公开(公告)号：US20170021387A1

公开(公告)日：2017-01-26

申请号：US14756006

申请日：2015-07-20

申请人： Yi-jun Lin ,  Shaio-yen Lee ,  Aruna Zhamu ,  Bor Z. Jang

发明人： Yi-jun Lin ,  Shaio-yen Lee ,  Aruna Zhamu ,  Bor Z. Jang

IPC分类号： B05D1/28 ,  B05D3/00 ,  B05D3/12 ,  C01B31/04 ,  B05D1/40

CPC分类号： B05D1/28 ,  B05D1/40 ,  B05D3/007 ,  B05D3/12 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B32/20 ,  C01B32/23

摘要： A process for producing a highly oriented graphene oxide (GO) film, comprising: (a) preparing either a GO dispersion having GO sheets dispersed in a fluid medium or a GO gel having GO molecules dissolved in a fluid medium; (b) dispensing the GO dispersion or gel onto a surface of an application roller rotating in a first direction to form an applicator layer of GO and transferring the applicator layer to a surface of a supporting film driven in a second direction opposite to the first direction to form a wet layer of GO on the supporting film; and (c) removing said fluid medium from the wet layer of GO to form a dried layer of GO having an inter-planar spacing d002 of 0.4 nm to 1.2 nm and an oxygen content no less than 5% by weight. This dried GO layer may be heat-treated to produce a graphitic film.

摘要翻译： 一种制备高取向氧化石墨（GO）膜的方法，包括：（a）制备具有分散在流体介质中的GO片的GO分散体或具有溶解在流体介质中的GO分子的GO凝胶; （b）将GO分散体或凝胶分配到沿第一方向旋转的施加辊的表面上，以形成GO的施用层，并将施加器层转移到沿与第一方向相反的第二方向驱动的支撑膜的表面 在支撑膜上形成GO的湿层; 和（c）从GO的湿层去除所述流体介质以形成具有0.4nm至1.2nm的平坦间距d002和氧含量不小于5％重量的GO的干燥层。 该干燥的GO层可以被热处理以产生石墨膜。

公开(公告)号：US09530531B2

公开(公告)日：2016-12-27

申请号：US13815317

申请日：2013-02-21

申请人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

发明人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

IPC分类号： B05D5/12 ,  H01B1/02 ,  H01B1/08 ,  H01B1/04 ,  B05D1/12 ,  C23C4/12 ,  C23C4/04 ,  B05D1/24 ,  H05K3/12

CPC分类号： H01B1/02 ,  B05D1/005 ,  B05D1/02 ,  B05D1/04 ,  B05D1/12 ,  B05D1/18 ,  B05D1/24 ,  B05D5/12 ,  C23C4/04 ,  C23C4/12 ,  H01B1/04 ,  H01B1/08 ,  H05K3/12

摘要： A process for producing a transparent conductive film, comprising (a) providing a graphene oxide gel; (b) dispersing metal nanowires in the graphene oxide gel to form a suspension; (c) dispensing and depositing the suspension onto a substrate; and (d) removing the liquid medium to form the film. The film is composed of metal nanowires and graphene oxide with a metal nanowire-to-graphene oxide weight ratio from 1/99 to 99/1, wherein the metal nanowires contain no surface-borne metal oxide or metal compound and the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square. This film can be used as a transparent conductive electrode in an electro-optic device, such as a photovoltaic or solar cell, light-emitting diode, photo-detector, touch screen, electro-wetting display, liquid crystal display, plasma display, LED display, a TV screen, a computer screen, or a mobile phone screen.

