07C41/00 ,  C07C43/115 ,  C07C43/162 ,  C07C43/305 ,  C07C45/00 ,  C07C49/317 ,  C07C49/527 ,  C07C67/00 ,  C07C239/00 ,  C07C251/44 ,  C07D303/04 ,  C11B9/00 ,  A23L1/226

CPC分类号： A23G4/06 ,  C07C35/29 ,  C11B9/0046 ,  C11D3/0084

摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 3,3-dimethyl-2(3-butenyl) norbornanol-2 (hereinafter referred to as the "norbornanol derivative" having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof) produced by a process which comprises reacting an allylic Grignard reagent having the structure: wherein X is chloro, bromo or iodo with camphene oxide having the structure: ##STR2## by either "exo" camphene oxide or "endo" camphene oxide or a mixture of "exo" and "endo" camphene oxide. Addition of the said norbornanol derivative to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavorings, chewing gums, toothpastes and medicinal products, sweet, fruity, berry-like aromas with woody, incense-like, cedarwood-like, tea-like and floral nuances and incense-like and cedarwood-like flavors with rosey, berry and tea-like nuances; and(b) In perfumes, colognes and perfumed articles, sweet, woody, thujone-like aromas with strong fir-balsam, armoise, cedarleaf, piney, earthy and camphoraceous nuances.

摘要翻译： 描述了用于食品，口香糖，牙膏和药用产品风味和芳香和香料香气的方法和组合物，其增强，增强，改性和赋予组合物以及作为食品，口香糖，牙膏，药用产品，香料和香料制品香气赋予 3,3-二甲基-2（3-丁烯基）降冰片烷醇-2的材料（以下称为“降冰片醇衍生物”，具有以下结构：（该结构旨在涵盖“endo”和“exo 通过包括使具有以下结构的烯丙基格利雅试剂（其中X为氯，溴或碘）与具有以下结构的camp氧化物反应的方法制得的：其异构体：通过“外部”camp oxide或“内 氧化camp oxide oxide or：camp camp camp camp camp camp camp camp camp camp camp camp：：：：：：：：：：：：：：：：：

公开(公告)号：US4081481A

公开(公告)日：1978-03-28

申请号：US740948

申请日：1976-11-11

申请人： Mark A. Sprecker ,  Manfred Hugo Vock ,  Frederick Louis Schmitt ,  John B. Hall ,  James Milton Sanders

发明人： Mark A. Sprecker ,  Manfred Hugo Vock ,  Frederick Louis Schmitt ,  John B. Hall ,  James Milton Sanders

IPC分类号： A23G3/00 ,  A23G3/36 ,  A23G4/00 ,  A23G4/06 ,  A23G4/12 ,  A23L27/20 ,  A24B15/30 ,  A24B15/34 ,  A61K8/35 ,  A61Q13/00 ,  C07C45/00 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C07C67/00 ,  C07C401/00 ,  C07C403/16 ,  C11B9/00 ,  C07C49/43

CPC分类号： A23G3/36 ,  A23G4/06 ,  A23G4/126 ,  A24B15/30 ,  A24B15/34 ,  C07C403/16 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C11B9/0015 ,  C11B9/0034 ,  C11D3/0084 ,  C07C2101/14 ,  Y10S514/974

摘要： Processes and compositions are described for the use in perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as perfume and perfumed article aroma imparting materials of 1-butanoyl-3,3-dimethylcyclohexane having the formula: ##STR1## produced according to the following process: Reacting 1-acetyl-3,3-dimethylcyclohexane with acetaldehyde in the presence of an inorganic base or a mixture of boron oxide and boric acid thereby forming one or more 1-butenoyl-3,3-dimethylcyclohexanes represented by the structure: ##STR2## (wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond) and reacting this compound with a reducing agent such as hydrogen in order to form a saturated ketone having the structure: ##STR3## Addition of the 1-butanoyl-3,3-dimethylcyclohexane (also referred to herein as 1-(3,3-dimethylcyclohexyl)-butan-1-one) to perfumes, colognes and perfumed articles produces fruity, berry and herbaceous aromas with green and tobacco nuances.

摘要翻译： 描述了用于香料和香料制品香气增强，增强和赋予组合物的方法和组合物，以及具有下式的1-丁酰基-3,3-二甲基环己烷的香料和香料制品香气赋予材料：＆lt; IMAGE＆gt; 以下过程：

公开(公告)号：US4064281A

公开(公告)日：1977-12-20

申请号：US765635

申请日：1977-02-04

申请人： John B. Hall ,  Mark A. Sprecker ,  Frederick Louis Schmitt ,  Manfred Hugo Vock

发明人： John B. Hall ,  Mark A. Sprecker ,  Frederick Louis Schmitt ,  Manfred Hugo Vock

IPC分类号： A23G3/00 ,  A23G3/36 ,  A23G4/00 ,  A23G4/06 ,  A23G4/12 ,  A23L27/20 ,  A24B15/30 ,  A24B15/34 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C11B9/00 ,  A23L1/226

CPC分类号： A23G3/36 ,  A23G4/06 ,  A23G4/126 ,  A24B15/30 ,  A24B15/34 ,  C07C403/16 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C11B9/0015 ,  C11B9/0034 ,  C11D3/0084 ,  C07C2101/14

摘要： Described is the compound 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane, a process for preparing same by means of reacting an allylic halide with acetyl-3,3-dimethylcyclohexane using a phase transfer agent and in a two phase system according to the reaction: ##STR1## wherein X is chloro or bromo, processes for adding 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane to consumable materials whereby:I. In foodstuffs and medicinal products, fruity, pineapple, allyl-caproate-like, galbanum and woody aroma characteristcs are augmented or enhanced and rosey, ionone, oriental-like and woody flavor characteristics are augmented or enhanced; andIi. In perfumes and perfumed articles, sweet, earthy, animal aromas with pineapple and ambery nuances and tobacco/animal notes are imparted, augmented and/or enhancedAnd flavor compositions and perfume compositions containing 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane.

