Fluorine-containing polymer composition and cured body
    3.
    发明授权
    Fluorine-containing polymer composition and cured body 有权
    含氟聚合物组合物和固化体

    公开(公告)号:US08242208B2

    公开(公告)日:2012-08-14

    申请号:US12399069

    申请日:2009-03-06

    IPC分类号: C08F8/00

    摘要: The invention provides a fluoropolymer composition capable of improving the characteristics of the cured material obtained therefrom. A fluoropolymer composition comprising a methylene group-containing fluoropolymer (A) and a hydrosilylation catalyst (B), wherein the methylene group-containing fluoropolymer (A) has methylene group-containing repeating units in the main chain thereof and is capable of hydrosilylation in the presence of the hydrosilylation catalyst (B) and one terminus of the chain is a carbon-carbon double bond or an Si—H group and the other terminus of the chain is an Si—H group or a carbon-carbon double bond.

    摘要翻译: 本发明提供能够改善由其获得的固化材料的特性的含氟聚合物组合物。 包含含亚甲基的含氟聚合物(A)和氢化硅烷化催化剂(B)的含氟聚合物组合物,其中所述含亚甲基的含氟聚合物(A)在其主链中具有含亚甲基的重复单元,并且能够在 氢化硅烷化催化剂(B)的存在和链的一个末端是碳 - 碳双键或Si-H基团,链的另一个末端是Si-H基团或碳 - 碳双键。

    Process for preparing vulcanizable fluorine-containing elastomer
    5.
    发明申请
    Process for preparing vulcanizable fluorine-containing elastomer 有权
    制备可硫化含氟弹性体的方法

    公开(公告)号:US20070299207A1

    公开(公告)日:2007-12-27

    申请号:US11892702

    申请日:2007-08-27

    IPC分类号: C08L27/14

    摘要: The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.

    摘要翻译: 本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。 本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。 该方法是在临界常数降低至少为0.95,临界常数降低至少为0.80的条件下进行的间歇共聚方法,其中降低的温度和减压是使用Peng-Robinson公式 在临界温度下,在具有下式的化合物的存在下,在反应容器中的气相中的每种单体的临界压力和组成比共聚,其中含有至少一个氟烯烃的烯键式不饱和化合物在具有下式的化合物的存在下共聚: 其中R 1是饱和或不饱和的氟代烃或其中R 1,R 2,R 3,R 4, 具有1至16个碳原子的氯氟烃基,x是R 1和...的整数1至4的整数。

    Process for preparing vulcanizable fluorine-containing elastomer
    7.
    发明授权
    Process for preparing vulcanizable fluorine-containing elastomer 有权
    制备可硫化含氟弹性体的方法

    公开(公告)号:US08247505B2

    公开(公告)日:2012-08-21

    申请号:US11892702

    申请日:2007-08-27

    IPC分类号: C08F14/18

    摘要: The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1·Ix wherein Rf1 is a saturated or unsaturated fluorohydrocarbon or chlorofluorohydrocarbon group having 1 to 16 carbon atoms, and x is the number of bonds of Rf1 and an integer of 1 to 4.

    摘要翻译: 本发明提供了一种通过在高压下进行碘转移聚合制备与非碘转移聚合方法相当的高生产率的含氟弹性体的方法。 本发明还提供了通过该方法制备的含氟弹性体和含氟成型体。 该方法是在临界常数降低至少为0.95,临界常数降低至少为0.80的条件下进行的间歇共聚方法,其中降低的温度和减压是使用Peng-Robinson公式 在临界温度下,在具有下式的化合物的存在下共聚反应容器中气相中各单体的临界压力和组成比:Rf1· 其中Rf1是具有1至16个碳原子的饱和或不饱和的氟代烃或氯氟烃基,x是Rf1的键数和1至4的整数。

    METHOD FOR PRODUCING FLUORINE-CONTAINING ELASTOMER
    9.
    发明申请
    METHOD FOR PRODUCING FLUORINE-CONTAINING ELASTOMER 有权
    生产含荧光弹性体的方法

    公开(公告)号:US20090234086A1

    公开(公告)日:2009-09-17

    申请号:US12307022

    申请日:2007-06-29

    IPC分类号: C08F16/24 C08F18/20

    CPC分类号: C08F214/18 C08F14/18 C08F2/22

    摘要: The present invention provides a method of producing a fluoroelastomer excellent in dispersion stability at low cost, at a high rate of polymerization and in high yields.The present invention is a method of producing a fluoroelastomer comprising an emulsion polymerization of a fluorinated monomer in the presence of a water-soluble radical polymerization initiator, wherein the emulsion polymerization is carried out in the presence of a compound (1) containing a functional group reactive in radical polymerization and a hydrophilic group and a fluorinated compound (2) containing a fluorocarbon group comprising 1 to 6 continuously united carbon atom with fluorine atom directly bound to each of them as well as a hydrophilic group.

    摘要翻译: 本发明提供以低成本,高聚合速率和高产率制备分散稳定性优异的含氟弹性体的方法。 本发明是一种在水溶性自由基聚合引发剂的存在下包含含氟单体的乳液聚合的含氟弹性体的方法,其中乳液聚合在含有官能团的化合物(1)的存在下进行, 自由基聚合反应性和亲水性基团以及含有含有1〜6个连续碳原子的碳氟化合物的含氟化合物(2)和与其各自直接键合的氟原子以及亲水基团。

    PROCESS FOR PREPARING FLUORINE-CONTAINING POLYMER AND FLUORINE-CONTAINING POLYMER PREPARED BY SAID PREPARATION PROCESS
    10.
    发明申请
    PROCESS FOR PREPARING FLUORINE-CONTAINING POLYMER AND FLUORINE-CONTAINING POLYMER PREPARED BY SAID PREPARATION PROCESS 有权
    制备含氟聚合物和含有准分子过程制备的含氟聚合物的方法

    公开(公告)号:US20090082519A1

    公开(公告)日:2009-03-26

    申请号:US11913287

    申请日:2006-04-28

    IPC分类号: C08K3/04 C08F214/18 C08L27/22

    摘要: The present invention provides the process for preparing a fluorine-containing polymer which can easily and efficiently separate a fluorine-containing polymer and water from an aqueous dispersion of a fluorine-containing polymer, and the fluorine-containing polymer obtained by the mentioned preparation process. Further the present invention provides the molded article obtained by crosslinking a curable composition comprising the above-mentioned fluorine-containing polymer and a crosslinking agent. The preparation process is a process for preparing a fluorine-containing polymer comprising a step for heat-treating an aqueous dispersion of a fluorine-containing polymer having a concentration of 3 to 70% by weight to obtain the fluorine-containing polymer having a water content of not more than 1% by weight.

    摘要翻译: 本发明提供一种制备含氟聚合物的方法,其可以容易且有效地从含氟聚合物的水性分散体中分离含氟聚合物和水,以及通过所述制备方法得到的含氟聚合物。 此外,本发明提供通过交联含有上述含氟聚合物的固化性组合物和交联剂而得到的成型体。 制备方法是一种制备含氟聚合物的方法,其包括用于热处理浓度为3-70重量%的含氟聚合物的水性分散体的步骤,以获得含水量的含氟聚合物 不超过1重量%。