摘要:
The anticorrosive properties of a coating autodeposited on a metal substrate are improved by contacting the autodeposited coating with an aqueous solution containing Group IIA or Group IIB metal cations (e.g., calcium or zinc cations) and phosphate anions prior to curing. The rinse solution is preferably acidic and can be prepared, for example, from calcium nitrate and an oxy acid of phosphorus or zinc dihydrogen phosphate. Optionally, the rinse solution also includes an accelerator such as hydroxylamine.
摘要:
Autodeposited coatings useful for protecting metal surfaces and in production of rubber-to-metal composites are obtained by curing adducts based on epoxy resins which are adhered to the metal surface. One or more epoxy resins, such as for example, the combination of a diglycidyl ether of bisphenol A and a flexibilizing epoxy resin, may be prereacted to form an adduct of higher average molecular weight than the starting epoxy resins. Said adduct may then be dispersed in water, with the resulting dispersion being used in an autodeposition bath composition.
摘要:
A film of a polymer or polymer precursor such as an epoxy resin is autodeposited on an active metal surface and then used to form an adhesive bond directly between the metal surface and the surface of a rubber substrate. Excellent adhesion of the metal to the rubber is obtained without the need to either phosphate the metal surface or use a primer or adhesive other than the autodeposited coating.
摘要:
Autodeposition compositions for polymeric coatings of reduced gloss, good corrosion resistance, and uniform appearance are prepared using a combination of acrylic and epoxy resins.
摘要:
This invention relates to compositions useful as adhesives and more particularly to the preparation of heat-curable epoxy-based adhesive compositions that are resistant to being washed off substrate surfaces prior to being cured. The incorporation of a solid diene-based rubber, in particular an acrylonitrile-butadiene copolymer rubber having a relatively high Mooney viscosity, significantly enhances the wash-off resistance of the adhesive, while still allowing the adhesive to be readily dispensed by pumping under high shear conditions.
摘要:
A decorative overlay comprised of thin plastic or metal may be securely fastened to a wheel using one or more preformed, solid, dimensionally stable, heat-activatable adhesive bodies. The use of such adhesive bodies offers significant processing and performance advantages over conventional methods for cladding wheels.
摘要:
Expandable, thermally curable compositions containing at least one epoxy resin, at least one polyester, at least one blowing agent, and at least one curing agent are useful as adhesives and structural reinforcement materials. When foamed and adhered to a metal substrate surface, such polyester-modified foamable compositions can exhibit improved adhesion to the substrate surface after exposure to a corrosive environment, as compared to compositions that do not contain polyester. Furthermore, these compositions can exhibit improved flow properties in the uncured state at temperatures between 50 and 100° C. They are granulatable, with the granules produced thereby having non-tacky surfaces at room temperature and being capable of being readily processed into molded objects by injection molding processes.
摘要:
An autodepositing liquid composition comprises dispersed non-film-forming polymer particles in addition to the dispersed film forming polymer characteristic of all autodepositing liquid compositions. Preferably, the non-film-forming polymer particles are gas-tight microballoons filled with a gas such as air and have an average particle size less than 1 &mgr;m. Such particles act in the autodepositing liquid compositions and in the dried coatings formed from them as opaque white pigments, unless the coatings are heated above about 130° C., if so heated, the coatings, unless they contain other heat stable pigment, become irreversibly transparent.
摘要:
Expandable, thermally curable compositions containing at least one epoxy resin, at least one polyester, at least one blowing agent, and at least one curing agent are useful as adhesives and structural reinforcement materials. When foamed and adhered to a metal substrate surface, such polyester-modified foamable compositions can exhibit improved adhesion to the substrate surface after exposure to a corrosive environment, as compared to compositions that do not contain polyester. Furthermore, these compositions can exhibit improved flow properties in the uncured state at temperatures between 50 and 100° C. They are granulatable, with the granules produced thereby having non-tacky surfaces at room temperature and being capable of being readily processed into molded objects by injection molding processes.
摘要:
This invention relates to compositions useful as adhesives and more particularly to epoxy-based adhesive compositions with improved impact resistance.