公开(公告)号：US20050031567A1

公开(公告)日：2005-02-10

申请号：US10500138

申请日：2003-01-20

申请人： Wilma Dausch ,  Bernd de Potzolli ,  Maximilian Angel ,  Jacqueline Engesser

发明人： Wilma Dausch ,  Bernd de Potzolli ,  Maximilian Angel ,  Jacqueline Engesser

IPC分类号： A61K8/81 ,  A61Q5/06 ,  A61K7/06 ,  A61K7/11

CPC分类号： A61K8/817 ,  A61K8/8147 ,  A61K8/8152 ,  A61K8/8158 ,  A61K8/8176 ,  A61K8/8182 ,  A61Q5/06

摘要： Hair-setting compositions comprising A) 0.5 to 20% by weight of a homopolymer of N-vinylcaprolactam or an anionic or nonionic copolymer of at least 70% by weight of N-vinylcaprolactam (polymer A), and B) 0.5 to 20% by weight of a terpolymer (polymer B) obtainable by copolymerization (a) of at least one C1-C4 N-alkylacrylamide or a C1-C4 N-alkylmethacrylamide and (b) at least one C1-C4 hydroxyalkyl ester or a C1-C4 alkyl ester of acrylic acid or methacrylic acid and (c) acrylic acid and/or methacrylic acid C) 0.5 to 20% by weight of a polymer chosen from the group consisting of copolymers of vinylpyrrolidone and a vinyl ester and of homopolymers of vinylpyrrolidone.

摘要翻译： 包含A）0.5〜20重量％的N-乙烯基己内酰胺的均聚物或至少70重量％的N-乙烯基己内酰胺（聚合物A）的阴离子或非离子共聚物，和B）0.5〜20重量％ 通过共聚（a）至少一种C 1 -C 4 N-烷基丙烯酰胺或C 1 -C 4 N-烷基甲基丙烯酰胺可获得的三元共聚物（聚合物B）的重量和（b）至少一种C 1 -C 4羟烷基酯或C 1 -C 4烷基 丙烯酸或甲基丙烯酸的酯和（c）丙烯酸和/或甲基丙烯酸C）0.5至20重量％的选自乙烯基吡咯烷酮和乙烯基酯的共聚物和乙烯基吡咯烷酮的均聚物的聚合物。

公开(公告)号：US07015294B2

公开(公告)日：2006-03-21

申请号：US10399498

申请日：2001-11-09

申请人： Wilma M. Dausch ,  Katrin Zeitz ,  Tanja Schneider ,  Maximilian Angel ,  Bernd de Potzolli ,  Claudia Wood

发明人： Wilma M. Dausch ,  Katrin Zeitz ,  Tanja Schneider ,  Maximilian Angel ,  Bernd de Potzolli ,  Claudia Wood

IPC分类号： C08F116/14

CPC分类号： A61Q5/06 ,  A61K8/8188 ,  C08F220/18

摘要： The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30° C., with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30° C., with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.

摘要翻译： 本发明涉及包含K值范围为10至60的丙烯酸酯聚合物，其可通过自由基聚合获得：30至99重量％ ％的丙烯酸叔丁酯和/或称为单体A的甲基丙烯酸叔丁酯; 1至28wt。 ％为指定为单体B的丙烯酸和/或甲基丙烯酸，以及; 0〜60重量％ ％的自由基共聚单体或称为单体C的自由基共聚单体混合物，其中至少一种单体C产生玻璃化转变温度低于30℃的均聚物，其条件是wt。 ％的总量为100.自由基聚合在C链长度为C 14至C 22的烷烃硫醇的存在下进行。本发明还涉及包含K值为10至60的丙烯酸酯聚合物，其可以 通过自由基聚合得到：30〜99wt。 ％的丙烯酸叔丁酯和/或称为单体A的甲基丙烯酸叔丁酯; 1至28wt。 ％为指定为单体B的丙烯酸和/或甲基丙烯酸，以及; 0〜60重量％ ％的自由基共聚单体或称为单体C的自由基共聚单体混合物，其中至少一种单体C产生玻璃化转变温度低于30℃的均聚物，其条件是wt。 ％的总量为100.自由基聚合在C链长为C 10〜C 22的烷烃硫醇存在下进行，然后进行过氧化氢处理。 本发明还涉及这些丙烯酸酯聚合物作为成膜剂的用途以及它们在化妆品制剂中的用途。