摘要翻译： 一种制造透明导电膜的方法，包括（a）提供石墨烯氧化物凝胶; （b）将金属纳米线分散在氧化石墨烯凝胶中以形成悬浮液; （c）将悬浮液分配并沉积到基底上; 和（d）除去液体介质以形成膜。 该膜由金属纳米线和氧化石墨烯组成，金属纳米线对石墨烯氧化物的重量比为1/99至99/1，其中金属纳米线不含表面金属氧化物或金属化合物，并且该膜表现出光学 透明度不低于80％，薄片电阻不高于300欧姆/平方。 该膜可以用作电光装置中的透明导电电极，例如光伏或太阳能电池，发光二极管，光电检测器，触摸屏，电润湿显示器，液晶显示器，等离子体显示器，LED 显示，电视屏幕，电脑屏幕或手机屏幕。

公开(公告)号：US08871296B2

公开(公告)日：2014-10-28

申请号：US13815730

申请日：2013-03-14

申请人： Aruna Zhamu ,  Yi-jun Lin ,  Bor Z. Jang

发明人： Aruna Zhamu ,  Yi-jun Lin ,  Bor Z. Jang

IPC分类号： C23C16/26 ,  C23C18/00 ,  B05D5/12 ,  B05D7/12 ,  B05D1/02 ,  H01B13/00

CPC分类号： H01B13/0036 ,  B05D1/02 ,  B05D5/12 ,  B05D7/12 ,  B22F1/0025 ,  B22F7/04 ,  B22F2007/042 ,  C22C26/00 ,  C23C16/26 ,  H01L31/1884 ,  H01L51/0021 ,  H01L51/0048 ,  H01L51/444 ,  Y02E10/50 ,  Y10S427/101

摘要： A method of producing a transparent and conductive film, comprising (a) forming aerosol droplets of a first dispersion comprising a first conducting nano filaments in a first liquid; (b) forming aerosol droplets of a second dispersion comprising a graphene material in a second liquid; (c) depositing the aerosol droplets of a first dispersion and the aerosol droplets of a second dispersion onto a supporting substrate; and (d) removing the first liquid and the second liquid from the droplets to form the film, which is composed of the first conducting nano filaments and the graphene material having a nano filament-to-graphene weight ratio of from 1/99 to 99/1, wherein the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square.

摘要翻译： 一种制造透明导电膜的方法，包括（a）在第一液体中形成包含第一导电纳米长丝的第一分散体的气溶胶滴; （b）在第二液体中形成包含石墨烯材料的第二分散体的气溶胶液滴; （c）将第一分散体的气溶胶液滴和第二分散体的气溶胶液滴沉积到支撑基底上; 和（d）从液滴中除去第一液体和第二液体以形成由第一导电纳米丝和石墨烯材料组成的膜，其具有1/99至99的纳米线 - 石墨烯重量比 / 1，其中所述膜显示不小于80％的光学透明度和不高于300欧姆/平方的薄层电阻。

公开(公告)号：US20140235123A1

公开(公告)日：2014-08-21

申请号：US13815316

申请日：2013-02-21

申请人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

发明人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

IPC分类号： H01B1/04 ,  H01B13/00

CPC分类号： H01B1/04 ,  B82Y30/00 ,  G06F3/041 ,  G06F2203/04103 ,  Y10T428/31678 ,  Y10T442/10

摘要： An optically transparent and electrically conductive film composed of metal nanowires or carbon nanotubes combined with pristine graphene with a metal nanowire-to-graphene or carbon nanotube-to-graphene weight ratio from 1/99 to 99/1, wherein the pristine graphene is single-crystalline and contains no oxygen and no hydrogen, and the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square. This film can be used as a transparent conductive electrode in an electro-optic device, such as a photovoltaic or solar cell, light-emitting diode, photo-detector, touch screen, electro-wetting display, liquid crystal display, plasma display, LED display, a TV screen, a computer screen, or a mobile phone screen.

