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    Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins
    4.
    发明授权
    Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins 失效
    茂金属化合物，其制备方法及其在烯烃聚合催化剂中的应用

    公开(公告)号：US06051728A

    公开(公告)日：2000-04-18

    申请号：US599483

    申请日：1996-01-23

    申请人： Luigi Resconi ,  Fabrizio Piemontesi ,  Ilya E. Nifant'ev ,  Pavel V. Ivchenko

    发明人： Luigi Resconi ,  Fabrizio Piemontesi ,  Ilya E. Nifant'ev ,  Pavel V. Ivchenko

    IPC分类号： C07F7/00 ,  C07F17/00 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C07F9/00 ,  C07F11/00

    CPC分类号： C08F10/06 ,  C07F17/00 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

    摘要： A class of metallocene compounds having two substituted cyclopentadienyl rings bridged by an alkylidene group wherein the cyclopentadienyl groups can be indenyl groups. The metallocene compounds have the following structures: ##STR1## The metallocenes are characterized by three principal features: (i) the cyclopentadienyl groups are substituted at the 3-position with a substituent other than hydrogen, while R.sup.2 in the 2-position bears a hydrogen (formula (I)) or is part of a condensed benzene ring (formula (II)); (ii) the bridge is a substituted-methylene bridge, i.e. a methylene group bearing at least one substituent other than hydrogen (R.sup.6 is always different from hydrogen); and (iii) the cyclopentadienyl groups are identically substituted (page 2, line 23). These metallocene compounds can be suitably used as catalyst components for the polymerization of olefins. In particular, by polymerizing propylene in the presence of a catalyst based on these metallocene compounds, polymers having very high isotactic indexes, high molecular weights, and narrow molecular weight distributions can be obtained in high yields. A process for preparing the metallocenes from the corresponding organic ligands is also disclosed.

    摘要翻译： 一类具有由亚烷基桥连的取代环戊二烯基环的茂金属化合物，其中环戊二烯基可以是茚基。 茂金属化合物具有以下结构：金属茂的特征在于三个主要特征：（i）环戊二烯基在3位被氢以外的取代基取代，而2-位的R2带有氢（式（式 I））或是稠合苯环的一部分（式（II））; （ii）桥是取代的亚甲基桥，即具有除氢之外的至少一个取代基的亚甲基（R6总是不同于氢）; 和（iii）环戊二烯基相同取代（第2页，第23行）。 这些茂金属化合物可以适合用作烯烃聚合的催化剂组分。 特别地，通过在基于这些茂金属化合物的催化剂的存在下聚合丙烯，可以高产率获得具有非常高的全同立构指数，高分子量和窄分子量分布的聚合物。 还公开了从相应的有机配体制备金属茂的方法。

    Catalyst components for the polymerization of olefins
    6.
    发明授权
    Catalyst components for the polymerization of olefins 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号：US08835578B2

    公开(公告)日：2014-09-16

    申请号：US13579027

    申请日：2011-02-22

    申请人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T. M. Pater ,  Giampiero Morini

    发明人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T. M. Pater ,  Giampiero Morini

    IPC分类号： C08F4/649 ,  C08F110/06

    CPC分类号： C08F110/06 ,  C08F4/6545 ,  C08F4/6465 ,  C08F4/651 ,  C08F2500/15

    摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where RI and RII are the same or different and are hydrogen or linear or branched C1-C18 hydrocarbon groups which can also form one or more cyclic structures; RIII groups, equal or different from each other, are hydrogen or C1-C18 hydrocarbon groups; RIV groups equal or different from each other, have the same meaning of RIII except that they cannot be hydrogen; each of RI to RIV groups can contain heteroatoms selected from halogens, N, O, S and Si.

    摘要翻译： 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两种电子给体化合物，其中一种选自烷氧基苯，另一种选自那些 其中R 1和R II相同或不同，为氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    10.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化组分

    公开(公告)号：US20120316300A1

    公开(公告)日：2012-12-13

    申请号：US13579029

    申请日：2011-02-22

    申请人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T.M. Pater ,  Giampiero Morini

    发明人： Simona Guidotti ,  Fabrizio Piemontesi ,  Joachim T.M. Pater ,  Giampiero Morini

    IPC分类号： C08F4/649 ,  C08F210/06

    CPC分类号： C08F110/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F4/6465 ,  C08F2500/15

    摘要： Catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) wherein: R2, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements or alkoxy groups of formula —OR1, two or more of the R2 groups can be connected together to form a cycle; R1, equal to or different from each other, are C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements, with the proviso that at least one of R2 is —OR1 and the other being selected from succinates of formula (II): wherein the radicals RI and RII, equal to or different from each other, are a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; the radicals RIII to RVI equal to or different from each other, are hydrogen or a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms, and the radicals RIII to RVI which are joined to the same carbon atom of the succinate chain can be linked together to form a cycle.

    摘要翻译： 用于烯烃CH 2 = CHR的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一个选自式（I）的那些，其中：R2 彼此相同或不同的是氢原子或任选含有属于式-OR1的元素或烷氧基的周期表第13-17族的杂原子的C1-C20烃基，R2基中的两个或更多个可以 连接在一起形成一个循环; R1彼此相同或不同的是C1-C20烃基，其任选地含有属于元素周期表第13-17族的杂原子，条件是R 2中的至少一个为-OR 1且另一个选自 来自式（II）的琥珀酸盐：其中基团R 1和R II彼此相同或不同，是任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基; RIII至RVI彼此相同或不同的基团是氢或任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳烷基或烷基芳基，以及RIII至RVI基团连接至 琥珀酸酯链的相同碳原子可以连接在一起形成循环。