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    Terminal unsaturated, glycidol-based macromonomers, polymers obtainable therefrom, preparation and use
    1.
    发明授权
    Terminal unsaturated, glycidol-based macromonomers, polymers obtainable therefrom, preparation and use 有权
    末端不饱和，缩水甘油基大分子单体，可从其获得的聚合物，制备和用途

    公开(公告)号：US08987410B2

    公开(公告)日：2015-03-24

    申请号：US13379303

    申请日：2010-06-04

    申请人： Wojciech Jaunky ,  Albert Frank ,  Alfred Bubat ,  Jürgen Omeis

    发明人： Wojciech Jaunky ,  Albert Frank ,  Alfred Bubat ,  Jürgen Omeis

    IPC分类号： C07C231/12 ,  C07C41/03 ,  C07C233/20 ,  C07C43/178 ,  C08G65/26 ,  C08G65/00 ,  C08G65/22

    CPC分类号： C08G65/2609 ,  C08G65/00 ,  C08G65/22 ,  C08G65/2612

    摘要： Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.

    摘要翻译： 制备大分子单体的方法，其中起始化合物H2C = CR1-C6H4-s（R4）s-R3-OH或H2C = CR2-CO-NH-R3-OH，其中R1和R2各自为H或直链或 具有1至4个碳原子的支链烷基，R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基，亚芳基，并且基团R 4各自彼此独立地为 具有1至20个碳原子且s = 0-4的直链或支链烷基，芳烷基，烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n（起始化合物）:n（环氧乙烷化合物）的摩尔量的摩尔比为1：100〜1：1的环氧乙烷环的开环自由基聚合。 可以通过该方法获得的大分子单体，可从其获得的聚合物及其作为涂料组合物，塑料和化妆品中的添加剂的用途。

    TERMINAL UNSATURATED, GLYCIDOL-BASED MACROMONOMERS, POLYMERS OBTAINABLE THEREFROM, PREPARATION AND USE
    2.
    发明申请
    TERMINAL UNSATURATED, GLYCIDOL-BASED MACROMONOMERS, POLYMERS OBTAINABLE THEREFROM, PREPARATION AND USE 有权
    端基不饱和，基于甘氨酸的麦芽糖，可获得的聚合物，制备和使用

    公开(公告)号：US20120165414A1

    公开(公告)日：2012-06-28

    申请号：US13379303

    申请日：2010-06-04

    申请人： Wojciech Jaunky ,  Albert Frank ,  Alfred Bubat ,  Jürgen Omeis

    发明人： Wojciech Jaunky ,  Albert Frank ,  Alfred Bubat ,  Jürgen Omeis

    IPC分类号： A61K8/81 ,  C07C231/12 ,  C07C43/178 ,  C09D125/08 ,  C08F220/58 ,  C08F216/14 ,  C09D133/26 ,  C07C41/03 ,  C07C233/20

    CPC分类号： C08G65/2609 ,  C08G65/00 ,  C08G65/22 ,  C08G65/2612

    摘要： Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.

    摘要翻译： 制备大分子单体的方法，其中起始化合物H2C = CR1-C6H4-s（R4）s-R3-OH或H2C = CR2-CO-NH-R3-OH，其中R1和R2各自为H或直链或 具有1至4个碳原子的支链烷基，R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基，亚芳基，并且基团R 4各自彼此独立地为 具有1至20个碳原子且s = 0-4的直链或支链烷基，芳烷基，烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n（起始化合物）:n（环氧乙烷化合物）的摩尔量的摩尔比为1：100〜1：1的环氧乙烷环的开环自由基聚合。 可以通过该方法获得的大分子单体，可从其获得的聚合物及其作为涂料组合物，塑料和化妆品中的添加剂的用途。

    Use of polyacrylate-modified polysiloxanes as levelling agents in coating compositions
    7.
    发明授权
    Use of polyacrylate-modified polysiloxanes as levelling agents in coating compositions 有权
    在涂料组合物中使用聚丙烯酸酯改性的聚硅氧烷作为流平剂

    公开(公告)号：US07230051B2

    公开(公告)日：2007-06-12

    申请号：US10465536

    申请日：2003-06-19

    申请人： Bernd Gobelt ,  Alfred Bubat ,  Albert Frank ,  Karlheinz Haubennestel

    发明人： Bernd Gobelt ,  Alfred Bubat ,  Albert Frank ,  Karlheinz Haubennestel

    IPC分类号： C08L83/02

    CPC分类号： C08G77/442 ,  C08F293/005 ,  C09D7/47 ,  Y10S525/934

    摘要： The invention relates to the use of block copolymers as leveling agents for surface coatings, having a weight-average molecular weight of from 1000 to 100000. The leveling agent is a linear or branched block copolymer composed of a polysiloxane block and one or more blocks prepared from ethylenically unsaturated monomers by controlled free-radical addition polymerization.The invention also relates to coating compositions which comprise the leveling agent.