摘要翻译： 由金属纳米线或碳纳米管与原始石墨烯组合的光学透明和导电膜，其中金属纳米线对石墨烯或碳纳米管与石墨烯的重量比为1/99至99/1，其中原始石墨烯为单一 不含氧而不含氢，膜的光学透明度不低于80％，薄层电阻不高于300欧姆/平方。 该膜可以用作电光装置中的透明导电电极，例如光伏或太阳能电池，发光二极管，光电检测器，触摸屏，电润湿显示器，液晶显示器，等离子体显示器，LED 显示，电视屏幕，电脑屏幕或手机屏幕。

公开(公告)号：US20170076833A1

公开(公告)日：2017-03-16

申请号：US15353906

申请日：2016-11-17

申请人： Yi-Jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

发明人： Yi-Jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

IPC分类号： H01B1/02 ,  H01B1/08 ,  B05D1/02 ,  B05D1/18 ,  B05D1/04 ,  H01B1/04 ,  B05D1/00

CPC分类号： H01B1/02 ,  B05D1/005 ,  B05D1/02 ,  B05D1/04 ,  B05D1/12 ,  B05D1/18 ,  B05D1/24 ,  B05D5/12 ,  C23C4/04 ,  C23C4/12 ,  H01B1/04 ,  H01B1/08 ,  H05K3/12

摘要： A process for producing a transparent conductive film, comprising (a) providing a graphene oxide gel; (b) dispersing metal nanowires in the graphene oxide gel to form a suspension; (c) dispensing and depositing the suspension onto a substrate; and (d) removing the liquid medium to form the film. The film is composed of metal nanowires and graphene oxide with a metal nanowire-to-graphene oxide weight ratio from 1/99 to 99/1, wherein the metal nanowires contain no surface-borne metal oxide or metal compound and the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square. This film can be used as a transparent conductive electrode in an electro-optic device, such as a photovoltaic or solar cell, light-emitting diode, photo-detector, touch screen, electro-wetting display, liquid crystal display, plasma display, LED display, a TV screen, a computer screen, or a mobile phone screen.

摘要翻译： 一种制造透明导电膜的方法，包括（a）提供石墨烯氧化物凝胶; （b）将金属纳米线分散在氧化石墨烯凝胶中以形成悬浮液; （c）将悬浮液分配并沉积到基底上; 和（d）除去液体介质以形成膜。 该膜由金属纳米线和氧化石墨烯组成，金属纳米线对石墨烯氧化物的重量比为1/99至99/1，其中金属纳米线不含表面金属氧化物或金属化合物，并且该膜表现出光学 透明度不低于80％，薄片电阻不高于300欧姆/平方。 该膜可以用作电光装置中的透明导电电极，例如光伏或太阳能电池，发光二极管，光电检测器，触摸屏，电润湿显示器，液晶显示器，等离子体显示器，LED 显示，电视屏幕，电脑屏幕或手机屏幕。

公开(公告)号：US20140231718A1

公开(公告)日：2014-08-21

申请号：US13815317

申请日：2013-02-21

申请人： Yi-Jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

发明人： Yi-Jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

IPC分类号： H01B13/30 ,  H01B1/02

CPC分类号： H01B1/02 ,  B05D1/005 ,  B05D1/02 ,  B05D1/04 ,  B05D1/12 ,  B05D1/18 ,  B05D1/24 ,  B05D5/12 ,  C23C4/04 ,  C23C4/12 ,  H01B1/04 ,  H01B1/08 ,  H05K3/12

摘要： A process for producing a transparent conductive film, comprising (a) providing a graphene oxide gel; (b) dispersing metal nanowires in the graphene oxide gel to form a suspension; (c) dispensing and depositing the suspension onto a substrate; and (d) removing the liquid medium to form the film. The film is composed of metal nanowires and graphene oxide with a metal nanowire-to-graphene oxide weight ratio from 1/99 to 99/1, wherein the metal nanowires contain no surface-borne metal oxide or metal compound and the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square. This film can be used as a transparent conductive electrode in an electro-optic device, such as a photovoltaic or solar cell, light-emitting diode, photo-detector, touch screen, electro-wetting display, liquid crystal display, plasma display, LED display, a TV screen, a computer screen, or a mobile phone screen.

