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公开(公告)号:US07253137B2
公开(公告)日:2007-08-07
申请号:US11487195
申请日:2006-07-14
CPC分类号: B32B3/26 , B32B3/10 , B32B5/12 , B32B5/26 , B32B37/0084 , B32B2038/0028 , B32B2262/0253 , B32B2432/00 , Y10T428/24479 , Y10T428/24612 , Y10T442/671 , Y10T442/673 , Y10T442/68 , Y10T442/699
摘要: A catalyst for preferentially reducing carbon monoxide in a hydrogen stream. The catalyst is formed from a chemical composition including a hexaaluminate, a metal hydroxide and a precious metal. The composition may be disposed on a support or may be extruded or cast into or onto a support. Incorporation of hexaaluminates allows inclusion of metal hydroxides that flux the active precious metal surface at higher temperatures than can aluminum oxide-based catalytic compositions, thereby enhancing resistance of the catalyst and monolithic support and increasing the durability and thermal range of the PROX catalyst. An additional advantage is that lesser amounts of precious metal oxides need be deposited onto the hexaaluminate, while retaining activity similar to aluminum oxide compositions.
摘要翻译: 用于优先还原氢气流中的一氧化碳的催化剂。 催化剂由包含六铝酸盐,金属氢氧化物和贵金属的化学组合物形成。 组合物可以设置在支撑体上,或者可以挤压或浇注到载体上或载体上。 六铝酸盐的加入允许包含在比氧化铝基催化剂组合物更高的温度下助熔活性贵金属表面的金属氢氧化物,从而增强催化剂和整体式载体的耐受性,并增加PROX催化剂的耐久性和热范围。 另外的优点是少量的贵金属氧化物需要沉积到六铝酸盐上,同时保持与氧化铝组合物类似的活性。
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公开(公告)号:US07105468B2
公开(公告)日:2006-09-12
申请号:US10310425
申请日:2002-12-05
CPC分类号: B01J23/002 , B01D53/864 , B01J23/58 , B01J23/63 , B01J23/89 , B01J37/0225 , B01J2523/00 , C01B3/583 , C01B2203/044 , C01B2203/047 , H01M8/0606 , H01M8/0662 , B01J2523/13 , B01J2523/25 , B01J2523/31 , B01J2523/821 , B01J2523/827 , B01J2523/828 , B01J2523/842 , B01J2523/3706
摘要: A catalyst for preferentially reducing carbon monoxide in a hydrogen stream. The catalyst is formed from a chemical composition including a hexaaluminate, a metal hydroxide and a precious metal. The composition may be disposed on a support or may be extruded or cast into or onto a support. Incorporation of hexaaluminates allows inclusion of metal hydroxides that flux the active precious metal surface at higher temperatures than can aluminum oxide-based catalytic compositions, thereby enhancing resistance of the catalyst and monolithic support and increasing the durability and thermal range of the PROX catalyst. An additional advantage is that lesser amounts of precious metal oxides need be deposited onto the hexaaluminate, while retaining activity similar to aluminum oxide compositions.
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公开(公告)号:US07595085B2
公开(公告)日:2009-09-29
申请号:US10797301
申请日:2004-03-09
申请人: Robert J. Svoboda , Haskell Simpkins , Joseph M. Keller , Vincent L. Sprenkle , Kerry D. Meinhardt , Nathan L. Canfield
发明人: Robert J. Svoboda , Haskell Simpkins , Joseph M. Keller , Vincent L. Sprenkle , Kerry D. Meinhardt , Nathan L. Canfield
IPC分类号: B05D5/12
CPC分类号: H01M4/8875 , H01M4/8621 , H01M4/8885 , H01M2008/147 , Y02E60/526
摘要: In one embodiment, the method of producing a ceramic assembly includes: disposing an electrode precursor on an electrolyte precursor having an electrolyte sintering shrinkage, disposing a stabilizer precursor having a stabilizer sintering shrinkage on the electrode precursor on a side opposite the electrolyte precursor to form a precursor assembly, and sintering the precursor assembly to form the ceramic assembly comprising a stabilizer layer, electrode, and electrolyte. The difference between the electrolyte sintering shrinkage and the stabilizer sintering shrinkage is less than or equal to ±1% and a surface of the ceramic assembly has less than or equal to about 5.0 degrees camber, as measured from the horizontal plane.
摘要翻译: 在一个实施方案中,制造陶瓷组件的方法包括:将电极前体设置在具有电解质烧结收缩率的电解质前体上,在与电解质前体相反的一侧在电极前体上设置稳定剂烧结收缩率的稳定剂前体,形成 前体组件,并烧结前体组件以形成包含稳定剂层,电极和电解质的陶瓷组件。 电解质烧结收缩率和稳定剂烧结收缩率之间的差异小于或等于±1%,陶瓷组件的表面从水平面测得的角度小于或等于约5.0度。
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公开(公告)号:US07582375B2
公开(公告)日:2009-09-01
申请号:US11199533
申请日:2005-08-08
CPC分类号: B23D31/002 , B23K26/38 , H01M8/1231 , Y10T83/0304 , Y10T83/0419 , Y10T83/2074
摘要: A method for severing a solid-oxide fuel cell bi-layer element including a structural anode and an electrolyte layer, comprising the steps of orienting the bi-layer element such that the surface thereof is accessible to laser treatment; impinging a laser beam on the electrolyte surface; moving the impinged laser beam past the surface along a path in a plane corresponding to the desired severed edge to form a groove in the element extending partially through the element to a predetermined depth; and applying a bending moment across the groove to cause the element to break into first and second portions. The groove depth is preferably about 15% of the total thickness of the element.
摘要翻译: 一种用于切断包括结构阳极和电解质层的固体氧化物燃料电池双层元件的方法,包括以下步骤:使所述双层元件定向使其表面能够进行激光处理; 将激光束撞在电解质表面上; 将冲击的激光束沿对应于期望的切割边缘的平面中的路径移动通过表面,以在元件中的部分地延伸到预定深度的元件中形成凹槽; 并且在所述凹槽上施加弯矩以使所述元件分解成第一和第二部分。 槽深度优选为元件总厚度的约15%。
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