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公开(公告)号：US20090176903A1
公开(公告)日：2009-07-09
申请号：US12329725
申请日：2008-12-08
申请人： Xaver Muenz , Bernd Mayer , Christian Scheffner , Rajat K. Agarwal , Michael S. Puckett , Gregory A. Ferguson , Olaf Lammerschop
发明人： Xaver Muenz , Bernd Mayer , Christian Scheffner , Rajat K. Agarwal , Michael S. Puckett , Gregory A. Ferguson , Olaf Lammerschop
CPC分类号： C08J9/16 , C08J9/0061 , C08J2201/03 , C08J2363/00 , C08J2467/00 , C08L63/00 , C08L67/00 , C08L2666/14
摘要： Expandable, thermally curable compositions containing at least one epoxy resin, at least one polyester, at least one blowing agent, and at least one curing agent are useful as adhesives and structural reinforcement materials. When foamed and adhered to a metal substrate surface, such polyester-modified foamable compositions can exhibit improved adhesion to the substrate surface after exposure to a corrosive environment, as compared to compositions that do not contain polyester. Furthermore, these compositions can exhibit improved flow properties in the uncured state at temperatures between 50 and 100° C. They are granulatable, with the granules produced thereby having non-tacky surfaces at room temperature and being capable of being readily processed into molded objects by injection molding processes.
摘要翻译： 包含至少一种环氧树脂，至少一种聚酯，至少一种发泡剂和至少一种固化剂的可膨胀的可热固化组合物可用作粘合剂和结构增强材料。 当发泡并粘附到金属基材表面时，与不含聚酯的组合物相比，这种聚酯改性的可发泡组合物可以在暴露于腐蚀性环境之后表现出改进的对基材表面的粘合性。 此外，这些组合物可以在50至100℃的温度下在未固化状态下表现出改进的流动性。它们是可成粒的，由此产生的颗粒在室温下具有非粘性表面，并且能够容易地通过 注塑工艺。
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公开(公告)号：US08288447B2
公开(公告)日：2012-10-16
申请号：US12329725
申请日：2008-12-08
申请人： Xaver Muenz , Bernd Mayer , Christian Scheffner , Rajat K. Agarwal , Michael S. Puckett , Gregory A. Ferguson , Olaf Lammerschop
发明人： Xaver Muenz , Bernd Mayer , Christian Scheffner , Rajat K. Agarwal , Michael S. Puckett , Gregory A. Ferguson , Olaf Lammerschop
CPC分类号： C08J9/16 , C08J9/0061 , C08J2201/03 , C08J2363/00 , C08J2467/00 , C08L63/00 , C08L67/00 , C08L2666/14
摘要： Expandable, thermally curable compositions containing at least one epoxy resin, at least one polyester, at least one blowing agent, and at least one curing agent are useful as adhesives and structural reinforcement materials. When foamed and adhered to a metal substrate surface, such polyester-modified foamable compositions can exhibit improved adhesion to the substrate surface after exposure to a corrosive environment, as compared to compositions that do not contain polyester. Furthermore, these compositions can exhibit improved flow properties in the uncured state at temperatures between 50 and 100° C. They are granulatable, with the granules produced thereby having non-tacky surfaces at room temperature and being capable of being readily processed into molded objects by injection molding processes.
摘要翻译： 包含至少一种环氧树脂，至少一种聚酯，至少一种发泡剂和至少一种固化剂的可膨胀的可热固化组合物可用作粘合剂和结构增强材料。 当发泡并粘附到金属基材表面时，与不含聚酯的组合物相比，这种聚酯改性的可发泡组合物可以在暴露于腐蚀性环境之后表现出改进的对基材表面的粘合性。 此外，这些组合物可以在50至100℃的温度下在未固化状态下表现出改进的流动性。它们是可成粒的，由此产生的颗粒在室温下具有非粘性表面，并且能够容易地通过 注塑工艺。
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3.发明授权公开(公告)号：US07473717B2
公开(公告)日：2009-01-06
申请号：US10867427
申请日：2004-06-14
CPC分类号： C08J9/0061 , C08G59/40 , C08J9/102 , C08J9/32 , C08J2363/00 , C08L63/00 , Y10T428/249953 , C08L2666/02 , C08L2666/04
摘要： Expandable thermosettable compositions containing at least one epoxy resin, at least one finely divided thermoplastic polymer powder, at least one blowing agent, at least one curing agent, and at least one filler are suitable for the production of thermosetting laminated bodies with a tacky surface. These laminated bodies can be produced and handled in a simple manner and are suitable for stiffening and reinforcing flat structural components, in particular vehicle body structural components, such as vehicle body frames, doors, trunk lids, engine hoods and/or roof components in automobile construction. The expandable thermosettable compositions are also suitable for the production of thermosetting, thermally expandable shaped articles for reinforcing hollow structural members by the injection molding process. In preferred embodiments, the composition is injected onto a metallic or thermoplastic carrier. These thermally expandable shaped articles are especially useful in the production of automobiles and other vehicles to maintain or increase the strength of structural members such as rockers, pillars, radiator support beams, doors, reinforcing beams, and the like.
