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    Photoelectric transfer material, manufacturing method thereof, photoelectric transfer element and manufacturing method thereof
    2.
    发明授权
    Photoelectric transfer material, manufacturing method thereof, photoelectric transfer element and manufacturing method thereof 有权
    光电转移材料及其制造方法，光电转移元件及其制造方法

    公开(公告)号：US07884281B2

    公开(公告)日：2011-02-08

    申请号：US11033587

    申请日：2005-01-11

    Applicant: Masashi Enomoto ,  Myung-Seok Choi ,  Yoshiaki Kobuke ,  Akiharu Satake

    Inventor： Masashi Enomoto ,  Myung-Seok Choi ,  Yoshiaki Kobuke ,  Akiharu Satake

    IPC: H01L31/00

    CPC classification number: H01L51/0035 ,  B82Y10/00 ,  C07D417/14 ,  H01L51/0037 ,  H01L51/0047 ,  H01L51/0092 ,  H01L51/0595 ,  H01L51/4253 ,  H01L2251/308 ,  Y02E10/549 ,  Y02P70/521

    Abstract: A photoelectric transfer material, manufacturing method thereof, photoelectric transfer element and manufacturing method thereof are provided. In an organic photoelectric transfer element of an organic solar cell or other like device, the photoelectric transfer material is composed of a conductive polymer such as MEH-PPV, electronic acceptor such as a fullerene derivative and antenna porphyrin aggregate. The photoelectric transfer material can be made by coating a mixed solution of the conductive polymer, electron acceptor and antenna porphyrin aggregate by spin coating, for example. This photoelectric transfer material and a photoelectric transfer element using the material exhibit high photoelectric transfer efficiency because of small electric resistance and high sunlight usage efficiency, and simultaneously exhibit stability.

    Abstract translation: 提供光电转移材料及其制造方法，光电转移元件及其制造方法。 在有机太阳能电池或其他类似器件的有机光电转移元件中，光电转移材料由导电聚合物如MEH-PPV，电子受体如富勒烯衍生物和天线卟啉骨料组成。 光电转移材料可以通过例如通过旋涂来涂覆导电聚合物，电子受体和天线卟啉骨料的混合溶液来制备。 该光电转移材料和使用该材料的光电转移元件由于电阻小且阳光使用效率高而表现出高的光电转移效率，同时表现出稳定性。

    Porphyrin-phthalocyanine dimer and tetramer having directly-bound Pi electron systems and production method thereof
    3.
    发明申请
    Porphyrin-phthalocyanine dimer and tetramer having directly-bound Pi electron systems and production method thereof 失效
    具有直接键合的Pi电子系的卟啉 - 酞菁二聚物和四聚体及其制备方法

    公开(公告)号：US20060217538A1

    公开(公告)日：2006-09-28

    申请号：US11442567

    申请日：2006-05-30

    Applicant: Yoshiaki Kobuke ,  Akiharu Satake ,  Kazuya Ogawa

    Inventor： Yoshiaki Kobuke ,  Akiharu Satake ,  Kazuya Ogawa

    IPC: C07F5/00 ,  C07D487/22

    CPC classification number: C07D519/00

    Abstract: A porphyrin/phthalocyanine dimer represented by the following Formula (A-1) and a tetramer represented by the following Formula (A-2) (where R1, R2 and R3 may be the same or different, and each represents a hydrogen atom or an alkyl or alkyloxy group; M1 and M2 may be the same or different, and each represents two protons or a bivalent or trivalent metal ion; X1 represents a single bond or an alkylene group; X represents —O—, —S—, >NR101 (where R101 represents H or alkyl group), CH2, or a single bond; Y represents 2H, ═O or ═S; m is an integer of 0 to 4; Z represents a five- or six-membered nitrogen-containing coordinating heteroaromatic ring group; provided that the multiple substituent groups represented by the same character may be the same or different.

    Abstract translation: 由下式（A-1）表示的卟啉/酞菁二聚体和由下式（A-2）表示的四聚体（其中R 1，R 2，和 R 3可以相同或不同，并且各自表示氢原子或烷基或烷氧基; M 1和M 2可以是 相同或不同，并且各自表示两个质子或二价或三价金属离子; X 1表示单键或亚烷基; X表示-O - ， - S-，> NR 101（其中R 101表示H或烷基），CH 2或单键; Y表示2H，-O或-S; m 是0〜4的整数，Z表示5元或6元的含氮配位杂芳环基团，条件是由相同字符表示的多个取代基可以相同或不同。