摘要翻译： 一种制造透明导电膜的方法，包括（a）提供石墨烯氧化物凝胶; （b）将金属纳米线分散在氧化石墨烯凝胶中以形成悬浮液; （c）将悬浮液分配并沉积到基底上; 和（d）除去液体介质以形成膜。 该膜由金属纳米线和氧化石墨烯组成，金属纳米线对石墨烯氧化物的重量比为1/99至99/1，其中金属纳米线不含表面金属氧化物或金属化合物，并且该膜表现出光学 透明度不低于80％，薄片电阻不高于300欧姆/平方。 该膜可以用作电光装置中的透明导电电极，例如光伏或太阳能电池，发光二极管，光电检测器，触摸屏，电润湿显示器，液晶显示器，等离子体显示器，LED 显示，电视屏幕，电脑屏幕或手机屏幕。

公开(公告)号：US20140315100A1

公开(公告)日：2014-10-23

申请号：US13986319

申请日：2013-04-22

申请人： Yanbo Wang ,  Bor Z. Jang ,  Hui He ,  Aruna Zhamu ,  Yi-jun Lin

发明人： Yanbo Wang ,  Bor Z. Jang ,  Hui He ,  Aruna Zhamu ,  Yi-jun Lin

IPC分类号： H01M4/36

CPC分类号： H01M4/366 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/621 ,  H01M4/625 ,  H01M10/3909 ,  H01M2004/021 ,  Y10T29/49115

摘要： A rechargeable lithium-sulfur cell comprising an anode, a separator and/or electrolyte, a sulfur cathode, an optional anode current collector, and an optional cathode current collector, wherein the cathode comprises (a) exfoliated graphite worms that are interconnected to form a porous, conductive graphite flake network comprising pores having a size smaller than 100 nm; and (b) nano-scaled powder or coating of sulfur, sulfur compound, or lithium polysulfide disposed in the pores or coated on graphite flake surfaces wherein the powder or coating has a dimension less than 100 nm. The exfoliated graphite worm amount is in the range of 1% to 90% by weight and the amount of powder or coating is in the range of 99% to 10% by weight based on the total weight of exfoliated graphite worms and sulfur (sulfur compound or lithium polysulfide) combined. The cell exhibits an exceptionally high specific energy and a long cycle life.

摘要翻译： 包括阳极，隔板和/或电解质，硫阴极，任选的阳极集电器和任选的阴极集电器的可再充电锂 - 硫电池，其中所述阴极包括（a）相互连接形成的剥离的石墨蠕虫 多孔导电石墨薄片网络，其包含尺寸小于100nm的孔; 和（b）设置在孔中的纳米级粉末或硫，硫化合物或多硫化锂的涂层，或涂覆在石墨片表面上，其中粉末或涂层具有小于100nm的尺寸。 剥离石墨蠕虫量在1重量％至90重量％的范围内，粉末或涂层的量基于脱落的石墨蠕虫和硫（硫化合物）的总重量在99重量％至10重量％的范围内 或多硫化锂）组合。 电池表现出特别高的比能量和较长的循环寿命。

公开(公告)号：US20140272199A1

公开(公告)日：2014-09-18

申请号：US13815729

申请日：2013-03-14

申请人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang ,  Shaio-yen Lee ,  Jui Chi Lin

发明人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang ,  Shaio-yen Lee ,  Jui Chi Lin

IPC分类号： H01B13/00

CPC分类号： B22F1/0025 ,  B22F7/04 ,  B22F2007/042 ,  C22C26/00 ,  H01B1/22 ,  H01L31/1884 ,  H01L51/444 ,  Y02E10/549

摘要： An ultrasonic spray coating method of producing a transparent and conductive film, comprising (a) operating an ultrasonic spray device to form aerosol droplets of a first dispersion comprising a first conducting nano filaments in a first liquid; (b) forming aerosol droplets of a second dispersion comprising a graphene material in a second liquid; (c) depositing the aerosol droplets of a first dispersion and the aerosol droplets of a second dispersion onto a supporting substrate; and (d) removing the first liquid and the second liquid from the droplets to form the film, which is composed of the first conducting nano filaments and the graphene material having a nano filament-to-graphene weight ratio of from 1/99 to 99/1, wherein the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square.