摘要翻译： 含有至少一种环氧树脂，至少一种细分散的热塑性聚合物粉末，至少一种发泡剂，至少一种固化剂和至少一种填料的可膨胀热固性组合物适用于生产具有粘性表面的热固性层压体。 这些层压体可以以简单的方式制造和处理，并且适用于加强和加强平面结构部件，特别是汽车车身结构部件，例如车身框架，门，行李箱盖，汽车中的发动机罩和/或屋顶部件 施工。 可膨胀的热固性组合物也适用于通过注射成型工艺生产用于加强中空结构构件的热固性热膨胀成形制品。 在优选的实施方案中，将组合物注射到金属或热塑性载体上。 这些热膨胀成形制品在汽车和其他车辆的生产中特别有用，以保持或增加诸如摇杆，支柱，散热器支撑梁，门，加强梁等的结构构件的强度。
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公开(公告)号：US20100130655A1
公开(公告)日：2010-05-27
申请号：US12692765
申请日：2010-01-25
CPC分类号： C08L21/00 , C08G59/182 , C08K3/346 , C08L9/00 , C08L75/04 , C08L2666/04 , C09J163/00 , C08L2666/02
摘要： This invention relates to compositions useful as adhesives and more particularly to epoxy-based adhesive compositions with improved impact resistance.
摘要翻译： 本发明涉及可用作粘合剂的组合物，更具体地说涉及具有改善耐冲击性的环氧基粘合剂组合物。
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公开(公告)号：US08545667B2
公开(公告)日：2013-10-01
申请号：US12793786
申请日：2010-06-04
IPC分类号： C09J163/02 , C09J119/00 , C08K3/34 , C08G59/24
CPC分类号： C09J11/08 , C08F220/00 , C08K3/346 , C08L63/00 , C08L2666/02 , C08L2666/28 , C09J163/00
摘要： This invention relates to compositions useful as adhesives and more particularly to the preparation of heat-curable epoxy-based adhesive compositions that are capable of being easily pumped under high shear at temperatures around room temperature but are resistant to being washed off substrate surfaces prior to being cured.
摘要翻译： 本发明涉及可用作粘合剂的组合物，更具体地说，涉及可热固化的环氧基粘合剂组合物的制备，该组合物能够在室温附近的温度下容易地在高剪切力下泵送，但耐受在基材表面之前被洗掉 治愈
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公开(公告)号：US20100176650A1
公开(公告)日：2010-07-15
申请号：US12635507
申请日：2009-12-10
申请人： Timothy J. Zens , Rajat K. Agarwal , James E. Thompson , Gregory A. Ferguson , Scott J. Beleck , David Inkpen
发明人： Timothy J. Zens , Rajat K. Agarwal , James E. Thompson , Gregory A. Ferguson , Scott J. Beleck , David Inkpen
CPC分类号： B60B7/06 , Y10T156/10
摘要： A decorative overlay comprised of thin plastic or metal may be securely fastened to a wheel using one or more preformed, solid, dimensionally stable, heat-activatable adhesive bodies. The use of such adhesive bodies offers significant processing and performance advantages over conventional methods for cladding wheels.
摘要翻译： 由薄塑料或金属组成的装饰性覆盖物可以使用一个或多个预制的，固体的，尺寸稳定的，可热激活的粘合体牢固地固定到轮上。 与传统的包覆方法相比，这种粘合体的使用提供了显着的加工和性能优点。
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公开(公告)号：US07119149B2
公开(公告)日：2006-10-10
申请号：US10336594
申请日：2003-01-03
IPC分类号： C08F8/00
CPC分类号： C08J9/32 , C08J2207/02 , C08J2363/00 , Y10T428/249986 , Y10T428/31511 , Y10T428/31725
摘要： The present invention is directed to a high expansion two-component structural foam that expands to about twice its original volume while maintaining good cell structure. The foam of the present invention is based on epoxy resins. Each component of the foam system exhibits storage stability, e.g., no phase separation, yet reacts when combined to provide a cured material having exceptionally good compression strength and modulus. The blowing system used to prepare the foam produces a foam which is uniform in appearance and is essentially free of the large voids often found in conventional two-part thermosettable compositions, even when a relatively large mass is utilized.
