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公开(公告)号：US5659056A
公开(公告)日：1997-08-19
申请号：US630298
申请日：1996-04-10
摘要： The present invention relates to a method of reducing hydrolysis and coupling of substituents of siloxane end capped polymers containing hydrolyzable substituents during contact with water. The Mooney viscosity of siloxane terminated polymers is stabilized during such contact by treating the polymer with a stabilizing amount of stabilizing agent selected from the group consisting of: an acid, an acyl halide, methane sulfonic acid, toluene sulfonic acid, sulfuryl chloride, thionylchloride, phosgene, carbon dioxide, sulfur dioxide, sulfur trioxide, SOCl.sub.2 and SO.sub.2 Cl.sub.2, prior to contacting the siloxane terminated polymer with water.
摘要翻译： 本发明涉及在与水接触期间减少含有可水解取代基的硅氧烷封端聚合物的水解和偶联的方法。 硅烷封端的聚合物的门尼粘度在这种接触期间通过用稳定量的稳定剂处理聚合物而稳定，稳定剂选自：酸，酰卤，甲磺酸，甲苯磺酸，磺酰氯，亚硫酰氯， 在将硅氧烷封端的聚合物与水接触之前，将光气，二氧化碳，二氧化硫，三氧化硫，SOCl 2和SO 2 Cl 2。
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公开(公告)号：US5248722A
公开(公告)日：1993-09-28
申请号：US889945
申请日：1992-06-02
摘要： A composition utilizing terminally functionalized diene polymers or diene-vinyl substituted aromatic copolymers and oxidized carbon black particulates dispersed therein has been found to provide reduced hysteresis properties and is particularly suited for use as rubber having reduced rolling resistance or hysteresis.The polymers and copolymers are preferably terminally functionalized with a compound having a nitrogen which acts as a Lewis base when bonded to the polymer. The oxidized carbon black is characterized by a relatively high acid content, with the acid sites of the carbon black interacting with the Lewis base sites on the polymer terminals to increase the carbon-polymer affinity.
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3.发明授权
公开(公告)号：US6080835A
公开(公告)日：2000-06-27
申请号：US936364
申请日：1997-09-24
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
CPC分类号： B60C1/0016 , B60C1/00 , B60C1/0025 , B60C15/06 , C08C19/44 , C08F36/04 , C08F4/48 , Y10T152/10
摘要： A functionialized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
摘要翻译： 根据本发明的官能化聚合物包括具有通式AYLi的聚合物分子，其中A是具有通式的含环胺基团，其中R 1是二价亚烷基，氧基或氨基亚烷基或具有6个 至约20个碳原子; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; Y是二价聚合物基团，Li是与Y的碳原子键合的锂原子。
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公开(公告)号：US6025450A
公开(公告)日：2000-02-15
申请号：US112913
申请日：1998-07-09
申请人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
发明人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
CPC分类号： C08C19/44 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C15/06 , C08F36/04 , Y10S152/905
摘要： A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.
摘要翻译： 官能化聚合物包括携带至少一种选自具有通式的烷基，二烷基和环烷基胺基的官能团的聚合物链和具有以下通式的环胺基：其中R1是具有1至约12个碳原子的烷基，环烷基或芳烷基 原子，并且R 2是具有约3至约16个亚甲基的亚烷基，取代的亚烷基，氧基或N-烷基氨基 - 亚烷基。 本发明还提供了基于这样的聚合物的产品。
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5.发明授权
公开(公告)号：US5610237A
公开(公告)日：1997-03-11
申请号：US658242
申请日：1996-06-04
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
IPC分类号： B60C1/00 , C08C19/44 , C08F2/04 , C08F2/06 , C08F4/42 , C08F4/48 , C08F36/04 , C08K3/04 , C08L19/00 , C08L101/00 , C08L101/02 , C08F293/00
CPC分类号： C08F4/48 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10T152/10
摘要： A functionalized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
摘要翻译： 根据本发明的官能化聚合物包括具有通式AYLi的聚合物分子，其中A是具有通式“IMAGE”的含环胺基团，其中R 1是二价亚烷基，氧基或氨基亚烷基或取代的亚烷基 具有6至约20个碳原子; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; Y是二价聚合物基团，Li是与Y的碳原子键合的锂原子。
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6.发明授权Functionalized polymer and rubber compositions produced from solubilized anionic polymerization initiators 失效由溶解的阴离子聚合引发剂制备的官能化聚合物和橡胶组合物
公开(公告)号：US5552473A
公开(公告)日：1996-09-03
申请号：US469389
申请日：1995-06-05
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10S152/905
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer wtih a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以提供聚合物多功能性。
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7.发明授权Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物
公开(公告)号：US5491230A
公开(公告)日：1996-02-13
申请号：US175294
申请日：1993-12-29
IPC分类号： C08F4/08 , C07F1/02 , C08F4/42 , C08F4/46 , C08F4/48 , C08F236/04 , C08F236/10 , C07D225/00
CPC分类号： C07F1/02
摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.
摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。
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8.发明授权
公开(公告)号：US4123503A
公开(公告)日：1978-10-31
申请号：US771221
申请日：1977-03-23
IPC分类号： C01B21/097 , C01B21/098 , C01B25/10
CPC分类号： C01B21/0986 , C01B21/097
摘要： Thermal polymerization of (NPCl.sub.2).sub.3,4 is improved by conducting the polymerization in the presence of Lewis Acid type compounds of Al or B.
摘要翻译： （NPCl2）3,4的热聚合通过在路易斯酸型Al或B的化合物存在下进行聚合而得到改善。
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公开(公告)号：US5698646A
公开(公告)日：1997-12-16
申请号：US467370
申请日：1995-06-06
IPC分类号： C08F4/42 , C08F4/48 , C08F4/56 , C08F36/04 , C08F236/10
CPC分类号： C08F36/04
摘要： The present invention is directed toward anionic polymerization employing lithio aldimines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio aldimines have the general formula (A)Li, where A is derived from a substituted aldimine. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of a substituted aldimine and an organolithium compound. The resulting polymers may be modified with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂二醛的阴离子聚合。 锂二亚胺具有通式（A）Li，其中A衍生自取代的醛亚胺。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明考虑了聚合物，聚合物组合物及其产物，其包括来自取代的醛亚胺与有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂进行改性，其可以提供聚合物的多功能性。
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公开(公告)号：US5616704A
公开(公告)日：1997-04-01
申请号：US639980
申请日：1996-04-29
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10S152/905
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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