公开(公告)号：US20120076834A1

公开(公告)日：2012-03-29

申请号：US13246324

申请日：2011-09-27

申请人： Karl Kolter ,  Maximilian Angel

发明人： Karl Kolter ,  Maximilian Angel

IPC分类号： A61K9/00 ,  A61K31/192 ,  A61K31/616

CPC分类号： A61K31/192 ,  A61K9/5073 ,  A61K31/616

摘要： Dosage forms provided with protective coatings in which a core comprising at least one acidic active ingredient is provided with at least one inner and one outer coating layer, where the outer layer comprises, as component A, a cationic polymer which is an emulsion polymer of N,N-diethylaminoethyl methacrylate and further monomers.

摘要翻译： 提供有保护性涂层的剂型，其中包含至少一种酸性活性成分的核心设置有至少一个内部和一个外部涂层，其中外层包含作为组分A的阳离子聚合物，其为N ，甲基丙烯酸N-二乙基氨基乙酯和其它单体。

公开(公告)号：US20110117142A1

公开(公告)日：2011-05-19

申请号：US13002179

申请日：2009-07-01

申请人： Karl Kolter ,  Nils Rottmann ,  Maximilian Angel

发明人： Karl Kolter ,  Nils Rottmann ,  Maximilian Angel

IPC分类号： A61K9/00 ,  A61K47/32 ,  A61K8/02 ,  C09D139/06 ,  A01C1/06 ,  B05D3/02 ,  A23P1/08 ,  A23P1/00 ,  A23L1/00 ,  A23L1/29

CPC分类号： A61K9/284 ,  A61K9/2853

摘要： The present invention relates to a polymeric composition for coating solid substrates (S) consisting of: a) 0.5-90% by weight of polyethylene glycol with a weight-average molecular weight in the range from 1500 to 20 000 g/mol (component A), b) 0.5-20% by weight of a water-soluble polyvinylpyrrolidone with a Fikentscher K value in the range from 12 to 90 (component B), c) 0-95% by weight of a solvent (L), and d) 0-70% by weight of one or more non-polymeric aids (component C).

摘要翻译： 本发明涉及一种用于涂布固体基质（S）的聚合物组合物，其由以下组成：a）0.5-90重量％的重均分子量为1500至200000g / mol的聚乙二醇（组分A ），b）0.5-20重量％的Fikentscher K值在12至90（组分B）范围内的水溶性聚乙烯吡咯烷酮，c）0-95重量％的溶剂（L），d ）0-70重量％的一种或多种非聚合助剂（组分C）。

公开(公告)号：US20110033532A1

公开(公告)日：2011-02-10

申请号：US12671529

申请日：2008-08-01

申请人： Maximilian Angel ,  Karl Kolter ,  Hartwig Voss

发明人： Maximilian Angel ,  Karl Kolter ,  Hartwig Voss

IPC分类号： A61K9/32 ,  C08F2/08 ,  C08K5/06 ,  C08L33/10 ,  C08L39/00 ,  A23L1/29

CPC分类号： C08K3/20 ,  A23L33/10 ,  A23V2002/00 ,  A61K9/1635 ,  A61K9/2018 ,  A61K9/2027 ,  A61K9/2054 ,  A61K9/2846 ,  A61K9/2853 ,  A61K9/5026 ,  A61K47/32 ,  C08F2/22 ,  C08F220/14 ,  C08F220/34 ,  C09D133/14 ,  C09J133/14

摘要： The present invention relates to a process for preparing an aqueous polymer dispersion by free-radical emulsion polymerization of a monomer mixture which comprises N,N-diethylaminoethyl methacrylate, to the polymer dispersion obtainable by this process, and to the use thereof.

