摘要:
A method for polymerizing olefins which comprises using a catalyst which comprises, as the essential components, (A) a metallocene-type transition metal compound and (B) at least one member selected from the group consisting of (1) an ion-exchanging layered compound other than a silicate and (2) an inorganic silicate, which is obtained by salt-treatment and/or acid-treatment and which has a water content of not higher than 1% by weight.
摘要:
A catalyst for polymerizing an olefin, which comprises (A) a metallocene transition metal compound, (B) (1) an ion-exchanging layered compound other than a silicate or (2) an inorganic silicate prepared by treating a starting ion-exchanging layer compound other than a silicate or a starting silicate with a salt, an acid, or a combination thereof, said component (B) having a water content not higher than 1% by weight which is obtained by heat-dehydrating component (B) under an inert gas atmosphere or under reduced pressure, and (C) an organoaluminum compound.
摘要:
A particulate phyllosilicate mixture comprising a mixture containing a phyllosilicte belonging to the smectite group and a phyllosilicate belonging to the mica group, the phyllosilicate particle having a content of the phyllosilicate belonging to the smectite group of 0.1 to 50% by weight and optionally satisfying the following requirements (a) to (c): (a): the average particle diameter is 20 to 1000 &mgr;m with not more than 20% of the total number of particles being accounted for by particles having a particle diameter of not more than 10 &mgr;m; (b): the crushing strength of the particle is not less than 0.5 MPa as measured with a microcompression tester and (c): the bulk density of the particle of not less than 0.6 g/cm3. Polymerization of olefins with catalyst comprising the particulate phyllosilicate mixture as a carrier or support for the catalysts is also disclosed
摘要翻译:一种颗粒状页硅酸盐混合物,其包含含有属于蒙脱石组的页硅酸盐和属于云母族的页硅酸盐的混合物,具有属于蒙皂石组的页硅酸盐含量为0.1-50重量%的页硅酸盐颗粒,并且任选地满足以下 要求(a)〜(c):( a)平均粒径为20〜1000μm,不超过粒径为10μm以下的颗粒占总粒数的20%以下; (b):使用微压缩试验机测定,颗粒的抗碎强度不小于0.5MPa,(c)颗粒的堆积密度不小于0.6g / cm 3。烯烃与包含颗粒的催化剂的聚合 还公开了页硅酸盐混合物作为催化剂的载体或载体
摘要:
A particulate phyllosilicate mixture comprising a mixture containing a phyllosilicte belonging to the smectite group and a phyllosilicate belogning to the mica group, the phyllosilicate particle having a content of the phyllosilicate belonging to the smectite group of 0.1 to 50% by weight and optionally satisfying the following requirements (a) to (c):(a): the average particle diameter is 20 to 1000 .mu.m with not more than 20% of the total number of particles being accounted for by particles having a particle diameter of not more than 10 .mu.m;(b): the crushing strength of the particle is not less than 0.5 MPa as measured with a microcompression tester and(c): the bulk density of the particle of not less than 0.6 g/cm.sup.3.Polymerization of olefins with catalyst comprising the particulate phyllosilicate mixture as a carrier or support for the catalysts is also disclosed.
摘要翻译:一种颗粒状页硅酸盐混合物,其包含含有属于蒙脱石组的页硅酸盐的混合物和与云母基团相连的页硅酸盐,具有属于蒙皂石组的页硅酸盐含量为0.1至50重量%的页硅酸盐颗粒,并且任选地满足以下 要求(a)至(c):(a):平均粒径为20〜1000μm,粒径不大于10μm的粒子占总粒数的20%以下 m; (b):使用微压缩试验机测定,颗粒的抗碎强度不小于0.5MPa,(c)颗粒的堆积密度不小于0.6g / cm3。 还公开了含有颗粒状页硅酸盐混合物的催化剂的烯烃与催化剂的载体或载体的聚合。
摘要:
Olefin polymerization catalysts for producing polyolefin resins which can dispense with a melt-kneading step necessitating great energy or a substitute addition step therefor and to which small amounts of antioxidants have been effectively added; and a process for the production of the catalysts. Specifically, a catalyst for olefin polymerization characterized by being prepared by conducting prepolymerization in the presence of [I] a solid catalyst for olefin polymerization having a mean particle diameter of 10 to 200 μm, [II] an antioxidant for resins, and [III] an olefin; and a catalyst for olefin polymerization characterized by containing [IV] an organoaluminum compound in addition to the components [I] to [III].
摘要:
Disclosed is a propylene block copolymer having excellent flexibility and impact resistance and showing a good polymer powder form. Also disclosed is a process for producing the copolymer. More specifically, the copolymer is a novel propylene block copolymer which satisfies a specific requirement and is produced by a process comprising continuously performing a multi-step polymerization composed of a former step in which a propylene homopolymer component or a specific propylene copolymer component is produced in the presence of a metallocene catalyst carried on a support and a latter step in which propylene and a specific copolymer component are produced by gas phase polymerization.
摘要:
Disclosed is a propylene block copolymer having excellent flexibility and impact resistance and showing a good polymer powder form. Also disclosed is a process for producing the copolymer. More specifically, the copolymer is a novel propylene block copolymer which satisfies a specific requirement and is produced by a process comprising continuously performing a multi-step polymerization composed of a former step in which a propylene homopolymer component or a specific propylene copolymer component is produced in the presence of a metallocene catalyst carried on a support and a latter step in which propylene and a specific copolymer component are produced by gas phase polymerization.