    Porphyrin array exhibiting large two photon absorption property and including, as structural unit, bis (imidazolylporphyrin metal complex) linked with acetylenic bond and the derivative thereof, and method of producing the same
    4.
    发明授权
    Porphyrin array exhibiting large two photon absorption property and including, as structural unit, bis (imidazolylporphyrin metal complex) linked with acetylenic bond and the derivative thereof, and method of producing the same 失效
    显示出大的双光子吸收特性的卟啉阵列，并且包括与炔键连接的双（咪唑基卟啉金属络合物）及其衍生物作为结构单元，以及其制备方法

    公开(公告)号：US07022840B2

    公开(公告)日：2006-04-04

    申请号：US10715493

    申请日：2003-11-19

    Applicant: Yoshiaki Kobuke ,  Kazuya Ogawa

    Inventor： Yoshiaki Kobuke ,  Kazuya Ogawa

    IPC: A61B5/055 ,  A61B10/00 ,  C07B47/00 ,  C07F5/10 ,  A61K31/555

    CPC classification number: C07D487/22

    Abstract: A porphyrin array exhibiting a large two-photon absorption property, and being linked with an acetylenic bond(s), represented by the following formulas: wherein R1 represents an alkyl or aryl group, M1 represents a metal ion capable of serving as a core metal and forming a coordinate bond with Im, M2 represents two protons or a metal ion incapable of forming a coordinate bond with Im, R2 and R3 represent a group selected from a porphyrin residue or porphyrin metal complex residue, a cyclic diimide residue, a dialkylviologen residue, a benzoquinone residue, an N-methylpyrrolidine-fullerene derivative residue and a ferrocene residue, Im is represented by Im1 or Im2: (R8 represents methyl or H), L1 represents —(—C≡C—)m— (m=1 to 3); n represents an integer of 1 or more; R9 represents one of R1, R2, R3 and Im.

    Abstract translation: 具有大的双光子吸收特性并与炔键连接的卟啉阵列由下式表示：其中R 1表示烷基或芳基， 1 表示能够作为核心金属并与Im形成配位键的金属离子，M 2表示两个质子或不能与Im形成配位键的金属离子 R 3和R 3代表选自卟啉残基或卟啉金属络合物残基的基团，环状二酰亚胺残基，二烷基生物碱残基，苯醌残基，N-甲基吡咯烷酮 - 富勒烯衍生物残基和二茂铁残基，Im由Im 1或Im 2表示：（R 8表示甲基或H），L < （m = 1〜3）表示 - （ - C≡C - ）m - n表示1以上的整数， R 9表示R 1，R 2，R 3和R 1中的一个。

    Porphyrin array having imidazolyl porphyrin metal complex as structural unit thereof and method of producing the same
    5.
    发明授权
    Porphyrin array having imidazolyl porphyrin metal complex as structural unit thereof and method of producing the same 失效
    具有咪唑基卟啉金属络合物作为其结构单元的卟啉阵列及其制备方法

    公开(公告)号：US06727358B2

    公开(公告)日：2004-04-27

    申请号：US10231074

    申请日：2002-08-30

    Applicant: Yoshiaki Kobuke ,  Kazuya Ogawa

    Inventor： Yoshiaki Kobuke ,  Kazuya Ogawa

    IPC: C07D48722

    CPC classification number: C07F3/003

    Abstract: A porphyrin array represented by the following general formula (1-1) or (1-2): wherein R1 represents an alkyl group or a substituted or unsubstituted aryl group; M1 represents a metal ion; R2 and R3 independently represent an electron acceptor or an electron donor; Im represents Im1 or Im2 set forth below: wherein R4 represents a hydrogen atom or a methyl group; and n represents an integer in the range of 1 to 100.

    Abstract translation: 由以下通式（1-1）或（1-2）表示的卟啉阵列：其中R1表示烷基或取代或未取代的芳基; M1表示金属离子; R2和R3独立地表示电子受体或电子给体; Im表示下述的Im1或Im2：其中R4表示氢原子或甲基; n表示1〜100的整数。

    Mercapto-substituted imidazolylporphyrin metal complex monomer, polymer having the same as a repeating unit and method of preparing the same
    6.
    发明授权
    Mercapto-substituted imidazolylporphyrin metal complex monomer, polymer having the same as a repeating unit and method of preparing the same 失效
    巯基取代的咪唑基卟啉金属络合物单体，与重复单元相同的聚合物及其制备方法