摘要翻译： 本发明涉及一种通过使含有甲基丙烯酸N，N-二乙基氨基乙酯的单体混合物通过该方法获得的聚合物分散体的自由基乳液聚合制备聚合物水分散体的方法及其用途。

公开(公告)号：US20100010236A1

公开(公告)日：2010-01-14

申请号：US12525826

申请日：2008-02-11

申请人： Hermann Bergmann ,  Frank Hoefer ,  Maximilian Angel

发明人： Hermann Bergmann ,  Frank Hoefer ,  Maximilian Angel

IPC分类号： C07D201/08

CPC分类号： C07D207/12

摘要： A process for preparing (meth)acrylic esters (F) of N-hydroxyalkylated lactams, in which cyclic N-hydroxyalkylated lactams (L) in whichR1 is C1-C5-alkylene, or C2-C20-alkylene interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or unsubstituted imino groups and/or by one or more cycloalkyl, —(CO)—, —O(CO)O—, —(NH)(CO)O—, —O(CO)(NH)—, —O(CO)— or —(CO)O— groups, where the radicals mentioned may each be substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles,with the proviso that R1 must not have any atom other than a carbon atom directly adjacent to the lactam carbonyl group,R2 is C1-C20-alkylene, C5-C12-cycloalkylene, C6-C12-arylene, or C2-C20-alkylene interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or unsubstituted imino groups and/or by one or more cycloalkyl, —(CO)—, —O(CO)O—, —(NH)(CO)O—, —O(CO)(NH)—, —O(CO)— or —(CO)O— groups, where the radicals mentioned may each be substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles, orR2—OH is a group of the formula —[Xi]k—H,k is from 1 to 50 andXi, for each i=1 to k, may each independently be selected from the group of —CH2—CH2—O—, —CH2—CH2—N(H)—, —CH2—CH2—CH2—N(H)—, —CH2—CH(NH2)—, —CH2—CH(NHCHO)—, —CH2—CH(CH3)—O—, —CH(CH3)—CH2—O—, —CH2—C(CH3)2—O—, —C(CH3)2—CH2—O—, —CH2—CH2—CH2—O—, —CH2—CH2—CH2—CH2—O—, —CH2—CHVin—O—, —CHVin—CH2—O—, —CH2—CHPh—O— and —CHPh—CH2—O—, in which Ph is phenyl and Vin is vinyl,in the presence of at least one metal salt of C1-C10-alkoxides (A), is esterified with (meth)acrylic acid (S) or transesterified with at least one (meth)acrylic ester (D), in which the metal salt of C1-C10-alkoxides (A) used as a catalyst is added in the absence of solvents and completely at the start of the reaction.

公开(公告)号：US07049360B2

公开(公告)日：2006-05-23

申请号：US09964796

申请日：2001-09-28

申请人： Maximilian Angel ,  Axel Sanner ,  Karl Kolter

发明人： Maximilian Angel ,  Axel Sanner ,  Karl Kolter

IPC分类号： C08K3/20

CPC分类号： A61K9/2846 ,  A61K9/2027 ,  C08F261/04

摘要： The present invention relates to water-soluble or water-dispersible copolymers obtainable by free-radical polymerization of a) 80 to 20% by weight of hydroxy-C1–C6-alkyl (meth)acrylate and, where appropriate, one or more compounds of the formula (A) or (B) with R1=H, C1–C6-alkyl, R2=H, CH3 R3=C1–C24-alkyl or mixtures thereof in the presence of b) 20 to 80% by weight of polyvinyl alcohol (PVA) and c) where appropriate 0 to 20% by weight of other polymerizable compounds (C), a process for their preparation, and their use as coating agent, binder and/or film-forming excipient in pharmaceutical dosage forms.