摘要翻译： 描述了化合物1-乙酰基-3,3-二甲基 - （2-丙烯基）环己烷，其通过使用相转移剂使烯丙基卤化物与乙酰基-3,3-二甲基环己烷反应制备的方法， 根据以下反应的相系统：其中X是氯或溴，将1-乙酰基-3,3-二甲基 - （2-丙烯基）环己烷加入到可消耗材料中，由此：

公开(公告)号：US4122120A

公开(公告)日：1978-10-24

申请号：US819960

申请日：1977-07-28

申请人： Mark A. Sprecker ,  Manfred Hugo Vock ,  Frederick Louis Schmitt ,  John B. Hall ,  James Milton Sanders

发明人： Mark A. Sprecker ,  Manfred Hugo Vock ,  Frederick Louis Schmitt ,  John B. Hall ,  James Milton Sanders

IPC分类号： A23G3/00 ,  A23G3/36 ,  A23G4/00 ,  A23G4/06 ,  A23G4/12 ,  A23L27/20 ,  A24B15/30 ,  A24B15/34 ,  A61K8/35 ,  A61Q13/00 ,  C07C45/00 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C07C67/00 ,  C07C401/00 ,  C07C403/16 ,  C11B9/00 ,  C07C49/61

CPC分类号： A23G3/36 ,  A23G4/06 ,  A23G4/126 ,  A24B15/30 ,  A24B15/34 ,  C07C403/16 ,  C07C45/62 ,  C07C45/68 ,  C07C47/21 ,  C07C47/232 ,  C07C49/303 ,  C07C49/557 ,  C07C49/647 ,  C11B9/0015 ,  C11B9/0034 ,  C11D3/0084 ,  C07C2101/14 ,  Y10S514/974

摘要： Described is a mixture of 1-(3,3-dimethylcyclohexyl)-4-methyl-cis-2-pentene-1-one, 1-(3,3-dimethylcyclohexyl)-4-methyl-trans-2-pentene-1-one, and 1-(3,3-dimethylcyclohexyl)-4-methyl-3-pentene-1-one and a mixture of 1-(3,3-dimethylcyclohexyl)-cis-2-pentene-1-one, 1-(3,3-dimethylcyclohexyl) -trans-2-pentene-1-one and 1-(3,3-dimethylcyclohexyl)-3-pentene-1-one, useful in augmenting or enhancing flavors and perfume and perfumed article aromas.

摘要翻译： 描述了1-（3,3-二甲基环己基）-4-甲基 - 顺式-2-戊烯-1-酮，1-（3,3-二甲基环己基）-4-甲基 - 反-2-戊烯-1 - 酮和1-（3,3-二甲基环己基）-4-甲基-3-戊烯-1-酮和1-（3,3-二甲基环己基） - 顺-2-戊烯-1-酮， - （3,3-二甲基环己基） - 反式-2-戊烯-1-酮和1-（3,3-二甲基环己基）-3-戊烯-1-酮，可用于增强或增强香料和香料和香料制品香气。

公开(公告)号：US4115431A

公开(公告)日：1978-09-19

申请号：US800889

申请日：1977-05-26

申请人： John B. Hall ,  Mark A. Sprecker ,  Edward J. Shuster ,  Frederick Louis Schmitt ,  Joaquin F. Vinals

发明人： John B. Hall ,  Mark A. Sprecker ,  Edward J. Shuster ,  Frederick Louis Schmitt ,  Joaquin F. Vinals

IPC分类号： A24B15/30 ,  A24B15/34 ,  C07C37/50 ,  C07C45/42 ,  C07C49/603 ,  C07C255/49 ,  C11B9/00 ,  C11D3/50 ,  C07C121/52

CPC分类号： C07C255/00 ,  A24B15/301 ,  A24B15/34 ,  C07C37/50 ,  C07C45/42 ,  C07C49/603 ,  C11B9/0061 ,  C11D3/50

摘要： Processes and compositions are described for the use in tobacco flavor and aroma and perfume aroma augmenting, modifying, enhancing and imparting compositions and as tobacco, perfume and perfumed article aroma imparting and augmenting materials of one or more substituted dimethyl dihydroxy benzene and/or cyclohexadiene compounds, represented either by the equilibrium mixture: ##STR1## (and other tautomers) or by one of the compounds which is a constituent of said equilibrium mixture, wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and R.sub.1 is either acetyl having the structure: ##STR2## or nitrile having the structure: ##STR3## with the proviso that when the dashed line is a carbon-carbon single bond, R.sub.1 is only nitrile and when the dashed line is a carbon-carbon double bond, R.sub.1 is either nitrile or acetyl.Also described is the class of novel compounds represented either by the equilibrium mixture: ##STR4## (and other tautomers) or by one of the components of the equilibrium mixture wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond.The above-mentioned compounds, taken alone or in combination, provide and/or enhance and/or enrich "Oak Moss" notes in perfumes such as "Mousse de Chene". These compounds also provide sweet, slightly woody, "Oak Moss"-like aromas in the mainstream and sidestream on smoking and prior to smoking in tobacco articles such as cigarettes and cigars.

摘要翻译： 通过混合取代的二甲基二羟基苯或环己二烯来增强或增强消耗材料如肥皂和洗涤剂的感官特性的方法。