Reversible Polymer/Metal Nano-Composites And Method For Manufacturing Same
    1.
    发明申请
    Reversible Polymer/Metal Nano-Composites And Method For Manufacturing Same 有权
    可逆聚合物/金属纳米复合材料及其制造方法相同

    公开(公告)号:US20080305336A1

    公开(公告)日:2008-12-11

    申请号:US12047896

    申请日:2008-03-13

    IPC分类号: B32B27/00 C08F8/42

    摘要: The present invention provides a polymer/metal nano-composite. The nano-composite includes at least one copolymer chain having alkenyl monomer units and maleimide monomer units, and a nano-sized metal or inorganic crystal. It also provides a method of producing nano-sized metal/inorganic crystals in pure form. These nano-composites and nano-crystals can be useful as polymer fillers, tire rubber compounds, semiconductors, nano-magnets, catalysts, and quantum dots etc.

    摘要翻译: 本发明提供一种聚合物/金属纳米复合材料。 纳米复合材料包括至少一种具有烯基单体单元和马来酰亚胺单体单元的共聚物链,以及纳米级金属或无机晶体。 还提供了以纯形式制备纳米尺寸金属/无机晶体的方法。 这些纳米复合材料和纳米晶体可用作聚合物填料,轮胎橡胶化合物,半导体,纳米磁体,催化剂和量子点等。

    Disk-like nanoparticles
    4.
    发明授权
    Disk-like nanoparticles 有权
    盘状纳米颗粒

    公开(公告)号:US08288473B2

    公开(公告)日:2012-10-16

    申请号:US12288174

    申请日:2008-10-17

    IPC分类号: B32B27/00 C08L53/02

    摘要: A disk-like nanoparticle includes a core layer that comprises a cross-linked multi-vinyl substituted aromatic hydrocarbon and a shell layer that comprises tri-block copolymer chains, each having a first, a second, and a third block. The first and third blocks of the tri-block copolymer chains comprise vinyl aromatic monomer units and are crosslinked with the core. The second block comprises conjugated diene monomer units and comprises a top and bottom axial surface of the disk-like nanoparticle. In the case of a nanoparticle having A-B-C tri-block copolymer chains, the third block comprises a top and bottom axial surface of the disk-like nanoparticle.

    摘要翻译: 盘状纳米颗粒包括包含交联的多乙烯基取代的芳族烃的核心层和包含三嵌段共聚物链的壳层,每个具有第一,第二和第三嵌段。 三嵌段共聚物链的第一和第三嵌段包含乙烯基芳族单体单元并与核交联。 第二块包括共轭二烯单体单元,并且包括盘状纳米颗粒的顶部和底部轴向表面。 在具有A-B-C三嵌段共聚物链的纳米颗粒的情况下,第三块包括盘状纳米颗粒的顶部和底部轴向表面。

    Reversible polymer/metal nano-composites and method for manufacturing same
    6.
    发明授权
    Reversible polymer/metal nano-composites and method for manufacturing same 有权
    可逆聚合物/金属纳米复合材料及其制造方法

    公开(公告)号:US08349964B2

    公开(公告)日:2013-01-08

    申请号:US12047896

    申请日:2008-03-13

    IPC分类号: C01D7/00

    摘要: The present invention provides a polymer/metal nano-composite. The nano-composite includes at least one copolymer chain having alkenyl monomer units and maleimide monomer units, and a nano-sized metal or inorganic crystal. It also provides a method of producing nano-sized metal/inorganic crystals in pure form. These nano-composites and nano-crystals can be useful as polymer fillers, tire rubber compounds, semiconductors, nano-magnets, catalysts, and quantum dots etc.