摘要翻译： 本发明涉及通过自由基聚合得到的水溶性或水分散性共聚物，该共聚物是a）80-20％（重量）的羟基-C 1 -C 6 - - （甲基）丙烯酸烷基酯和（如果合适的话）一种或多种式（A）或（B）的化合物，其中R 1 = H，C 1 -C C 1 -C 6烷基，R 2 = H，CH 3 3 R 3 = C 1〜 -C 24 - - - 烷基或其混合物，b）20-80％（重量）的聚乙烯醇（PVA）和c）适当时0-20％重量的其它可聚合化合物（C ），其制备方法，以及它们作为药物剂型中的包衣剂，粘合剂和/或成膜赋形剂的用途。

公开(公告)号：US20050107498A1

公开(公告)日：2005-05-19

申请号：US10501773

申请日：2003-02-04

申请人： Karl Kolter ,  Maximilian Angel

发明人： Karl Kolter ,  Maximilian Angel

IPC分类号： A61K9/28 ,  C08K5/15 ,  C08K3/00 ,  C08K3/34

CPC分类号： A61K9/2853

摘要： A quick dissolving film coating composition for coating solid substrates is composed of a) 10-90% by weight of a polyvinyl alcohol-polyether graft copolymer (component A), b) 5-80% by weight of at least one further component containing at least one functional group selected from the group consisting of hydroxyl, amide and ester functions (component B), and c) 0-70% by weight of further customary coating constituents (components C).

摘要翻译： 用于涂布固体基材的快速溶解膜涂料组合物由a）10-90重量％的聚乙烯醇 - 聚醚接枝共聚物（组分A）组成，b）5-80重量％的至少一种另外的组分，其含有 至少一个选自羟基，酰胺和酯官能团的官能团（组分B），和c）0-70重量％的进一步常规涂料组分（组分C）。

公开(公告)号：US20050084469A1

公开(公告)日：2005-04-21

申请号：US10506871

申请日：2003-03-13

申请人： Claudia Wood ,  Maximilian Angel ,  Lysander Chrisstoffels

发明人： Claudia Wood ,  Maximilian Angel ,  Lysander Chrisstoffels

IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/46 ,  A61K8/72 ,  A61K8/86 ,  A61K8/91 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  C08F2/44 ,  A61K7/06 ,  A61K7/11

CPC分类号： A61Q5/06 ,  A61K8/91 ,  A61K2800/5426 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/12

摘要： The present invention relates to cationic polymers, to processes for the preparation thereof, and to the use thereof in cosmetic formulations.

摘要翻译： 本发明涉及阳离子聚合物，其制备方法及其在化妆品制剂中的用途。

公开(公告)号：US06552142B1

公开(公告)日：2003-04-22

申请号：US09505708

申请日：2000-02-17

申请人： Helmut Meffert ,  Maximilian Angel

发明人： Helmut Meffert ,  Maximilian Angel

IPC分类号： C08F2608

CPC分类号： C08F226/02 ,  C08F226/06

摘要： A description is given of a process for preparing aqueous copolymer dispersions by free-radical polymerization of ethylenically unsaturated monomers in an aqueous solution in which (a) from 10 to 90% by weight of at least one hydrophilic monomer A which has an N-vinyl group and whose polymerisation rate possesses a maximum at pH levels above 7, and (b) from 10 to 90% by weight of at least-one monoethylenically unsaturated hydrophobic monomer B whose polymerisation rate possesses a maximum at pH levels below 7, are copolymerised in the presence of a free-radical initiator system such that in the course of the polymerization the pH falls by from 2 to 5 units. The copolymer dispersions prepared in this way and the copolymers obtainable therefrom are suitable as auxiliaries for pharmaceutical, cosmetic or agrochemical formulations and for preparing paints, coating compositions, sizes, and adhesives.

摘要翻译： 描述了通过烯键式不饱和单体在水溶液中的自由基聚合制备含水共聚物分散体的方法，其中（a）10至90重量％的至少一种亲水单体A，其具有N-乙烯基 并且其聚合速率在pH值高于7时具有最大值，和（b）10至90重量％的聚合速率在pH值低于7时具有最大值的至少一种单烯属不饱和单体B，其共聚合 自由基引发剂体系的存在使得在聚合过程中pH下降2至5单位。以这种方式制备的共聚物分散体和可从其获得的共聚物适合作为药物，化妆品或农药制剂的助剂 并用于制备涂料，涂料组合物，尺寸和粘合剂。