    公开(公告)号：US06602998B2

    公开(公告)日：2003-08-05

    申请号：US09802923

    申请日：2001-03-12

    Applicant: Yoshiaki Kobuke ,  Kazuya Ogawa

    Inventor： Yoshiaki Kobuke ,  Kazuya Ogawa

    IPC: C07D48722

    CPC classification number: C07D519/00 ,  Y02E10/542

    Abstract: A mercapto-substituted imidazolylporphyrin metal complex monomer represented by a general formula (1): wherein R1 represents a group selected from the group consisting of an alkyl group, unsubstituted aryl group, alkyl-substituted aryl group and alkyloxy-substituted aryl group, M represents a metal ion selected from the group consisting of Zn(II), Ga(III), Fe(II), Co(II), and Ru(II), X represents a divalent linking group containing at least one group selected from the group consisting of an arylene group and an alkylene group, R2 represents a hydrogen atom or an acetyl group, and Im represents Im1 or Im2 set forth below: wherein R3 represents a hydrogen atom or an alkyl group.

    Abstract translation: 由通式（1）表示的巯基取代的咪唑基卟啉金属络合物单体：其中R1表示选自烷基，未取代的芳基，烷基取代的芳基和烷氧基取代的芳基的基团，M表示 选自Zn（II），Ga（III），Fe（II），Co（II）和Ru（II）的金属离子，X表示含有至少一个选自 由亚芳基和亚烷基组成，R2表示氢原子或乙酰基，Im表示下述的Im1或Im2：其中R3表示氢原子或烷基。

    Porphyrin-phthalocyanine dimer and tetramer having directly-bound π electron systems and production method thereof
    7.
    发明授权
    Porphyrin-phthalocyanine dimer and tetramer having directly-bound π electron systems and production method thereof 失效
    卟啉 - 酞菁二聚体和四聚体具有直接键合 电子系统及其制造方法

    公开(公告)号：US07767808B2

    公开(公告)日：2010-08-03

    申请号：US11442567

    申请日：2006-05-30

    Applicant: Yoshiaki Kobuke ,  Akiharu Satake ,  Kazuya Ogawa

    Inventor： Yoshiaki Kobuke ,  Akiharu Satake ,  Kazuya Ogawa

    IPC: C07B47/00

    CPC classification number: C07D519/00

    Abstract: A porphyrin/phthalocyanine dimer represented by the following Formula (A-1) and a tetramer represented by the following Formula (A-2) (where R1, R2 and R3 may be the same or different, and each represents a hydrogen atom or an alkyl or alkyloxy group; M1 and M2 may be the same or different, and each represents two protons or a bivalent or trivalent metal ion; X1 represents a single bond or an alkylene group; X represents —O—, —S—, >NR101 (where R101 represents H or alkyl group), CH2, or a single bond; Y represents 2H, ═O or ═S; m is an integer of 0 to 4; Z represents a five- or six-membered nitrogen-containing coordinating heteroaromatic ring group; provided that the multiple substituent groups represented by the same character may be the same or different.

    Abstract translation: 由下式（A-1）表示的卟啉/酞菁二聚体和由下式（A-2）表示的四聚体（其中R 1，R 2和R 3可以相同或不同，各自表示氢原子或 烷基或烷氧基; M1和M2可以相同或不同，分别表示两个质子或二价或三价金属离子; X1表示单键或亚烷基; X表示-O - ， - S-，NR101 （其中R 101表示H或烷基），CH 2或单键; Y表示2H，= O或= S; m表示0〜4的整数; Z表示五元或六元含氮配位杂芳族 只要由相同字符表示的多个取代基可以相同或不同。

    12-Alkyl-1,4,7,10-tetraazacyclotridecane
    10.
    发明授权
    12-Alkyl-1,4,7,10-tetraazacyclotridecane 失效
    12-烷基-1,4,7,10-四氮杂环十三烷

    公开(公告)号：US4174319A

    公开(公告)日：1979-11-13

    申请号：US871349

    申请日：1978-01-23

    Applicant: Yoshiaki Kobuke

    Inventor： Yoshiaki Kobuke

    IPC: B01J45/00 ,  C07C29/147 ,  C07D257/02 ,  C09K3/00

    CPC classification number: C07D257/02 ,  C07C29/147

    Abstract: 12-alkyl-1,4,7,10-tetraazacyclotridecane of the formula ##STR1## wherein R is an alkyl group containing at least 8 carbon atoms. This compound can be used for capturing metal ions.

    Abstract translation: 其中R是含有至少8个碳原子的烷基的式“IMAGE”的12-烷基-1,4,7,10-四氮杂环十二烷。 该化合物可用于捕获金属离子。

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