    摘要翻译: 本发明提供一种聚合物/金属纳米复合材料。 纳米复合材料包括至少一种具有烯基单体单元和马来酰亚胺单体单元的共聚物链,以及纳米级金属或无机晶体。 还提供了以纯形式制备纳米尺寸金属/无机晶体的方法。 这些纳米复合材料和纳米晶体可用作聚合物填料,轮胎橡胶化合物,半导体,纳米磁体,催化剂和量子点等。

    Nanoparticles with controlled architecture and method thereof
    7.
    发明授权
    Nanoparticles with controlled architecture and method thereof 有权
    具有受控结构的纳米颗粒及其方法

    公开(公告)号:US07538159B2

    公开(公告)日:2009-05-26

    申请号:US11305281

    申请日:2005-12-16

    IPC分类号: C08F279/00

    摘要: The present invention provides polymer nanoparticles with a controlled architecture of nano-necklace, nano-cylinder, nano-ellipsoid, or nano-sphere. The polymer nanoparticle comprises a core polymerized from multiple-vinyl-substituted aromatic hydrocarbons, a shell polymerized from alkyl-substituted styrene, and a polystyrene layer between the core and the shell. The present invention also provides a method of preparing the polymer nanoparticles and a rubber article such as a tire manufactured from a formulation comprising the polymer nanoparticles.

    摘要翻译: 本发明提供具有纳米项链,纳米圆柱体,纳米椭圆体或纳米球体的受控结构的聚合物纳米颗粒。 聚合物纳米颗粒包含由多个乙烯基取代的芳族烃聚合的核心,由烷基取代的苯乙烯聚合的壳和在核心和壳体之间的聚苯乙烯层。 本发明还提供了制备聚合物纳米颗粒的方法和由包含聚合物纳米颗粒的制剂制成的橡胶制品,例如轮胎。

    Method of making nano-particles of selected size distribution
    9.
    发明授权
    Method of making nano-particles of selected size distribution 有权
    制备选择尺寸分布的纳米颗粒的方法

    公开(公告)号:US08063142B2

    公开(公告)日:2011-11-22

    申请号:US10791049

    申请日:2004-03-02

    IPC分类号: C08L53/02

    摘要: A process for forming a nanoparticle composition is provided. The process includes polymerizing conjugated diene monomer in a hydrocarbon solvent to form a first reaction mixture, and charging excess alkenylbenzense monomer and anionic catalyst to form mono-block and diblock polymers. Micelles of said mono-block and diblock polymers are formed, and at least one crosslinking agent is added to cross-link the micelles and form nanoparticles. The nanoparticles preferably have a poly(alkenylbenzene) core and an outer layer including monomer units selected from the group consisting of conjugated dienes, alkenylbenzenes, alkylenes, and mixtures thereof, and a size distribution of between about 1 and 1000 nm.

    摘要翻译: 提供了形成纳米颗粒组合物的方法。 该方法包括在烃溶剂中聚合共轭二烯单体以形成第一反应混合物,并加入过量的链烯基苯基单体和阴离子催化剂以形成单嵌段和二嵌段聚合物。 形成所述单嵌段和二嵌段聚合物的胶束,并加入至少一种交联剂以交联胶束并形成纳米颗粒。 纳米颗粒优选具有聚(烯基苯)核,外层包括选自共轭二烯,烯基苯,亚烷基及其混合物的单体单元,其尺寸分布在约1nm至1000nm之间。

    Nano-composite and method thereof
    10.
    发明授权
    Nano-composite and method thereof 有权
    纳米复合材料及其制备方法

    公开(公告)号:US07601772B2

    公开(公告)日:2009-10-13

    申请号:US11642190

    申请日:2006-12-20

    IPC分类号: C08K9/04

    CPC分类号: C08J5/005 B82Y30/00

    摘要: The present invention provides a nano-composite comprising a clay and a cationic mediator comprised of a hydrophobic unit and a cationic unit. The clay is exfoliated or intercalated by the cationic mediator. The present invention further provides a polymer formulation comprising the nano-composite. The nano-composite is practically useful in formulating compositions such as rubber and tire products with improved and well-balanced properties including gas permeability, cure properties, and/or mechanical properties etc.

    摘要翻译: 本发明提供一种包含粘土和由疏水单元和阳离子单元组成的阳离子介体的纳米复合材料。 粘土被阳离子介质剥离或嵌入。 本发明还提供了包含纳米复合材料的聚合物制剂。 纳米复合材料实际上可用于配制诸如橡胶和轮胎产品的组合物,其具有改进的良好平衡的性能,包括气体渗透性,固化性能和/或机械性能等。