    摘要翻译： 本发明涉及嵌段共聚物作为表面涂料的流平剂的用途，其重均分子量为1000-100000。流平剂是由聚硅氧烷嵌段和一个或多个嵌段制备的直链或支链嵌段共聚物 通过控制的自由基加成聚合从烯属不饱和单体中获得。 本发明还涉及包含流平剂的涂料组合物。

    Coating compositions and polymeric moulding compounds having anti-adhesion and dirt repellency properties
    8.
    发明授权
    Coating compositions and polymeric moulding compounds having anti-adhesion and dirt repellency properties 有权
    涂料组合物和具有防粘附性和防污性的聚合物模塑料

    公开(公告)号：US07122599B2

    公开(公告)日：2006-10-17

    申请号：US09967504

    申请日：2001-09-28

    申请人： Karlheinz Haubennestel ,  Alfred Bubat ,  Albert Frank ,  Axel Woocker ,  Udo Krappe

    发明人： Karlheinz Haubennestel ,  Alfred Bubat ,  Albert Frank ,  Axel Woocker ,  Udo Krappe

    IPC分类号： C08L43/04

    CPC分类号： C08G77/42 ,  C08G77/442 ,  C08G77/445 ,  C08G77/458

    摘要： The invention relates to coating compositions having anti-adhesion and dirt repellency properties, these compositions being admixed as additive with from 0.1 to 10% by weight, based on the solids content of the coating composition, of a branched polymer which possesses a weight-average molecular weight of from 2000 to 200,000 and comprises a polymeric base molecule and also polydiorganosiloxane side chains which are bonded covalently to the base molecule via Si—C bonds, have a weight-average molecular weight of between 1000 and 30,000, and whose fraction of the total weight of the branched polymer is from 5 to 25% by weight. The present invention further relates to polymeric moulding compounds having anti-adhesion and dirt repellency properties, to which this branched polymer is added as additive in an amount of from 0.1 to 10% by weight, based on the total weight of the polymeric moulding compounds. The invention additionally relates to the use of the branched polymers as additives for coating compositions and polymeric moulding compounds.

    摘要翻译： 本发明涉及具有防粘附性和防污性的涂料组合物，这些组合物以占涂料组合物的固体含量为基准的0.1至10重量％的混合添加剂，其具有重均分子量 分子量为2000至200,000，并且包含通过Si-C键与基础分子共价键合的聚合物基础分子和聚二有机硅氧烷侧链，其重均分子量为1000至30,000，并且其分子量为 支链聚合物的总重量为5〜25重量％。 本发明还涉及具有抗粘附性和防污性的聚合物模塑料，该支化聚合物以其占聚合物模塑料总重量的0.1至10重量％的量加入其中。 本发明还涉及使用支化聚合物作为涂料组合物和聚合物模塑料的添加剂。

    Levelling agents for surface coatings
    9.
    发明授权
    Levelling agents for surface coatings 失效
    流平剂表面涂层

    公开(公告)号：US06710127B2

    公开(公告)日：2004-03-23

    申请号：US09967499

    申请日：2001-09-28

    申请人： Karlheinz Haubennestel ,  Alfred Bubat ,  Albert Frank

    发明人： Karlheinz Haubennestel ,  Alfred Bubat ,  Albert Frank

    IPC分类号： C08L7900

    CPC分类号： C08F290/04 ,  C08F283/12 ,  C08F290/06 ,  C08F290/061 ,  C08F290/068 ,  C09D7/47

    摘要： The invention relates to levelling agents for surface coatings having a weight-average molecular weight of from 5000 to 100,000. The levelling agent is a branched polymer comprising a free-radically or ionically polymerized base molecule into which macromonomeric units containing at one end a monomeric unit which has an ethylenically unsaturated bond and possessing a weight-average molecular weight of from 1000 to 30,000 have been incorporated by free-radical or ionic copolymerization, the weight fraction of the macromonomeric units, based on the total weight of the branched polymer, being from 1 to 60% by weight. The invention further relates to the use of appropriate polymers as levelling agents for coating formulations and to coating formulations comprising the levelling agents of the invention.

    摘要翻译： 本发明涉及重均分子量为5000至100,000的表面涂层流平剂。 流平剂是包含自由基或离子聚合的碱分子的支链聚合物，其中含有一端具有烯键式不饱和键并具有1000至30,000重均分子量的单体单元的大分子单体已经被引入 通过自由基或离子共聚，基于支化聚合物的总重量，大分子单元的重量分数为1至60重量％。 本发明还涉及合适的聚合物作为流平剂用于涂布制剂和包含本发明的流平剂的包衣制剂的用途。

    METHOD FOR CONTINUOUS HYDROSILYLATION
    10.
    发明申请
    METHOD FOR CONTINUOUS HYDROSILYLATION 有权
    连续氢化法的方法

    公开(公告)号：US20130060058A1

    公开(公告)日：2013-03-07

    申请号：US13579648

    申请日：2011-02-18

    申请人： Jörg Issberner ,  Frank Tlauka ,  Tom Beckmann ,  Alfred Bubat

    发明人： Jörg Issberner ,  Frank Tlauka ,  Tom Beckmann ,  Alfred Bubat

    IPC分类号： C07F7/18

    CPC分类号： C08G77/46 ,  C08G77/38

    摘要： The invention relates to a method for continuously producing silanes and/or organopolysiloxanes by hydrosilylation, in which at least one compound (A) containing at least one carbon-carbon multiple bond is reacted with at least one compound (B) comprising at least one Si—H functionality, wherein the reaction is carried out in a reaction mixing pump.

    摘要翻译： 本发明涉及通过氢化硅烷化连续生产硅烷和/或有机聚硅氧烷的方法，其中至少一种含有至少一个碳 - 碳多键的化合物（A）与至少一种包含至少一种Si -H官能团，其中反应在反应混合泵中进行。