摘要翻译： 一种制造透明和导电膜的超声波喷涂方法，包括（a）操作超声波喷射装置以形成第一分散体的气溶胶滴，所述第一分散体包含第一液体中的第一导电纳米长丝; （b）在第二液体中形成包含石墨烯材料的第二分散体的气溶胶液滴; （c）将第一分散体的气溶胶液滴和第二分散体的气溶胶液滴沉积到支撑基底上; 和（d）从液滴中除去第一液体和第二液体以形成由第一导电纳米丝和石墨烯材料组成的膜，其具有1/99至99的纳米线 - 石墨烯重量比 / 1，其中所述膜显示不小于80％的光学透明度和不高于300欧姆/平方的薄层电阻。

公开(公告)号：US20140272172A1

公开(公告)日：2014-09-18

申请号：US13815730

申请日：2013-03-14

申请人： Aruna Zhamu ,  Yi-jun Lin ,  Bor Z. Jang

发明人： Aruna Zhamu ,  Yi-jun Lin ,  Bor Z. Jang

IPC分类号： H01B13/00

CPC分类号： H01B13/0036 ,  B05D1/02 ,  B05D5/12 ,  B05D7/12 ,  B22F1/0025 ,  B22F7/04 ,  B22F2007/042 ,  C22C26/00 ,  C23C16/26 ,  H01L31/1884 ,  H01L51/0021 ,  H01L51/0048 ,  H01L51/444 ,  Y02E10/50 ,  Y10S427/101

摘要： A method of producing a transparent and conductive film, comprising (a) forming aerosol droplets of a first dispersion comprising a first conducting nano filaments in a first liquid; (b) forming aerosol droplets of a second dispersion comprising a graphene material in a second liquid; (c) depositing the aerosol droplets of a first dispersion and the aerosol droplets of a second dispersion onto a supporting substrate; and (d) removing the first liquid and the second liquid from the droplets to form the film, which is composed of the first conducting nano filaments and the graphene material having a nano filament-to-graphene weight ratio of from 1/99 to 99/1, wherein the film exhibits an optical transparence no less than 80% and sheet resistance no higher than 300 ohm/square.

公开(公告)号：US20140224466A1

公开(公告)日：2014-08-14

申请号：US13815246

申请日：2013-02-14

申请人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

发明人： Yi-jun Lin ,  Aruna Zhamu ,  Bor Z. Jang

IPC分类号： F28F21/02

CPC分类号： B82Y30/00 ,  H01L23/373 ,  H01L23/3735 ,  H01L23/3737 ,  H01L2924/0002 ,  Y10S977/833 ,  H01L2924/00

摘要： An integrated heat sink article composed of a heat collection member and at least one heat dissipation member integral to the heat collection member, wherein the heat collection member is configured to be in thermal contact with a heat source, collects heat from the heat source, and dissipates heat through the at least one heat dissipation member, and further wherein the heat sink is formed of a nano graphene platelet-reinforced composite having nano graphene platelets or sheets (NGPs) as a first reinforcement phase dispersed in a matrix material and the first reinforcement phase occupies a weight fraction of 1-90% based on the total composite weight. Preferably, these NGPs, alone or in combination with a second reinforcement phase, are bonded by an adhesive and constitute a continuous 3-D network of electron- and phonon-conducting paths.

摘要翻译： 1.一种集热散热片，其特征在于，由集热构件和与所述集热构件成一体的至少一个散热构件构成，其特征在于，所述集热构件与热源热接触，从所述热源收集热量， 通过所述至少一个散热构件散热，并且其中所述散热器由纳米石墨烯片增强复合材料形成，纳米石墨烯片增强复合材料具有分散在基质材料中的纳米石墨烯片晶或片材（NGP）作为第一增强相，所述第一增强材料 基于总复合重量，相的重量分数为1-90％。 优选地，这些NGP单独地或与第二增强相结合，通过粘合剂结合并构成电子和声子传导路径的连续3-D网络。