摘要翻译： 本发明涉及一种高膨胀双组分结构泡沫，其膨胀至其原始体积的大约两倍，同时保持良好的泡孔结构。 本发明的泡沫是基于环氧树脂。 泡沫体系的每个组分表现出储存稳定性，例如没有相分离，但当组合时反应以提供具有非常好的压缩强度和模量的固化材料。 用于制备泡沫的吹塑系统产生外观均匀的泡沫，并且基本上没有常规的两部分可热固组合物中常见的大空隙，即使当使用相对较大的质量时。
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公开(公告)号：US06833398B2
公开(公告)日：2004-12-21
申请号：US10279160
申请日：2002-10-24
申请人： Rajat K. Agarwal , Brian D. Bammel , William E. Fristad , Gregg W. Rossier , Elizabeth J. Siebert , Zhiqi Yang
发明人： Rajat K. Agarwal , Brian D. Bammel , William E. Fristad , Gregg W. Rossier , Elizabeth J. Siebert , Zhiqi Yang
IPC分类号： B32B1508
CPC分类号： C09D163/00 , C08G59/182 , C08G59/4021 , Y10T428/31522 , Y10T428/31529 , C08L2666/04
摘要： Autodeposited coatings useful for protecting metal surfaces and in production of rubber-to-metal composites are obtained by curing adducts based on epoxy resins which are adhered to the metal surface. One or more epoxy resins, such as for example, the combination of a diglycidyl ether of bisphenol A and a flexibilizing epoxy resin, may be prereacted to form an adduct of higher average molecular weight than the starting epoxy resins. Said adduct may then be dispersed in water, with the resulting dispersion being used in an autodeposition bath composition.
摘要翻译： 用于保护金属表面和生产橡胶 - 金属复合材料的自动沉积涂层是通过固化基于粘合到金属表面上的环氧树脂的加合物获得的。 可以预先反应一种或多种环氧树脂，例如双酚A的二缩水甘油醚和柔性环氧树脂的组合，以形成比起始环氧树脂更高的平均分子量的加合物。 然后可将所述加合物分散在水中，所得分散体用于自沉积浴组合物中。
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公开(公告)号：US09133375B2
公开(公告)日：2015-09-15
申请号：US12770342
申请日：2010-04-29
CPC分类号： C09J163/00 , C08K5/0008 , C08L33/20 , C08L2666/04 , C08L2666/54
摘要： This invention relates to compositions useful as adhesives and more particularly to the preparation of heat-curable epoxy-based adhesive compositions that are resistant to being washed off substrate surfaces prior to being cured. The incorporation of a solid diene-based rubber, in particular an acrylonitrile-butadiene copolymer rubber having a relatively high Mooney viscosity, significantly enhances the wash-off resistance of the adhesive, while still allowing the adhesive to be readily dispensed by pumping under high shear conditions.
摘要翻译： 本发明涉及可用作粘合剂的组合物，更具体地说，涉及可固化的环氧基粘合剂组合物的制备，其在固化之前被耐基材表面洗掉。 固体二烯类橡胶，特别是具有较高门尼粘度的丙烯腈 - 丁二烯共聚物橡胶的引入显着增强了粘合剂的耐洗涤性，同时仍然允许粘合剂通过在高剪切下泵送而容易地分配 条件。
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公开(公告)号：US06613387B2
公开(公告)日：2003-09-02
申请号：US09990066
申请日：2001-11-21
IPC分类号： B05D310
CPC分类号： B05D7/144
摘要： The anticorrosive properties of a coating autodeposited on a metal substrate are improved by contacting the autodeposited coating with an aqueous solution containing Group IIA or Group IIB metal cations (e.g., calcium or zinc cations) and phosphate anions prior to curing. The rinse solution is preferably acidic and can be prepared, for example, from calcium nitrate and an oxy acid of phosphorus or zinc dihydrogen phosphate. Optionally, the rinse solution also includes an accelerator such as hydroxylamine.
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