摘要:
In one embodiment, the method of producing a ceramic assembly includes: disposing an electrode precursor on an electrolyte precursor having an electrolyte sintering shrinkage, disposing a stabilizer precursor having a stabilizer sintering shrinkage on the electrode precursor on a side opposite the electrolyte precursor to form a precursor assembly, and sintering the precursor assembly to form the ceramic assembly comprising a stabilizer layer, electrode, and electrolyte. The difference between the electrolyte sintering shrinkage and the stabilizer sintering shrinkage is less than or equal to ±1% and a surface of the ceramic assembly has less than or equal to about 5.0 degrees camber, as measured from the horizontal plane.
摘要:
Lanthanum strontium cobalt iron oxides (La(1-x)SrxCoyFe1-yO3-f; (LSCF) have excellent power density (>500 mW/cm2 at 750° C.). When covered with a metallization layer, LSCF cathodes have demonstrated increased durability and stability. Other modifications, such as the thickening of the cathode, the preparation of the device by utilizing a firing temperature in a designated range, and the use of a pore former paste having designated characteristics and combinations of these features provide a device with enhanced capabilities.
摘要:
Lanthanum strontium cobalt iron oxides (La(1-x)SrxCoyFe1-yO3-f; (LSCF) have excellent power density (>500 mW/cm2 at 750° C.). When covered with a metallization layer, LSCF cathodes have demonstrated increased durability and stability. Other modifications, such as the thickening of the cathode, the preparation of the device by utilizing a firing temperature in a designated range, and the use of a pore former paste having designated characteristics and combinations of these features provide a device with enhanced capabilities.
摘要:
An electrode supported electrolyte membrane includes an electrode layer 630 facing an electrolyte layer 620. The opposing side of the electrode layer 630 includes a backing layer 640 of a material with a thermal expansion coefficient approximately equal to the thermal expansion coefficient of the electrolyte layer 620. The backing layer 640 is in a two dimensional pattern that covers only a portion of the electrolyte layer 630. An electrochemical cell such as a SOFC is formed by providing a cathode layer 610 on an opposing side of the electrolyte layer 620.
摘要:
An electrode supported electrolyte membrane includes an electrode layer 630 facing an electrolyte layer 620. The opposing side of the electrode layer 630 includes a backing layer 640 of a material with a thermal expansion coefficient approximately equal to the thermal expansion coefficient of the electrolyte layer 620. The backing layer 640 is in a two dimensional pattern that covers only a portion of the electrolyte layer 630. An electrochemical cell such as a SOFC is formed by providing a cathode layer 610 on an opposing side of the electrolyte layer 620.
摘要:
Methods for making composite anodes, such as macroporous composite anodes, are disclosed. Embodiments of the methods may include forming a tape from a slurry including a substrate metal precursor, an anode active material, a pore-forming agent, a binder, and a solvent. A laminated structure may be prepared from the tape and sintered to produce a porous structure, such as a macroporous structure. The macroporous structure may be heated to reduce a substrate metal precursor and/or anode active material. Macroporous composite anodes formed by some embodiments of the disclosed methods comprise a porous metal and an anode active material, wherein the anode active material is both externally and internally incorporated throughout and on the surface of the macroporous structure.
摘要:
A membrane device and processes for fabrication and for using are disclosed. The membrane device may include a number of porous metal membranes that provide a high membrane surface area per unit volume. The membrane device provides various operation modes that enhance throughput and selectivity for mass exchange, mass transfer, separation, and/or filtration applications between feed flow streams and permeate flow streams.
摘要:
Thin, porous metal sheets and methods for forming them are presented to enable a variety of applications and devices. The thin, porous metal sheets are less than or equal to approximately 200 μm thick, have a porosity between 25% and 75% by volume, and have pores with an average diameter less than or equal to approximately 2 μm. The thin, porous metal sheets can be fabricated by preparing a slurry having between 10 and 50 wt % solvent and between 20 and 80 wt % powder of a metal precursor. The average particle size in the metal precursor powder should be between 100 nm and 5 μm.
摘要:
Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.
摘要:
Methods for making composite anodes, such as macroporous composite anodes, are disclosed. Embodiments of the methods may include forming a tape from a slurry including a substrate metal precursor, an anode active material, a pore-forming agent, a binder, and a solvent. A laminated structure may be prepared from the tape and sintered to produce a porous structure, such as a macroporous structure. The macroporous structure may be heated to reduce a substrate metal precursor and/or anode active material. Macroporous composite anodes formed by some embodiments of the disclosed methods comprise a porous metal and an anode active material, wherein the anode active material is both externally and internally incorporated throughout and on the surface of the macroporous structure.